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Published on: 30/10/2019
Hydroxy Compounds and Ethers
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Which of the following compound can be used as antifreeze in automobile rediators?
methanol
ethanol
Neopentyl alcohol
ethan -1, 2-diol
2.
In the reaction Ethanol \(\overset { { PCl }_{ 5 } }{ \longrightarrow } X\overset { alc.KOH }{ \longrightarrow } Y\overset { { H }_{ 2 }{ SO }_{ 4 }/{ H }_{ 2 }O }{ \underset { 298k }{ \longrightarrow } } Z.\) The ‘Z’ is ______.
ethane
ethoxyethane
ethylbisulphite
ethanol
3.
(CH3)3-C-CH(OH) CH3 \(\overset { con{ H }_{ 2 }{ SO }_{ 4 } }{ \longrightarrow } \)X (major product)
(CH3)3 CCH = CH2
(CH3)2C = C (CH3)2
CH2= C(CH3)CH2-CH2- CH3
CH2= C (CH3) - CH2- CH2- CH3
4.
Which one of the following will react with phenol to give salicyladehyde after hydrolysis.
Dichlo methane
trichloroethane
trichloro methane
CO2
5.
An alcohol (x) gives blue colour in victormayer’s test and 3.7g of X when treated with metallic sodium liberates 560 mL of hydrogen at 273 K and 1 atm pressure what will be the possible structure of X?
CH3 CH (OH) CH2CH3
CH3 – CH (OH) – CH3
CH3 – C (OH) – (CH3)2
CH3- CH2 –CH (OH) – CH2 – CH3
6.
0.44g of a monohydric alcohol when added to methyl magnesium iodide in ether liberates at STP 112 cm3 of methane with PCC the same alcohol form a carbonyl compound that answers silver mirror test. Identify the compound.
7.
Phenol is distilled with Zn dust followed by friedel – crafts alkylation with prophyl chloride to give a compound B, B on oxidation gives (c) Indentify A,B and C.
8.
How will you convert acetylene into n-butyl alcohol.
9.
Write Kolbe’s reaction.
10.
Can we use nucelophiles such as NH3,CH3O - for the Nucleophilic substitution of alcohols
11.
Suggest a suitable reagent to prepare secondary alcohol with identical group using Grignard reagent.
12.
Draw the major product formed when 1-ethoxyprop-1-ene is heated with one equivalent of HI.
13.
What is metamerism? Give the structure and IUPAC name of metamers of 2-methoxy propane
14.
Write the structure of the aldehyde, carboxylic acid and ester that yield 4- methylpent -2-en-1-ol.
1.
(d)
ethan -1, 2-diol
2.
3.
(CH3)2C = C (CH3)2
4.
trichloro methane
5.
CH3 CH (OH) CH2CH3
2R-OH+ 2Na ⟶ 2RONa + H2 ↑
2 moles of alcohol gives 1 mole of H2 which occupies 22.4 L at 273 K and 1 atm number of moles of alcohol
= 2 moles of R -OH/22.4L of H2 x 560 ml
= 0.05 moles
No of moles = mass/molar mass = m/M
= 3.7/0.05 = 74 g mol-1
General formula for (R-OH) Cn H2n + 1OH
n(12) + (2n + 1) (1) + 16 + 1 = 74
14n = 74 - 18
14n = 56
n = 56/14 = 4
The "2" alcohol which contains 4 carbon is CH3 - CH (OH) CH2 - CH3
6.
Mass = 0.44 g
No. of moles = Given Volume/Molar Volume = 112/22400
Molar Mass = 0.44/112 x 22400 = 88g
CnH2n+1 + OH = 88
12n+ (1)(2n+1) + 16 +1 = 88
14n + 18 = 88
14n = 88 - 18
n =70/14 = 5
Pentanoicacid
7.
\(\underset {Phenol} {\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{OH}}+\mathrm{Zn}(\text { dust }) \rightarrow \underset {benzene(A)} {\mathrm{C}_{6} \mathrm{H}_{6}}+\mathrm{ZnO}\)
8.
9.
In this reaction, phenol is first converted into sodium phenoxide which is more reactive than phenol towards electrophilic substitution reaction with CO2, Treatment of sodium phenoxide with CO2 at 400 K, 4-7 bar pressure followed by acid hydrolysis gives salicylic acid.
10.
Yes, we can use nucleophiles such as NH3, CH3O- for the nucleophilic substitution of alcohol.
Example
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+\mathrm{NH}_{3} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2}+\mathrm{H}_{2} \mathrm{O} \)
\(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+\mathrm{CH}_{2} \mathrm{~N}_{2} \rightarrow \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OCH}_{3}+\mathrm{N}_{2}\)
11.
Acetaldehyde - CH3-CHO
12.
13.
Ethers having same molecular formula, but alkyl groups attached to the oxygen atom are different. This phenomenon is known as metamerism.
Metamers of 2- methoxy propane
\(\mathrm{C}_{2} \mathrm{H}_{5}-\mathrm{O}-\mathrm{C}_{2} \mathrm{H}_{5}-\) diethyl ether
\(\mathrm{CH}_{3}-\mathrm{O}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{3}\) methyl n-propyl ether
14.
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