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Published on: 30/10/2019
Chemistry In Everyday Life
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Which is the monomer of neoprene in the following?
\({ CH }_{ 2 }-\underset { \underset { CL }{ | } }{ C } { -CH=CH }_{ 2 }\)
\({ CH }_{ 2 }=CH-C\equiv CH\)
\({ CH }_{ 2 }=CH-CH={ CH }_{ 2 }\)
\({ CH }_{ 2 }-\underset { \underset { { CH }_{ 3 } }{ | } }{ C } { -CH=CH }_{ 2 }\)
2.
Terylene is an example of _______.
polyamide
polythene
polyester
polysaccharide
3.
4.
Antiseptics and disinfectants either kill or prevent growth of microorganisms. Identify which of the following statement is not true.
dilute solutions of boric acid and hydrogen peroxide are strong antiseptics.
Disinfectants harm the living tissues
A 0.2% solution of phenol is an antiseptic while 1% solution acts as a disinfectant
Chlorine and iodine are used as strong disinfectants
5.
Dettol is the mixture of _____________.
Chloroxylenol and bithionol
Chloroxylenol and \(\alpha\)-terpineol
phenol and iodine
terpineol and bithionol
6.
Which sweetening agent are used to prepare sweets for a diabetic patient?
7.
Name one substance which can act as both analgesic and antipyretic.
8.
What are antibiotics?
9.
Write a note on vulcanization of rubber
10.
How is terylene prepared?
11.
Write a note on co –polymer
12.
What are food preservatives?
13.
Explain the mechanism of cleansing action of soaps and detergents.
14.
What are drugs? How are they classified.
1.
(a)
\({ CH }_{ 2 }-\underset { \underset { CL }{ | } }{ C } { -CH=CH }_{ 2 }\)
2.
(c)
polyester
3.
(a)
4.
(a)
dilute solutions of boric acid and hydrogen peroxide are strong antiseptics.
5.
(b)
Chloroxylenol and \(\alpha\)-terpineol
6.
(i) Sucralose is used as sugar substituent like Sorbitol, Xylitol and Mannitol. All these have sweetness. They are metabolised without the influence of insulin.
(ii) Artificial sweetening agents like Aspartarne, Alitame and Saccharin are also used. These have negligible nutritional value.
Example : Saccharin,Aspartame, Sucralose, Alitame
7.
Aspirin (o - acetyl salicylic acid) - is a substance which lowers body temperature and also reduces body pain. So it acts as both analgesic and antiphyretic.
8.
(i) Many micro organisms (bacteria, fungi and moulds) produce certain chemicals which inhibit the growth or metabolism of some other micro organism. Such chemicals are called antibiotics.
(ii) Eg: Penicillin from the mould penicillium notatum
9.
(i) Natural rubber is mixed with 3-5% sulphur and heated at 100-150°C causes cross-linking of the cis-1,4-polyisoprene chains through disulphide (-S-S-) bonds.
(ii) The physical properties of rubber can be altered by controlling the amount of sulphur that is used for vulcanization.
(iii) In sulphur rubber, made with about 1 to 3% sulphur is soft and stretchy.When 3 to 10% sulphur is used the resultant rubber is somewhat harder but flexible.
10.
(i) Monomers :Ethylene glycol and terepathalic acid (or) dimethyl terephthalate.
(ii) Catalyst : Zinc acetate and antimony trioxide.
(iii) Temperature : 500 K
(iv) Product : Terylene
(v) Uses : blending with cotton or wool fibres and as glass reinforcing materials in safety helmets
11.
(i) A polymer containing two or more different kinds of monomer units is called a copolymer.
(ii) For example, SBR rubber(Buna-S) contains styrene and butadiene monomer units.
(iii) Copolymers have properties quite different from the homopolymers.
(iv) Mixture of styrene and 1,3 butadiene to form a copolymer (Buna -S)
Preparation of Buna-S:
It is a co-polymer. It is obtained by the polymerisation of buta -1,3 - diene and styrene in the ratio 3: 1 in the presence of sodium.
12.
(i) Preservatives are chemicals added to food which are capable of inhibiting, retarding or arresting the process of fermentation, acidification or other decomposition of food by the growth of micro organisms (or)
(ii) Chemical substances which are added to food that prevents the spoilage of food materials by destroying the food - spoiling micro-organisms are called food preservatives.
(iii) Eg: sodium benzoate, NaCl, Acetic acid Sodium metabisulphite, potassium meta bisulphite etc.
13.
(i) To understand how a soap works as a cleansing agent, let us consider sodium palmitate an example of a soap. The cleansing action of soap is directly related to the structure of carboxylate ions (palmitate ion) present in soap. The structure of palmitate exhibit dual polarity. The hydrocarbon portion is non polar and the carboxyl portion is polar.
(ii) The nonpolar portion is hydrophobic while the polar end is hydrophilic. The hydrophobic hydro carbon portion is soluble in oils and greases, but not in water. The hydrophilic carboxylate group is soluble in water.
(iii) The dirt in the cloth is due to the presence of dust particles intact or grease which stick. When the soap is added to an oily or greasy part of the cloth, the hydrocarbon part of the soap dissolve in the grease, leaving the negatively charged carboxylate end exposed on the grease surface.
(iv) At the same time the negatively charged carboxylate groups are strongly attracted by water, thus leading to the formation of small droplets called micelles and grease is floated away from the solid object. When the water is rinsed away, the grease goes with it. As a result, the cloth gets free from dirt and the droplets are washed away with water. The micelles do not combine into large drops because their surfaces are all negatively charged and repel each other. The cleansing ability of a soap depends upon its tendency to act as a emulsifying agent between water and water insoluble greases.
The cleansing action of detergents are similar to cleansing action of soap. Eg: the structure of a cationic detergents is:
14.
A drug is a substance that is used to modify or explore physiological systems or pathological states for the benefit of the recipient. It is used for the purpose of diagnosis, prevention, cure/relief of a disease.
a) Classification of drugs:
Drugs are classified based on their properties such as chemical structure, pharmacological effect, target system, site of action etc.
b) Classification based on the chemical structure:
In this classification, drugs with a common chemical skeleton are classified into a single group. For example, ampicillin, amoxicillin, methicillin etc.. all have similar structure and are classified into a single group called penicillin. Similarly, we have other group of drugs such as opiates, steroids, catecholamines etc. Compounds having similar chemical structure are expected to have similar chemical properties. However, their biological actions are not always similar. For example, all drugs belonging to penicillin group have same biological action, while groups such as barbiturates, steroids etc.. have different biological action.
Penicillins
Classification based on Pharmacological effect:
In this classification, the drugs are grouped based on their biological effect that they produce on the recipient. For example, the medicines that have the ability to kill the pathogenic bacteria are grouped as antibiotics. This kind of grouping will provide the full range of drugs that can be used for a particular condition (disease). The physician has to carefully choose a suitable medicine from the available drugs based on the clinical condition of the recipient.
Examples:
Antibiotic drugs: amoxicillin, ampicillin, cefixime, cefpodoxime, erythromycin, tetracycline etc.. Antihypertensive drugs: propranolol, atenolol, metoprolol succinate, amlodipine etc...
Classification based on the target system (drug action):
In this classification, the drugs are grouped based on the biological system/process, that they target in the recipient. This classification is more specific than the pharmacological classification. For example, the antibiotics streptomycin and erythromycin inhibit the protein synthesis (target process) in bacteria and are classified in a same group. However, their mode of action is different. Streptomycin inhibits the initiation of protein synthesis, while erythromycin prevents the incorporation of new amino acids to the protein.
Classification based on the site of action (molecular target):
The drug molecule interacts with biomolecules such as enzymes, receptors etc, which are referred as drug targets. We can classify the drug based on the drug target with which it binds. This classification is highly specific compared to the others. These compounds often have a common mechanism of action, as the target is the same.
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