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Published on: 25/10/2025
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1.
Arrange the following in order of increasing acidity
A. o-nitrobenzoic acid
B. p-nitrobenzoic acid
C. p-hydroxybenzoic acid
D. benzoic acid
A < B < C < D
B < C < A < D
C < B < D < A
C < D < B < A
2.
Of the following which is the product formed when cyclohexanone undergoes aldol condensation followed by heating?




3.
Among the following amines, the strongest Bronsted base is _____________

NH3


4.
The order of basic strength of amines in aqueous solution is
(CH3)3N > (CH3)2NH > CH3NH2 > NH3
CH3NH2 > (CH3)2 NH > (CH3)3 > H3
NH3 > (CH3)3N > (CH3)2NH > CH3NH2
(CH3)2NH > CH3NH2 > (CH3)3N > NH3
5.
Benzene diazonium chloride when reacts with hypophosphorus acid produces
Benzene
Phenol
Phenol isocyanide
Phenyl phosphate
6.
Hardness of water is estimated by simple titration with Na2 - EDTA because
Ca2+ ions form stable complexes with EDTA
Mg2+ ions form stable complexes with EDTA
Ca2+ions form unstable complexes with EDTA
Both (a) and (b)
7.
Which of the following compounds is used as the starting material for the preparation of potassium dichromate?
K2SO4 . Cr2(SO4)3.24H2O(chrome alum)
PbCrO4(chromite yellow)
FeCr2O4 (chromite)
PbCrO4. PbO(chrome red)
8.
The variability of oxidation state
is a characteristic of transition elements
arises out of incomplete filling of d-orbitals in such a way that their oxidation states differ from each other by unity
differs from the variability of oxidation states of non-transition elements, where the oxidation states normally differ by two unit.
All of the above are true
9.
What reagent is used in Hinsberge test of amines?
(CH3CO)2O and pyridine
C6H5SO2CI in aq.NaOH
NaNO2 in aq.H2SO4
CH3I (excess) followed by AgOH
10.
Positive carbylamine test is shown by
N, N-dimethylaniline
triethylamine
N-methylaniline
p-methylbenzylamine
dimethylamine
11.
On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is
alkyl isocyanide
an alkanol
an alkanediol
an alkyl cyanide
12.
The total number of structural isomers possible for an amine with molecular formula C4H11N is
6
5
7
4
8
13.
Through which of the following reactions number of carbon atoms can be increased in the chain ?
Grignard reaction
Cannizzaro's reaction
Aldol condensation
HVZ reaction
14.
The correct order of increasing acidic strength is ________________.
Phenol
Ethanol
Ethanol
Chloroacetic acid
15.
Mohr salt, FeSO4, (NH4)2SO4. 6 H2 O, is preferred over FeSO4. 7 H2O for standardization of KMnO4 solution because.
Mohr salt is a double salt while ferrous sulphate is a single salt.
Mohr salt is not hygroscopic but FeSO4. 7 H2O is hygroscopic
Mohr salt contains only ferrous ions whereas ferrous sulphate contains some ferric ions.
Mohr salt solution can be titrated even in the absence of H2SO4
16.
In the nitration of benzene using a mixture of conc. H2SO4 and conc.HNO3, the species which initiates the reaction is......................... .
NO2
NO+
\({ NO }_{ 2 }^{ + }\)
\({ NO }_{ 2 }^{ - }\)
17.
A red solid is insoluble in water. However, it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is
HgI2
HgO
Pb3O4
(NH4)2 Cr2O7
18.
Reason of lanthanoid contraction is
negligible screening effect of 'f' - orbitals
increasing nuclear charge
decreasing nuclear charge
decreasing screening effect
19.
The coloured spot of KMnO4 on any article can be bleached by
SO2 + H+
C2\({ O }_{ 4 }^{ 2- }\) + H+
H2O2 + H+
all of these
20.
When manganous salt is fused with a mixture of KNO3 and solid NaOH, the oxidation number of Mn changes from +2 to
+4
+3
+6
+7
21.
Among the oxides, Mn2O7 (I), V2O3(II),V2O5 (III),CrO (IV) and Cr2O3 (V), the basic oxides are
I and II
II and III
III and IV
II and IV
III and V
22.
Propinic acid with Br2/P yields a dibromo product. Its structure would be
CHBr2 _ CH2COOH
CH2Br _ CH2COBr
CH3 _ CBr2 _ COOH
CH2Br _ CHBr _ COOH
23.
Among the followig compounds, the one(s) that gives effervescence with aqueous NaHCO3 solution is (are)
I. (CH3CO)2O
II. CH3COOH
III. PhOH
IV. CH3COCHO
I and II
I and III
only II
I and IV
24.
Identify the optically active compounds from the following :
\([Co(en)_3]^{3+}\)
\(trans-[Co(en)_2Cl_2]^{+}\)
\(cis-[Co(en)_2Cl_2]^+\)
\([Cr(NH_3)_5Cl]\)
25.
Which of the following complexes are heteroleptic ?
\([Cr(NH_3)_6]^{3+}\)
\([Co(NH_3)_4Cl_2]^+\)
\([Ni(CN)_4]^{2-}\)
\([Ni(NH_3)_4Cl_2]\)
26.
Which of the following complexes are homoleptic ?
\([Co(NH_3)_6]^{3+}\)
\([Co(NH_3)_4Cl_2]^+\)
\([Ni(CN)_4]^{2-}\)
\([Ni(NH_3)_4Cl_2]\)
27.
A coordination complex compound of cobalt has the molecular formula containing four ammonia molecules, one nitro group and two chlorine atoms. A solution of this complex was prepared by dissolving 2.44 g of it in water and making the volume to 200 mL. Excess of AgNO3 solution was then added to it and the precipitate of AgCl formed was filtered and dried. The weight of AgCl thus obtained was found to be 1.435 g (Atomic mass of Co = 59, Ag = 108]
The formula of the complex would be
[Co(NH3)4(NO2)]Cl2
[Co(NH3)4Cl(NO2)]Cl
[Co(NH3)4Cl2]NO2
[Co(NH3)4Cl2(NO2)]
28.
Which one of the following is a homoleptic complex?
tris(ethane-1, 2-diamine) cobalt (III) chloride
triamminetriaquachromium (III) chloride
diamminechloridonitro-N-Platinum(II)
dichlorido bis(ethane-1, 2-diamine ) cobalt(III)
pentaamminecarbonato cobalt (III) chloride
29.
Which of the following is an outer orbital complex?
[Fe(CN)6]4-
[FeF6]3-
[Co(NH3)6]3+
[Co(CN)6]2+
30.
KMnO4, oxidation number of Mn is
+ 2
+ 4
+ 6
+ 7
1.
(d)
C < D < B < A
2.
(a)

3.
(d)

4.
(d)
(CH3)2NH > CH3NH2 > (CH3)3N > NH3
5.
(a)
Benzene
6.
(d)
Both (a) and (b)
7.
(c)
FeCr2O4 (chromite)
8.
(d)
All of the above are true
9.
(b)
C6H5SO2CI in aq.NaOH
10.
Only \({ 1 }^{ \circ }\) amines, i.e., p-methylbenzylamine, (p) CH3-C6H4-CH2NH2, give carbylamine test.
11.
In carbylamine reaction, alkyl isocyanides are formed.
12.
(e)
8
13.
(c)
Aldol condensation
14.
(c)
Ethanol
15.
(c)
Mohr salt contains only ferrous ions whereas ferrous sulphate contains some ferric ions.
16.
(c)
\({ NO }_{ 2 }^{ + }\)
17.
(a)
HgI2
18.
(a)
negligible screening effect of 'f' - orbitals
19.
(d)
all of these
20.
(c)
+6
21.
(d)
II and IV
22.
(c)
CH3 _ CBr2 _ COOH
23.
(a)
I and II
24.
(a)
\([Co(en)_3]^{3+}\)
25.
(b)
\([Co(NH_3)_4Cl_2]^+\)
26.
(a)
\([Co(NH_3)_6]^{3+}\)
27.
(b)
[Co(NH3)4Cl(NO2)]Cl
28.
(a)
tris(ethane-1, 2-diamine) cobalt (III) chloride
29.
(b)
[FeF6]3-
30.
(d)
+ 7
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