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Published on: 13/10/2020
12th Standard Chemistry English Medium Free Online Test 1 Mark Questions 2020
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Which of the following amino acids are achiral?
Alanine
Leucine
Proline
Glycine
2.
_______.
3.
Carbolic acid is _____.
Phenol
Picri cacid
benzoic acid
phenylacetic acid
4.
Which one of the following is an example for homogeneous catalysis?
manufacture of ammonia by Haber’s process
manufacture of sulphuric acid by contact process
hydrogenation of oil
Hydrolysis of sucrose in presence of all HCl
5.
Which of the following relation is correct for degree of hydrolysis of ammonium acetate?
\(h=\sqrt { \frac { { K }_{ h } }{ C } } \)
\(h=\sqrt { \frac { { K }_{ a } }{ K_b } } \)
\(h=\sqrt { \frac { { K }_{ w } }{ { K }_{ a }.{ K }_{ b } } } \)
\(h=\sqrt { \frac { { { K }_{ a }.{ K }_{ b } } }{ { K }_{ w } } } \)
6.
Which will make basic buffer?
50 mL of 0.1M NaOH+25mL of 0.1M CH3COOH
100 mL of 0.1M CH3COOH+100 mL of 0.1M NH4OH
100 mL of 0.1M HCl+200 mL of 0.1M NH4OH
100 mL of 0.1M HCl+100 mL of 0.1M NaOH
7.
A binary solid A+B has a structure with B- ions constituting the lattice and A+ ions occupying 25% tetrahedral holes. Formula of the solid is _______.
A2B
AB2
AB
AB4
8.
Coinage metals are _______.
normal metals
transition metals
active metals
alkali metals
9.
Which of the following is incorrect with respect to metallurgy of iron in the blast furnace?
Zone of combustion : \(C+{ O }_{ 2 }\rightarrow { CO }_{ 2 }\)
Zone of heat absorption : \({ CO }_{ 2 }\rightarrow C+{ O }_{ 2 }\)
Zone of slag formation : \(CaO+{ SiO }_{ 2 }\rightarrow CaSiO_{ 3 }\)
Zone of reduction : \({ Fe }_{ 2 }{ O }_{ 3 }3C\rightarrow 3CO+2Fe\)
10.
Phthalo blue - a bright blue figment is a complex of _______.
Copper (I) ion
Copper (II) ion
Nickel (II) ion
Nickel (IV) ion
11.
The geometry of [Ni(CN)4]2- is _______.
Tetrahedral
Square planar
Triangular
Octahedral
12.
In a homogeneous reaction A⟶B+C+D, the initial pressure was P0 and after time t it was P expression for rate constant in terms of P0, P and t will be _____.
\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 2{ P }_{ 0 } }{ { 3P }_{ 0 }-P } \right) \)
\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { { 2P }_{ 0 } }{ { P }_{ 0 }-P } \right) \)
\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 3{ P }_{ 0 }-P }{ 2P_{ 0 } } \right) \)
\(k=\left( \frac { 2.303 }{ t } \right) \log\left( \frac { 2{ P }_{ 0 } }{ { 3P }_{ 0 }-2P } \right) \)
13.
In a reversible reaction, the enthalpy change and the activation energy in the forward direction are respectively −x kJ mol-1 and y kJ mol-1. Therefore, the energy of activation in the backward direction is _______.
(y-x) kJ mol-1
(x+y) J mol-1
(x-y) KJ mol-1
(x+y) x 103J mol-1
14.
The crystal with a metal deficiency defect is ________.
NaCl
FeO
ZnO
KCl
15.
If ‘a’ stands for the edge length of the cubic system sc, bcc, and fcc. Then the ratio of radii of spheres in these systems will be respectively ________.
\(\left( \frac { 1 }{ 2 } a;\frac { \sqrt { 3 } }{ 2 } a;\frac { \sqrt { 2 } }{ 2 } a \right) \)
\(\left( \sqrt { 1a } :\sqrt { 3a } :\sqrt { 2a } \right) \)
\(\left( \frac { 1 }{ 2 } a:\frac { \sqrt { 3 } }{ 4 } a:\frac { 1 }{ 2\sqrt { 2 } } a \right) \)
\(\frac { 1 }{ 2 } a:\sqrt { 3 } a:\frac { 1 }{ \sqrt { 2 } } a\)
16.
The ratio of close packed atoms to tetrahedral hole in cubic packing is ________.
1:1
1:2
2:1
1:4
17.
Which one of the following pairs represents linkage isomers?
[Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]
[Co(NH3)5(NO3)]SO4 and [Co(NH3)5(ONO)]
[Co(NH3)4(NCS)2]Cl and [Co(NH3)4(SCN)2]Cl
both (b) and (c)
18.
An excess of silver nitrate is added to 100ml of a 0.01M solution of Pentaaquachlorochromium (III)chloride. The number of moles of AgCl precipitated would be _______.
0.02
0.002
0.01
0.2
19.
The magnetic moment of Mn2+ ion is _______.
5.92BM
2.80BM
8.95BM
3.90BM
20.
The geometry at which carbon atom in diamond are bonded to each other is _______.
Tetrahedral
hexagonal
Octahedral
none of these
21.
The basicity of pyrophosphorous acid ( H4P2O5) is _______.
4
2
3
5
22.
An element belongs to group 15 and 3rd period of the periodic table, its electronic configuration would be_______.
1s2 2s2 2p4
1s2 2s2 2p3
1s2 2s2 2p6 3s2 3p2
1s2 2s2 2p6 3s2 3p3
23.
Which of the following metals has the largest abundance in the earth’s crust?
Aluminium
Calcium
Magnesium
Sodium
24.
The incorrect statement among the following is______.
Nickel is refined by Mond’s process
Titanium is refined by Van Arkel’s process
Zinc blende is concentrated by froth floatation
In the metallurgy of gold, the metal is leached with dilute sodium chloride solution
25.
Wolframite ore is separated from tinstone by the process of________.
Smelting
Calcination
Roasting
Electromagnetic separation
1.
(d)
Glycine
2.
3.
(a)
Phenol
4.
(d)
Hydrolysis of sucrose in presence of all HCl
5.
(c)
\(h=\sqrt { \frac { { K }_{ w } }{ { K }_{ a }.{ K }_{ b } } } \)
6.
Basic buffer is the solution which has weak base and its salt.
NH4OH + HCI → NH4CI +H2O + NH4OH
200 ml 100 ml salt 100 ml weak base
7.
(b)
AB2
8.
(b)
transition metals
9.
(b)
Zone of heat absorption : \({ CO }_{ 2 }\rightarrow C+{ O }_{ 2 }\)
10.
(b)
Copper (II) ion
11.
(b)
Square planar
12.
| A | ⟶ | B | C | D | |
| Initial rate (M s-1) | a | 0 | 0 | 0 | |
| Reaction number | x | - | - | - | - |
| After time t | (a - x) | x | x | x | |
| Total number of moles | = (a + 2x) |
13.
14.
(b)
FeO
15.
sc ⇒ 2r = a
⇒ r = a/2
bcc ⇒ 4r = \( \sqrt{3a} \) ⇒ r = \(\frac { \sqrt{3a}} {4}\)
fcc ⇒ 4r ⇒ \( \sqrt{2a} \) ⇒ r = \(\frac { \sqrt{2a}} {4} = \frac { a} {2\sqrt{2a}}\)
\(\left( \frac { a }{ 2 } :\frac { \sqrt { 3 } }{ 4 } a:\frac { a }{ 2\sqrt { 2 } } \right) \)
16.
If number of close packed atoms = N, then
The number of Tetrahedral holes formed = 2N
The number of Octahedral holes formed = N
Therefore, N:2N = 1:2
17.
(a) coordination isomers
(b) no isomerism ( different molecular formula)
(c)⬅NCS; ⬅SCN coordinating atom differs : linkage isomers
18.
The complex is [M(H2O)5Cl]Cl2
1000 ml of 1 M solution of the complex gives 2 moles of Cl- ions 1000 ml of 0.01 M solution of the complex will give
\(\frac{100 ml \times 0.01M \times 2Cl^-}{1000 ml \times 1M}\)
= 0.002 moles of Cl- ions
19.
Mn2+ ⇒ 3d5 contains 5 unpaired electrons
n = 5,
\( \sqrt{n(n+ 2)} \) BM
\(= \sqrt{5(5+ 2)} = \sqrt{35} = 5.92 BM\)
20.
(a)
Tetrahedral
21.
(b)
2
22.
(d)
1s2 2s2 2p6 3s2 3p3
23.
(a)
Aluminium
24.
(d)
In the metallurgy of gold, the metal is leached with dilute sodium chloride solution
25.
(d)
Electromagnetic separation
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