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Published on: 02/09/2022
QB365 provides a detailed and simple solution for every Possible Creative Questions in Class 12 Chemistry Subject - Electro Chemistry, English Medium. It will help Students to get more practice questions, Students can Practice these question papers in addition to score best marks.
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Questions + Answers key
Take MCQ Chemistry Test

1.
Express Kohlrausch's law for molar conductance of a uni - univalent electrolyte NaCl
2.
Give the expression that relates molar conductivity and degree of dissociation.
3.
On dilution of 0.1 M of Na2SO4, what will happen to its
(a) Conductance (C)
(b) Conductivity K
(c) Molar conductance \({ \Lambda }_{ m }\)
(d) Equivalent conductance \({ \Lambda }\)
4.
Molar conductivity increases with dilution. Is the above statement true? Justify your answer
5.
Account for the following : For a strong electrolyte molar conductivity decreases as concentration increases
6.
Give the empirical relationship between molar conductance and concentration of the electrolyte.
7.
For a uni - univalent electrolyte write the Debye - Huckel Onsager equation
8.
Derive the unit of specific conductance.
9.
Give a mathematical expression that relates I cell constant, specific conductance and specific resistance.
10.
Define specific conductance
11.
Define conductance. Give its unit
12.
Two electrodes having cross sectional area of l A and are separated by a distance l. What is the ratio of length by area called?
13.
Define resistivity
14.
Define resistance. Give its mathematical expression
15.
Give the mathematical expression of ohm's law.
1.
For a uni - univalent electrolyte such as NaCl, the Kohlrausch's law is expressed as
\({ ({ \Lambda }_{ m }^{ o }) }_{ NaCl }=({ { \lambda }_{ m }^{ o })_{ { Na }^{ + } }+{ ({ \lambda }_{ m }^{ o }) }_{ { Cl }^{ - } } }\)
2.
\(\alpha =\frac { { \Lambda }_{ m } }{ { \Lambda }_{ m }^{ o } } \)
3.
Conductivity, molar conductance and equivalent conductance increases with dilution whereas Conductance (C) decreases.
4.
Yes, the above given statement is true.
When the dilution increases, the ions are far apart and the attractive forces decrease. At infinite dilution the ions are so far apart, the interaction between them becomes insignificant and hence, the molar conductivity increases and reaches a maximum value at infinite dilution
5.
(i) For a strong electrolyte, at high concentration, the number of constituent ions of the electrolyte in a given volume is high and hence the attractive force between the oppositely charged ions is also high.
(ii) Moreover the ions also experience a viscous drag due to greater solvation.
(iii) These factors attribute for the low molar conductivity at high concentration.
6.
Kohlrausch deduced the following empirical relationship between the molar conductance (\({ \Lambda }_{ m }\)) and the concentration of the electrolyte (C).
\({ \Lambda }_{ m }={ \Lambda }_{ m }^{ o }-k\sqrt { C } \)
7.
\({ \Lambda }_{ m }={ \Lambda }_{ m }^{ o }-(-A+B{ \Lambda }_{ m }^{ o })\sqrt { C } \)
8.
Unit of x
\(k=\frac { 1 }{ \rho } .\frac { l }{ A } \left( \frac { 1 }{ ohm } .\frac { m }{ { m }^{ 2 } } \right) \)
= ohm-1 m-1 = mho m-1 (or) Sm-1
9.
k = \(\frac{1}{R}.\frac{1}{a}=\frac{1}{ρ}\)
Where K is specific conductance
R is resistance and \(\frac1a\) is cell constant.
ρ is specific resistance.
10.
The specific conductance is defined as the conductance of a cube of an electrolytic solution of unit dimensions.
11.
The reciprocal of the resistance \((\frac{l}{R})\) gives the conductance of an electrolytic solution. The SI unit of conductance is Siemen (S).
12.
The ratio \((\frac{l}{A})\) is called the cell constant.
13.
Resistivity is defined as the resistance of an electrolyte confined between to electrodes having unit cross sectional area and are separated by a unit distance. The ratio \((\frac{l}{A})\) is called the cell constant, Unit of resistivity is ohm metre (Ωm).
14.
The resistance of such an electrolytic solution is also directly proportional to the length (l) and inversely proportional to the cross sectional area (A)
R α \(\frac{l}{A}\)
R = ρ \(\frac{l}{A}\)
15.
i.e., I α V (or) I = \(\frac{V}{R}\) ⇒ V = IR
Where 'R' is the resistance of the solution in ohm (Ω)
Here the resistance is the opposition that a cell offers to the flow of electric current through it.
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