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Published on: 22/01/2020
Carbonyl Compounds
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Acetone is soluble in water but benzophenone is not. Give reason.
2.
Complete the following reaction
3.
Write any three uses of acetaldehyde.
4.
Write a note on haloform reaction.
5.
Ethanal is more reactive towards nucleophilic addition reaction than propanone. Why?
6.
What are the Cartesian sign conventions for a spherical mirror?
7.
Derive the relation between f and R for a spherical mirror.
8.
Give the characteristics of image formed by a plane mirror.
9.
What is angle of deviation due to reflection?
10.
State the laws of reflection.
11.
A hydrocarbon A (molecular formula C8H10) on ozonolysis gives B (C4H6O2) only. Compound C (C3H5Br) on treatment with magnesium in dry ether gives (D) which on treatment with CO2 followed by acidification gives(C). Identify A, B and C.
12.
Identify X and Y.
\({ CH }_{ 3 }CO{ CH }_{ 2 }{ CH }_{ 2 }COO{ C }_{ 2 }{ H }_{ 5 }\overset { { CH }_{ 3 }MgBr }{ \longrightarrow } X\overset { { H }_{ 3 }{ O }^{ + } }{ \longrightarrow } Y\)
13.
How is propanoic acid is prepared starting from
(a) an alcohol
(b) an alkylhalide
(c) an alkene
14.
A Compound (A) with molecular formula C2H3N on acid hydrolysis gives (B) which reacts with thionylchloride to give compound(C). Benzene reacts with compound (C) in presence of anhydrous AlCl3 to give compound(D). Compound (D) on reduction with Zn/Hg and Conc.HCl gives (E). Identify (A), (B), (C) (D) and (E). Write the equations.
15.
Identify A, B and C
1.
Acetone is soluble in water due to the intermolecular hydrogen bonding between polar carbonyl group and water molecules. In benzophenone, the phenyl groups are bulkier so C = 0 cannot form hydrogen bonds with water due to steric hindrance.
2.
HCHO + CaCO3
3.
Acetaldehyde is used:
(i) Acetaldehyde is used for silvering of mirrors
(ii) Paraldehyde is used in medicine as a hypnotic.
(iii) Acetaldehyde is used in the commercial preparation of number of organic compounds like acetic acid, ethyl acetate etc.,
4.
Acetaldehyde and methyl ketones, containing \(\\ \\ { CH }_{ 3 }-\underset { \overset { | }{ O } }{ C } -group\) , when treated with halogen and alkali give the corresponding haloform. This is known as Haloform reaction
\({ CH }_{ 3 }-\underset { \overset { || }{ O } }{ C } -{ CH }_{ 3 }\overset { { 3Cl }_{ 2 } }{ \underset { Na }{ \longrightarrow } } { CCl }_{ 3 }-\underset { \overset { || }{ O } }{ C } -{ CH }_{ 3 }\overset { NaOH }{ \longrightarrow } { CHCl }_{ 3 }+{ CH }_{ 3 }-\underset { \overset { || }{ O } }{ C } -ONa\)
5.
(i) Ethanal (CH3CHO) is more reactive towards nucleophilic addition reaction than propanone (\({ CH }_{ 3 }-\underset { \overset { || }{ O } }{ C } -{ CH }_{ 3 }\)) because of steric and electronic reasons.
(ii) Greater the number of alkyl groups attached, less will be the reactivity of carbonyl compound towards nucleophilic addition.
(iii) Soethanal is more reactive than propanone.
6.
(i) The Incident light is taken from left to right (i.e. object on the left of mirror).
(ii) All the distances are measured from the pole of the mirror (pole is taken as origin).
(iii) The distances measured to the right of pole along the principal axis are taken as positive.
(iv) The distances measured to the left of pole along the principal axis are taken as negative.
(v) Heights measured in the upward perpendicular direction to the principal axis are taken as positive.
(vi) Heights measured in the downward perpendicular direction to the principal axis, are taken as negative.
7.
(i) C be the centre of curvature of the mirror.
(ii) Consider a light ray parallel to the principal axis is incident on the mirror at M and passes through the principal focus F after reflection. An.
(iii) The line CM is the normal to the mirror at M. Let i be the angle of incidence and the same will be the angle of reflection.
(iv) If MP is the perpendicular from M on the principal axis, then from the geometry.
(v) The angles ∠MCP = i and ∠MFP = 2i
(vi) From right -angle triangles ΔMCP and ΔMFP,
\(tani=\cfrac { PM }{ PC } \) and \(tan2i=\cfrac { PM }{ PF } \)
(vii) As the angles are small, tan i≈i
\(i=\cfrac { PM }{ PC } \) and \(2i=\cfrac { PM }{ PF } \)
(viii) Simplifying
\(2\cfrac { PM }{ PC } =\cfrac { PM }{ PF } ;2PF=PC\)
8.
(i) The image formed by a plane mirror is virtual, erect, and laterally inverted.
(ii) The size of the image is equal to the size of the object.
(iii The image distance far behind the mirror is equal to the object distance in front of it.
(iv) If an object is placed between two plane mirrors inclined at an angle e, then the number of images n formed is as,
\(n=\left( \cfrac { 360 }{ \theta } -1 \right) \)
9.
The angle between the incident and deviated light ray is called angle of deviation of the light ray.
10.
According to law of reflection,
(i) The incident ray, reflected ray and normal to the reflecting surface all are coplanar (i.e: lie in the same plane).
(ii) The angle of incidence i is equal to the angle of reflection r.
i = r
11.
The compound with molecular formula C8H10
Compound (C) with molecular formula C3HSBr is
12.
13.
An alcohol:
An alkylhalide:
An alkene:
14.
15.
| Compound | Name |
| A | Benzoyl Chloride |
| B | Benzophenone |
| C | Ethylbenzoate |
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