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Published on: 02/09/2022
QB365 provides a detailed and simple solution for every Possible Creative Questions in Class 12 Chemistry Subject - Solid State, English Medium. It will help Students to get more practice questions, Students can Practice these question papers in addition to score best marks.
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Take MCQ Chemistry Test

1.
Define the term: space lattice.
2.
Aluminium crystallises in a fee structure. Atomic radius of the metal is 125 pm. What is the length of the side of the unit cell of the metal?
3.
Diamond and solid rhombic sulphur are covalent solids but the latter has very low melting point than the former. Explain why?
4.
What is point defect in crystals?
5.
Define void.
6.
Define the term amorphous.
7.
Which point effect in crystal doesn't alter the density of the relevant solid?
8.
Name an element with which silicon can be doped to give an n-type semi conductor.
9.
What is the total number of atoms per unit cell in a face - centered cubic structure (fcc)?
10.
What type of defect can arise when a solid is heated? Which physical property is affected by it and in what way?
11.
Distinguish between : Face - centred and body - centred unit cells.
12.
Ionic solids conduct electricity in molten state but not in solid state. Explain.
13.
What type of stoichiometric defect is shown by ZnS.
14.
Classify the following as amorphous or crystalline solids. Polyurethane, Naphthalene, Benzoic acid, Teflon, Potassium nitrate, Cellophane, Polyvinyl chloride, Fiber glass, Copper.
15.
Why do solids have a definite volume?
1.
Space Lattice:
An infinite three dimensional array of points showing how atoms (or) molecules are arranged in a crystal is known as space lattice. The points are known as lattice points.
2.
The length of the side of the unit cell of the metal is 353.55 pm.
For fee unit cell, a =(2√2) x r
= 2 x 1.414 x 125
= 353.55pm.
3.
(I) Diamond has network structure, while sulphur does not.
(II) Due to this, particles of carbon are held at their positions firmly which makes diamond hard, brittle with extremely high melting point.
4.
The defects which are caused by missing or misplaced atoms or ions in the crystal.
5.
The empty spaces present between the metal atom or the ions when they are packed within the crystal are called voids.
6.
A solid is said to be amorphous if its constituent particles are not arranged in a regular fashion
7.
Frenkel defect
8.
Gallium.
9.
Total number of atoms per unit cell in a fcc structure = 4 atoms.
10.
(i) When a solid is heated, vacancy defect can arise.
(ii) A solid crystal is said to have vacancy defect when some of the lattice sites are vacant
(iii) Vacancy defect leads to a decrease in the density of the solid
11.
| Face - centred unit cells | body - centred unit cells |
| In a face - centred unit cell, the constituent particles are present at the corners and one at the centre of each face. | A body - centred unit cell contains particles at the corners and one at the body centre. |
12.
(i) In ionic compounds, electricity is conducted by ions.
(ii) In solid state, ions are held together by A strong electrostatic forces and are not free to move about within the solid.
(iii) Hence, ionic solids do not conduct electricity in solid state
(iv) However, in molten state or in solution form, the ions are free to move and can conduct electricity.
13.
ZnS exhibits Frenkel defect.
14.
| Amorphous Solids | Crystalline solids |
| Polyurethane | Naphthalene |
| Teflon | Benzoic acid |
| Cellophane | Potassium nitrate |
| Polyvinyl chloride | Copper |
| Fiber glass |
15.
(i) The intermolecular forces of attraction that are present in solids are very strong.
(ii) The constituent particles of solids have fixed position.
(iii) Hence, solids have a definite volume.
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