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Published on: 13/05/2022
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Questions + Answers key
Take MCQ Chemistry Test1.
_______.
H3PO2 and H2O
H+/H2O
HgSO4/H2SO4
Cu2Cl2
2.
An alkene “A” on reaction with O3 and Zn - H2O gives propanone and ethanol in equimolar ratio. Addition of HCl to alkene “A” gives “B” as the major product. The structure of product “B” is ______.
\(Cl-{ CH }_{ 2 }-CH_{ 2 }-\overset { \overset { CH_{ 3 } }{ | } }{ \underset { \underset { CH_{ 3 } }{ | } }{ CH } } \)
\({ H }_{ 3 }C-{ CH }_{ 2 }-\overset { \overset { CH_{ 2 }Cl }{ | } }{ CH } -{ CH }_{ 3 }\)
\(\\ { H }_{ 3 }C-{ CH }_{ 2 }-\overset { \overset { CH_{ 3 } }{ | } }{ \underset { \underset { CL{ } }{ | } }{ C } } -{ CH }_{ 3 }\)
\({ H }_{ 3 }C-{ CH }-\overset { \overset { CH_{ 3 } }{ | } }{ \underset { \underset { Cl }{ | } }{ C } } \)
3.
Benzoic acid \(\overset { i){ NH }_{ 3 } }{ \underset { ii)\Delta }{ \longrightarrow } } A\overset { NaOBr }{ \longrightarrow } B\overset { NaN{ O }_{ 2 }/HCl }{ \longrightarrow } \) C 'C' is ______.
anilinium chloride
O – nitro aniline
benzene diazonium chloride
m– nitro benzoic acid
4.
The correct IUPAC name of the compound
4 – chloro – 2,3 – dimethyl pentan – 1-ol
2,3 – dimethyl – 4- chloropentan -1-ol
2,3,4 – trimethyl – 4- chlorobutan -1-ol
4– chloro – 2,3,4 – trimethyl pentan – 1-ol
5.
The most effective electrolyte for the coagulation of As2S3Sol is _______.
NaCl
Ba(NO3)2
K3[Fe(CN)6]
Al2(SO4)3
6.
Which of the following electrolytic solution has the least specific conductance?
2N
0.002N
0.02N
0.2N
7.
Which of the following fluro compounds is most likely to behave as a Lewis base?
BF3
PF3
CF4
SiF4
8.
For a first order reaction A ⟶ product with initial concentration x mol L-1, has a half life period of 2.5 hours. For the same reaction with initial concentration \(\left( \frac { x }{ 2 } \right) \) mol L-1 the half life is
(2.5 x 2) hours
\(\left( \frac { 2.5 }{ 2 } \right) \) hours
2.5 hours
Without knowing the rate constant, t1/2 cannot be determined from the given data
9.
10.
Crystal field stabilization energy for high spin d5 octahedral complex is _______.
-0.6\({ \Delta }_{ 0 }\)
0
2(P-\({ \Delta }_{ 0 }\))
2(P+\({ \Delta }_{ 0 }\))
11.
The catalytic behaviour of transition metals and their compounds is ascribed mainly due to _______.
their magnetic behaviour
their unfilled d orbitals
their ability to adopt variable oxidation states
their chemical reactivity
12.
Duralumin is an alloy of ______.
Cu, Mn
Cu, Al, Mg
Al, Mn
Al, Cu, Mn, Mg
13.
Which of the following is strongest acid among all?
HI
HF
HBr
HCl
14.
Which of the following reduction is not thermodynamically feasible?
\({ Cr }_{ 2 }{ O }_{ 3 }+2Al\longrightarrow { Al }_{ 2 }{ O }_{ 3 }+2Cr\)
\(\mathrm{Al}_2 \mathrm{O}_3+2 \mathrm{Cr} \longrightarrow \mathrm{Cr}_2 \mathrm{O}_3+2 \mathrm{Al}\)
\(3Ti{ O }_{ 2 }+4Al\longrightarrow 2A{ l }_{ 2 }{ O }_{ 3 }+3Ti\)
none of these
15.
Which of the metal is extracted by Hall-Heroult process?
Al
Ni
Cu
Zn
1.
(a)
H3PO2 and H2O
2.
3.
4.
(a)
4 – chloro – 2,3 – dimethyl pentan – 1-ol
5.
As2S3 is a negatively charged colloid. It will be most effectively coagulated by the cation with greater valency. i.e., Al3+.
6.
In general, specific conductance of an electrolyte decreases with dilution.So,0.002N solution has least specific conductance.
7.
BF3 → electron deficient → Lewis acid
PF3 → electron rich → Lewis base
CF4 → neutral → neither Lewis acid nor base
SiF4 → neutral → neither Lewis acid nor base
8.
For a first order reaction
t1/2 = \(\frac { 0.693 }{ { k }}\)
t1/2 does not depend on the initial concentration and it remains constant (whatever may be the initial concentration)
t1/2 = 2.5 hrs
9.
(c)
10.
The electronic configuration t2g3, e2g
[ 3 x (-0.4)+ 2(0.6)]Δ0
[-1.2 + 1.2] Δ0 = 0
11.
(c)
their ability to adopt variable oxidation states
12.
(d)
Al, Cu, Mn, Mg
13.
(a)
HI
14.
(b)
\(\mathrm{Al}_2 \mathrm{O}_3+2 \mathrm{Cr} \longrightarrow \mathrm{Cr}_2 \mathrm{O}_3+2 \mathrm{Al}\)
15.
(a)
Al
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