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12th Standard English Medium Chemistry Subject Carbonyl Compounds Creative 5 Mark Questions with Solution Part - II

12th Standard

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Chemistry

Time : 00:30:00 Hrs
Total Marks : 25
    5 x 5 = 25
  1. Compound (A) with molecular formula C2H4O reduces Tollen's reagent. (A) On treatment with HCN gives compound (B). Compound (B) on hydrolysis with an acid gives compound (C) with molecular formula C3H6O3 which is an optically active compound. Compound (A) on reduction with N2H/C2HsONa gives a hydrocarbon (D) of molecular formula C2H6. Identify (A), (B), (C) and (D) and explain the reactions.

  2. An organic compound (A) of molecular formula C7H6O is called as oil of bitter almonds. (A) on oxidation gives (B) of molecular formula C7H6O2 which gives brisk effervescence with NaHCO3 solution. When (A) is refluxed with aqueous alcoholic (KCN) compound (C) is formed. Identify A, B and C and write the equations.

  3. Ail organic compound. (A) C7H6O reduces Tollens reagent. Compound (A) reacts with acetic anhydride in the presence of anhydrous sodium acetate and gives an unsaturated acid (B). Compound (A) reacts with acetone in the presence of alkali and gives (C). What are (A)(B) and (C) Explain the reactions.

  4. An organic compound Aofmolecular formula C3H6O answers iodoform test. Another organic compound B of molecular formula C7H6O is known as oil of bitter almonds. A reacts with B to form an unsaturated compound C of molecular formula C10H10O. Compound B reacts with malonic acid in the presence of pyridine to form an unsaturated acid D of molecular formula C9H5O2 Identify A, B, C and D. Explain the reactions.

  5. Compound (A) with Molecular formula C7H6O does not reduce Fehling's solution. Compound (A) reacts with acetone in the presence of NaOH to give a compound (B) which is an α, β-unsaturated compound. Further (A) reacts with dimethyl aniline in the presence of cone, H2SO4 to give compound (C) which is a dye. Identify (A) (B) and (C). Explain the reactions.

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