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Published on: 12/06/2021
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Questions + Answers key
Take MCQ Science Test1.
What is the pH of 1.0 × 10–5 molar solution of KOH?
2.
Lemon juice has a pH 2, what is the concentration of H+ ions?
3.
Calculate the pH of a solution in which the concentration of the hydrogen ions is 1.0 × 10–8 mol litre–1
4.
What would be the pH of an aqueous solution of sulphuric acid which is 5 × 10–5 mol litre–1 in concentration.
5.
A solid compound ‘A’ decomposes on heating into ‘B’ and a gas ‘C’. On passing the gas ‘C’ through water, it becomes acidic. Identify A, B and C.
1.
KOH is a strong base and dissolve in water and gives
\(\mathrm{KOH_{(aq)}} \rightarrow \mathrm{K}^{+}_{(s)}+\mathrm{OH}^{-}_{(aq)}\)
Each KOH molecules gives one OH- ion. So 1.0 x 10-5 molar molar solution of KOH gives 1.0 x 10-5 OH- ions.
\({\left[\mathrm{OH}^{-}\right] } =1.0 \times 10^{-5} \)
\(\mathrm{pOH} =-\log _{10}\left[\mathrm{OH}^{-}\right] \)
\(=-\log _{10} 1.0 \times 10^{-5} \)
\(=-(-5) \log _{10} 10 \)
\(\mathrm{pOH} =5 \times 1 \)
\(\mathrm{pOH} =5 \)
\(\mathrm{pH}+\mathrm{pOH} =14 \)
\(\mathrm{pH} =14-\mathrm{pOH} \)
=14 - 5
pH = 9
The pH of 1.0 x10-5 molar solution of KOH is 9.
2.
Concentration of hydrogen ion H+ = 10-pH M
Concentration of hydrogen ion in lemon juice = 10-2 M
= 0.01 M
Concentration of lemon juice is 0.01 M
3.
Here, although the solution is extremely dilute, the concentration given is not of an acid or a base but that of H+ ions. Hence, the pH can be calculated from the relation:
pH = –log10[H+]
given [H+] = 1.0 × 10–8 mol litre–1
pH = –log1010–8 = –(–8 × log1010)
= –(–8 × 1) = 8
4.
Sulphuric acid dissociates in water as:
H2SO4(aq) → 2 H+(aq) + SO42-(aq)
Each mole of sulphuric acid gives two mole of H+ ions in the solution. One litre of H2SO4 solution contains 5 × 10–5 moles of H2SO4 which would give 2 × 5 × 10–5 = 10 × 10–5 or 1.0 × 10–4 moles of H+ ion in one litre of the solution.
Therefore,
[H+] = 1.0 × 10–4 mol litre–1
pH = –log10[H+] = –log1010–4 = –(–4 × log1010)
= –(–4 × 1) = 4
5.
(i) On passing ' C ' through water it becomes acidic.
(ii) Therefore the gas ' C ' must be a non-metal oxide \(\left(\mathrm{CO}_{2}\right)\).
(iii) So a solid compound must be a calcium carbonate.
(iv) It decomposes into calcium oxide and carbon dioxide. (C)
\(\mathrm{CaCO}_{3(\mathrm{~g})} \rightarrow \mathrm{CaO}_{(\mathrm{S})}+\mathrm{CO}_{2(\mathrm{~g})} \uparrow\\ \quad \mathrm{A} \quad \quad \quad \quad \mathrm{B} \quad \quad \quad \quad \mathrm{C}\)
| A | CaCo3 | Calcium carbonate |
| B | CaO | Calcium oxide |
| C | CO2 | Carbon di oxide |
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