Duralumin is an alloy of ______.

(a)

Cu,Mn

(b)

Cu,Al,Mg

(c)

Al,Mn

(d)

Al,Cu,Mn,Mg

On hydrolysis, PCl₃ gives________.

(a)

H₃PO₃

(b)

PH₃

(c)

H₃PO₄

(d)

POCl₃

Most easily liquefiable gas is _______.

(a)

Ar

(b)

Ne

(c)

He

(d)

Kr

In acid medium, potassium permanganate oxidizes oxalic acid to _______.

(a)

oxalate

(b)

Carbon dioxide

(c)

acetate

(d)

acetic acid

Which one of the following is not correct?

(a)

La(OH)₃ is less basic than Lu(OH)₃

(b)

In lanthanoid series ionic radius of Ln³⁺ ions decreases

(c)

La is actually an element of transition metal series rather than lanthanide series

(d)

Atomic radii of Zr and Hf are same because of lanthanide contract

Choose the correct statement.

(a)

Square planar complexes are more stable than octahedral complexes

(b)

The spin only magnetic moment of [Cu(Cl)₄]^2- is BM and it has square planar structure.

(c)

Crystal field splitting energy \(\left( { \Delta }_{ 0 } \right) \) [FeF₆]^4- is higher than the \((\Delta _{ 0 })\) of [Fe(CN)₆]^4- 

(d)

crystal field stabilization energy of [V(H₂O)₆]²⁺ is higher than the crystal field stabilization of [Ti(H₂O)₆]²⁺

CsCl has bcc arrangement, its unit cell edge length is 400pm, its inter atomic distance is ________.

(a)

400pm

(b)

800pm

(c)

\(\sqrt { 3 } \times 100pm\)

(d)

\(\left( \frac { \sqrt { 3 } }{ 2 } \right) \times 400pm\)

For a first order reaction A ⟶ product with initial concentration x mol L^-1, has a half life period of 2.5 hours. For the same reaction with initial concentration \(\left( \frac { x }{ 2 } \right) \) mol L^-1 the half life is

(a)

(2.5 x 2) hours

(b)

\(\left( \frac { 2.5 }{ 2 } \right) \) hours

(c)

2.5 hours

(d)

Without knowing the rate constant, t_1/2 cannot be determined from the given data

In a homogeneous reaction A⟶B+C+D, the initial pressure was P₀ and after time t it was P expression for rate constant in terms of P₀, P and t will be _____.

(a)

\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 2{ P }_{ 0 } }{ { 3P }_{ 0 }-P } \right) \)

(b)

\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { { 2P }_{ 0 } }{ { P }_{ 0 }-P } \right) \)

(c)

\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 3{ P }_{ 0 }-P }{ 2P_{ 0 } } \right) \)

(d)

\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 2{ P }_{ 0 } }{ { 3P }_{ 0 }-2P } \right) \)

The solubility of BaSO₄ in water is 2.42 × 10^-3gL^-1 at 298K. The value of its solubility product(K_sp) will be (Given molar mass of BaSO₄ =233g mol^-1)

(a)

1.08 × 10^-14mol²L^-2

(b)

1.08 × 10^-12mol²L^-2

(c)

1.08 × 10^-10mol²L^-2

(d)

1.08 × 10^-8mol²L^-2

Electrolyte	KCl	KNO3	HCl	NaOAC	NaCl
Λ- (Scm2 mol-1)	149.9	145.0	426.2	91.0	126.5

Calculate Λ^o_HoAC using appropriate molar conductances of the electrolytes listed above at infinite dilution in water at 25^oC_______.

(a)

517.2

(b)

552.7

(c)

390.7

(d)

217.5

The equivalent conductance of M/36 solution of a weak monobasic acid is 6 mho cm² equivalent^-1 and at infinite dilution is 400 mho cm² equivalent^-1. The dissociation constant of this acid is ______.

(a)

1.25 x 10⁻⁶

(b)

6.25 x 10^-6

(c)

1.25 x 10⁻⁴

(d)

6.25 x 10 ^-5

On which of the following properties does the coagulating power of an ion depend?

(a)

Both magnitude and sign of the charge on the ion.

(b)

Size of the ion alone

(c)

the magnitude of the charge on the ion alone

(d)

the sign of charge on the ion alone.

The correct IUPAC name of the compound

(a)

4 – chloro – 2,3 – dimethyl pentan – 1-ol

(b)

2,3 – dimethyl – 4- chloropentan -1-ol

(c)

2,3,4 – trimethyl – 4- chlorobutan -1-ol

(d)

4– chloro – 2,3,4 – trimethyl pentan – 1-ol

Assertion: Phenol is more reactive than benzene towards electrophilic substitution reaction
Reason: In the case of phenol, the intermediate arenium ion is more stabilized by resonance
Codes:
a) if both assertion and reason are true and reason is the correct explanation of assertion.
b) if both assertion and reason are true but reason is not the correct explanation of assertion.
c) assertion is true but reason is false
d) both assertion and reason are false.

(a)

if both assertion and reason are true and reason is the correct explanation of assertion.

(b)

if both assertion and reason are true but reason is not the correct explanation of assertion.

(c)

assertion is true but reason is false

(d)

both assertion and reason are false.

Among the following ethers which one will produce methyl alcohol on treatment with hot HI?

(a)

(H₃C)₃C-O-CH₃

(b)

(CH₃-)₂-CH-CH₂-O-CH₃

(c)

CH₃-(CH₂)₃-O-CH₃

(d)

CH₃-CH₂-\(\underset { \overset { | }{ { CH }_{ 3 } } }{ CH } \)-O-CH₃

The ionization constant of phenol is higher than that of ethanol because ______.

(a)

phenoxide ion is bulkier than ethoxide

(b)

phenoxide ion is stronger base than ethoxide.

(c)

phenoxide ion is stablized through delocalisation.

(d)

phenoxide ion is less stable than ethoxide ion.

Compound of molecular formula C₇H₈O is a sweet smeeling liquid. A on reaction with acidified K₂Cr₂O₇ gives compound B of molecular formula C₇H₈O. B reduces Tollen's reagent A and B are respectively.

(a)

benzaldelyde and benzoic acid

(b)

Methyl phenykarbinol and acetophenone

(c)

benzyl alcohol and benzaldehyde

(d)

diphenyl carbinol and benzophenone

CH₂ = CH₂+H₂O  The above reaction is _______.

(a)

Lucas test

(b)

Saponification

(c)

Victor Meyer's test

(d)

hydroxylation

Ethers in the presence of atmospheric oxygen oxidises to give hydroperoxides and dialkyl peroxides Such a spontaneous reaction by atmospheric oxygen is called ______.

(a)

auto oxidation

(b)

acylation

(c)

alkylation

(d)

dehydration

Formation of o and p - hydroxy benzaldehyde from phenol on treatment with CHCl₃ and NaOH is _______.

(a)

Riemer-Tiemann reaction

(b)

Kolbe's reaction

(c)

Coupling reaction

(d)

Hydrogenation

When phenol reacts with CCl₄ and NaOH, the product formed is ________ acid.

(a)

salicylic

(b)

cinnamic

(c)

benzoic

(d)

carboxylic

The formation of cyanohydrin from acetone is an example of _______.

(a)

nucleophilic substitution

(b)

electrophilic substitution

(c)

electrophilic addition

(d)

Nucleophilic addition

The IUPAC name of 

(a)

but – 3- enoicacid

(b)

but – 1- ene-4-oic acid

(c)

but – 2- ene-1-oic acid

(d)

but -3-ene-1-oicacid

In aqueous solution of amino acids mostly exists in ______.

(a)

NH₂-CH(R)-COOH

(b)

NH₂-CH(R)-COO^-

(c)

H₃N⁺-CH(R)-COOH

(d)

H₃N⁺-CH(R)-COO^-