The sum of primary valence and secondary valence of the metal M in the complex [M(en)₂(Ox)]Cl is________.

(a)

3

(b)

6

(c)

-3

(d)

9

As per IUPAC guidelines, the name of the complex [Co(en)₂(ONO)Cl]Cl is _______.

(a)

chlorobisethylenediaminenitritocobalt(III) chloride

(b)

chloridobis(ethane-1, 2-diamine)nitro  K-Ocobaltate(III) chloride

(c)

chloridobis(ethane-1, 2-diammine)nitrito K-Ocobalt(II) chloride

(d)

chloridobis(ethane-1, 2-diamine)nitrito K-O cobalt(III) chloride

A magnetic moment of 1.73BM will be shown by one among the following.

(a)

TiCl₄

(b)

[CoCl₆]^4-

(c)

[Cu(NH₃)₄]²⁺

(d)

[Ni(CN)₄]^2-

In which of the following coordination entities the magnitude of Δ₀ will be maximum?

(a)

[Co(CN)₆]^3-

(b)

[Co(C₂O₄)₃]^3-

(c)

[Co(H₂O)₆]³⁺

(d)

[Co(NH₃)₆]³⁺

Which type of isomerism is exhibited by [Pt(NH₃)₂Cl₂]?

(a)

Coordination isomerism

(b)

Linkage isomerism

(c)

Optical isomerism

(d)

Geometrical isomerism

Which one of the following pairs represents linkage isomers?

(a)

[Cu(NH₃)₄][PtCl₄] and [Pt(NH₃)₄][CuCl₄]

(b)

[Co(NH₃)₅(NO₃)]SO₄ and [Co(NH₃)₅(ONO)]

(c)

[Co(NH₃)₄(NCS)₂]Cl and [Co(NH₃)₄(SCN)₂]Cl

(d)

both (b) and (c)

Formula of tris(ethane-1, 2-diamine)iron(II)phosphate _______.

(a)

[Fe(CH₃-CH(NH₂)₂)₃](PO₄)₃

(b)

[Fe(H₂N-CH₂-CH₂-NH₂)₃](PO₄)

(c)

[Fe(H₂N-CH₂-CH₂-NH₂)₃](PO₄)₂

(d)

[Fe(H₂N-CH₂-CH₂-NH₂)₃]₃(PO₄)₂

Fac-mer isomerism is shown by _______.

(a)

[CO(en)₃]³⁺

(b)

[Co(NH₃)₄(Cl)₂]⁺

(c)

[Co(NH₃)₃(Cl)₃]

(d)

[Co(NH₃)₅Cl]SO₄

An example of an ambidentate ligand is _______.

(a)

CN^-

(b)

Cl^-

(c)

NO^-₂

(d)

I^-

In [Fe¹¹(CN)₆]^4-, the central metal ion is _______.

(a)

Fe

(b)

Fe²⁺

(c)

Fe³⁺

(d)

CN^-

A metal ion from the first transition series forms an octahedral complex with magnetic moment of 4.9 BM and another octahedral, complex which is diamagnetic. The metal ion is _______.

(a)

Fe²⁺

(b)

Co²⁺

(c)

Mn²⁺

(d)

Ni²⁺

Which of the following complexes does not give white precipitate with AgNO₃?

(a)

[Co(NH₃)₆]Cl₃

(b)

[Co(NH₃)₃Cl₃]

(c)

[Co(NH₃)5Cl]Cl₃

(d)

[Co(NH₃)₄Cl₂]Cl₃

An example of unidentate ligand is_______.

(a)

NH₂ - CH₂ - CH₂ - NH₂

(b)

C₂O^2-₄

(c)

CH₃COO^-

(d)

both (b) and (c)

The isomerism exhibited by the complexes [Co(NH₃)₆] [Cr(CN)₆] and [Cr(NH₃)₈] [CO(CN)₆] is_______.

(a)

Geometrical

(b)

Coordination

(c)

linkage

(d)

ionisation

Pick out the central metal ion in the complex K₃[AI(C₂O₄)₃].

(a)

3K⁺

(b)

Al³⁺

(c)

C₂O₄^2-

(d)

both (a) and (b)

According to IUPAC, No is _________.

(a)

nitro

(b)

nitrosyl

(c)

nitrato

(d)

nitrito

______is used as an antitumor drug in cancer treatment.

(a)

Ca - EDTA

(b)

Cis - platin

(c)

Sodium thio sulphate

(d)

Nickel chloride

Crystal field stabilization energy for high spin d⁴ octahedral complex is ______.

(a)

- 0. 6 \({ \triangle }_{ 0 }\)

(b)

- 1. 8 \({ \triangle }_{ 0 }\)

(c)

- 1. 6 \({ \triangle }_{ 0 }\)

(d)

- 1. 4 \({ \triangle }_{ 0 }\)

The chemical formula for diammine silver (I) chloride is _______.

(a)

[Ag(NH₃)₂] Cl

(b)

[Ag(NH₃)]Cl

(c)

[Ag(NH₂)₂]Cl

(d)

[Ag(NH₄)₂]Cl

The oxidation state of the central metal ion in the complex [Co(H₂O)(CN)(en)₂]²⁺ is________.

(a)

0

(b)

+1

(c)

+2

(d)

+3