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Published on: 09/10/2019
Hydrogen
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1.
Give ion electron equations for the following reactions.
Oxidation of sulphurous acid to sulphuric acid
2.
Scientist of UK has designed the cars, working on hydrogen fuel cells instead of petrol engines. Here hydrogen is used as sources of electrical energy i.e. a reaction of hydrogen and oxygen is used to generate electrical energy. It has many advantages over the conventional fossil fuels and electric power generation.
What are the values possessed by scientists of UK?
3.
Scientist of UK has designed the cars, working on hydrogen fuel cells instead of petrol engines. Here hydrogen is used as sources of electrical energy i.e. a reaction of hydrogen and oxygen is used to generate electrical energy. It has many advantages over the conventional fossil fuels and electric power generation.
Give two advantages of hydrogen over fossil fuels?
4.
In India, there is the shortage of drinking water. Thus, projects like rainwater harvesting are used by Green Park Association to increase the amount of underground water. Rainwater is the almost pure form of water after the heavy shower as it is, in fact, the distilled water. The first shower contains dissolved gases from the atmosphere. Being a good solvent, when it flows on the surface of the earth, it dissolves many salts in the form of hydrogen carbonate, chloride and sulphate in water which make it hard Give the values possessed by the office bearer of Green Park Association?
5.
At the home of Mr.Kumar, Dalda ghee is generally used. He is suffering from high blood pressure and diabetes. Mr.Sharma, a friend of Mr.Kumar has advised him to change from ghee to vegetable oil like mustard oil.
Dihydrogen (H2) is used in the manufacture of vanaspati ghee by hydrogenation of polyunsaturated vegetable oils using nickel as a catalyst.
Vegetable oil \(\xrightarrow [ { H }_{ 2 } ]{ Ni } \) vanaspati ghee
Should we use vegetable oils for cooking? why?
6.
Calculate the mass of oxygen which will be liberated by the decomposition of 200mL of this solution.
7.
What mass of hydrogen peroxide will be present in 2L of a 5M solution?
8.
How would you prepare very pure dihydrogen in the laboratory?
9.
An ionic hydride of an alkali metal has significant covalent character and is almost unreactive towards oxygen and chlorine. This is used in the synthesis of other useful hydrides. Write its reaction with \({ Al }_{ 2 }{ Cl }_{ 6 }\)
10.
Complete the following reactions.
\(CO(g)+{ H }_{ 2 }(g)\xrightarrow [ ]{ \Delta } \)
11.
Complete the following reactions.
\({ H }_{ 2 }(g)+{ M }_{ m }{ O }_{ 0 }(s)\underrightarrow { \Delta } \)
1.
\(\mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow \mathrm{H}_{2} \mathrm{O}+\mathrm{O}
\)
\(\mathrm{H}_{2} \mathrm{SO}_{3}+\mathrm{O} \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}
\)
_____________________
\(
\mathrm{H}_{2} \mathrm{SO}_{3}+\mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow \mathrm{H}_{2} \mathrm{SO}_{4}+\mathrm{H}_{2} \mathrm{O}
\)
or \(\mathrm{SO}_{3}^{2-}+\mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow \mathrm{SO}_{4}^{2-}+\mathrm{H}_{2} \mathrm{O}
\)
2.
The values possessed by UK scientists are control of environmental pollution and generation of new sources of energy which are highly efficient.
3.
It produce more energy per unit mass of fuel and does not create pollution.
4.
The value possessed by the office bearer of Green Park Association are best to use of rainwater, saving water for drinking irrigation, domestic purpose etc.
5.
Yes, because these are unsaturated fats and hence,good for health. They do not form cholesterol if taken in small quantity.
6.
0.2 L(or 200 mL) of 5M solution will contain
\(\frac { 340\times0.2 }{ 2 } =34g{ H }_{ 2 }{ O }_{ 2 }\)
\(\underset { 2\times 34=68g }{ { 2H }_{ 2 }O_{ 2 } } \rightarrow { 2H }_{ 2 }O+\underset { 2\times 16=32g }{ { O }_{ 2 } } \)
\(\because \ 68g \ { H }_{ 2 }O_{ 2 }\) on decomposition will give 32g\(O_{ 2 }\)
\(\therefore \ 34g \ { H }_{ 2 }O_{ 2 }\) on decomposition will give
\(\frac { 32\times 34 }{ 68 } =16g{ O }_{ 2 }\)
7.
Molar mass of \({ H }_{ 2 }{ O }_{ 2 }=34 \ gmol^{ -1 }\)
1L of 5M solution of \({ H }_{ 2 }O_{ 2 }\)will contain 34 x 5g \({ H }_{ 2 }O_{ 2 }\)
2L of 5M solution of \({ H }_{ 2 }O_{ 2 }\)will contain 34 x 5 x 2 = 340g \({ H }_{ 2 }O_{ 2 }\)
Mass of \({ H }_{ 2 }O_{ 2 }\)present in 2L of 5 molar solution = 340g
8.
I.Highly pure Dihydrogen (hydrogen gas ) can be prepared by the following methods.
Fairly pure hydrogen can be obtained by treating pure magnesium or pure aluminium with chemically pure H2SO4 or HCl diluted with distilled water. The gas is passed over P2O5
and is collected by the displacement of mercury.
\(Mg(s)+{ H }_{ 2 }{ SO }_{ 4 }(aq)\rightarrow Mg{ SO }_{ 4 }(aq)+{ H }_{ 2 }(g)\)
Highly pure hydrogen gas can be obtained by electrolyzing a warm solution of Ba(OH)2 in a U tube using nickel electrodes. The gas is purified by passing it over heated platinum gauze when traces of oxygen combine with hydrogen forming water.
The gas is then dried by passing it over caustic potash sticks and photash sticks and phophorous pentoxide. Hydrogen is finally absorbed in palladium and the impurities remain unadsorbed. On heating palladium under reduced pressure, pure hydrogen is liberated.
9.
It is LiH because it has significant covalent character due to the smallest alkali metal Li. LiH is very stable. It is almost unreactive towards oxygen and chlorine.
It reacts with \({ Al }_{ 2 }{ Cl }_{ 6 }\) to form lithium aluminium hydride.
\(8LiH+{ Al }_{ 2 }{ Cl }_{ 6 }\longrightarrow 2LiAl{ H }_{ 4 }+6LiCl\)
10.
\(CO(g)+{ H }_{ 2 }(g)\xrightarrow [ \Delta ]{ Catalyst } { CH }_{ 3 }OH(l)\)
11.
\({ H }_{ 2 }(g)+{ M }_{ m }{ O }_{ 0 }(s)\underrightarrow { \Delta } \)
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