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1.
Sodium salt of which acid will be needed for the preparation of propane? Write chemical equation for the reaction.
2.
For the reaction,\({ H }_{ 2 }(g)+{ I }_{ 2 }(g)\rightleftharpoons 2HI(g)\) the standard free energy is \(\Delta { G }^{ \circleddash }>0\) . How is the equilibrium constant effected?
3.
If the combustion of 1g of graphite produces 20.4kJ of heat, what will be molar enthalpy change? Give the significance of sign also.
4.
In \({ PO }_{ 4 }^{ 3- }\) ion, formal charge on each O-atom of P-O bond is.
5.
Arranges, p and d- subshells of a shell in the increasing order of effective nuclear charge (Zeff) experienced by the electron present in the nucleus.
6.
What is the lowest value of n that allows g orbitals to exist?
7.
One mole of oxygen gas at STP is equal to?
8.
What are the sources of dissolved oxygen in water?
9.
Write one chemical reaction for the preparation of \({ D }_{ 2 }O_{ 2 }\)
10.
A gas that follows Boyle's law, Charle's law and Avogadro's law is called an ideal gas.Under what condition a real gas would behave ideally?
1.
Butanoic acid,
\(\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{COO}^{-} \mathrm{Na}^{+}+\mathrm{NaOH} \stackrel{\mathrm{CaO}}{\longrightarrow} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_3+\mathrm{Na}_2 \mathrm{CO}_3\)
2.
ΔG⊝ and K are related as
ΔG⊝= -RT In Kc
When G⊝ > 0means ΔG⊝ is a positive. This can be so only if 1n Kc is negative i.e Kc < 1.
3.
Molar enthalpy change for the combustion of graphite, △H = enthalpy of combustion of 1 g graphite molar mass
△H=−20.7kJg−1 × 12gmol−1
=−2.48×102kJmol−1
Negative sign in the value of △H indicates that the reaction is exothermic.
4.
In \({ PO }_{ 4 }^{ 3- }\)ion, formal charge on each O-atom of P-O
\(\text{bond}=\frac{\text{total charge}}{\text{Numbers of O−atom}}=−\frac{3}{4}=−0.75\)
5.
S- orbital is spherical in shape, it shields the electrons from the nucleus more effectively than p-orbital which in turn shields more effectively than d-orbital. Therefore, the effective nuclear charge (Zeff) experienced by electrons present in them is d.
6.
For g-orbitals, l = 4.
As for any value ‘n’ of principal quantum number, the Azimuthal quantum number (l) can have a value from zero to (n – 1).
∴For l = 4, minimum value of n = 5
7.
1 mole of O2 gas at STP = 6.022 ×× 1023 molecules of O2
( Avogadro number ) = 32 g of O2
Hence, 1 mole of oxygen gas is equal to molecular weight of oxygen as well as Avogadro number.
8.
( )
Sources of dissolved oxygen in water are:
(i) photosynthesis
(ii) natural aeration and
(iii) mechanical aeration.
9.
( )
\({ D }_{ 2 }O_{ 2 }\)is prepared by distillation of potassium persulphate (\({ K }_{ 2 }S_{ 2 }O_{ 8 }\)) with \(D_{ 2 }O\).
\(\underset { Potassium \ persulphate }{ { K }_{ 2 }{ S }_{ 2 }{ O }_{ 8 } } +{ 2D }_{ 2 }O\underrightarrow { Distilation } { D }_{ 2 }{ O }_{ 2 }+2KDSO_{ 4 }\)
10.
( )
A low pressure and high temperature, a real gas behaves as an ideal gas.
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