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Hydroxy Compounds and Ethers Three Marks Questions

12th Standard

    Reg.No. :
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Chemistry

Time : 01:00:00 Hrs
Total Marks : 40
    8 x 5 = 40
  1. What will be the product (X and A) for the following reaction acetylchloride \(\frac{\text { i) } \mathrm{CH}_{3} \mathrm{MgBr}}{\text { ii) } \mathrm{H}_{3} \mathrm{O}^{+}}{\longrightarrow} \mathrm{X} \stackrel{\text { acid } \mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}}{\longrightarrow}\) 

  2. How will you convert acetylene into n-butyl alcohol.

  3. Predict the product A,B,X and Y in the following sequence of reaction

  4. Complete the following reactions

    ii) \(C_6H_5-CH_{2}CH(OH)CH(CH_3)_2 \overset{ConH_2SO_4}\longrightarrow\)

  5. Phenol is distilled with Zn dust followed by friedel – crafts alkylation with prophyl chloride to give a compound B, B on oxidation gives (c) Indentify A,B and C.


  6. Identify A,B,C,D and write the complete equation

  7. Complete the following reactions 
    i) CH3- CH2 - OH \(\overset { { P}{ Br_3 }{ } }{ \underset { {} }{ \longrightarrow } }\)  A  \(\overset { { aq.NaOH}{ }{ } }{ \underset { {} }{ \longrightarrow } }\) B \(\overset { { Na}{ } }{ \underset { {} }{ \longrightarrow } }\) C
    ii) C6H5- OH  \(\overset { { Zn \ dust}{ } }{ \underset { {} }{ \longrightarrow } }\) A \(\overset { { CH_3}{Cl}{ } }{ \underset { {Anhydrs}{AlCl_3} }{ \longrightarrow } }\) B \(\overset { { acid}{K MnO_4}{ } }{ \underset { {} }{ \longrightarrow } }\) C

  8. 0.44g of a monohydric alcohol when added to methyl magnesium iodide in ether liberates at STP 112 cm3 of methane with PCC the same alcohol form a carbonyl compound that answers silver mirror test. Identify the compound.

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