When aniline reacts with acetic anhydride the product formed is_______.

The product formed by the reaction an aldehyde with a primary amine ________.

Which one of the following nitro compounds does not react with nitrous acid.

CH₃CH₂ Br \(\overset { aqNaOH }{ \underset { \Delta }{ \longrightarrow } } A\overset { { KMnO }_{ 4 }{ /H }^{ + } }{ \underset { \Delta }{ \longrightarrow } } B\overset { { NH }_{ 3 } }{ \underset { \Delta }{ \longrightarrow } } C\overset { { Br }_{ 2 }/NaOH }{ \longrightarrow } D\)  D' is________.

The method by which aniline cannot be prepared is _________.

There are two isomers with the formula  CH₃NO₂. How will you distinguish between them?

Identify A to E in the following sequence of reactions
   
 \(\overset { {CH_3} {CL} }{ \underset { {AlCl}_3 }{ \longrightarrow } }\) A \(\overset { {HNO_3}/ {H_2So_4} }{ \underset { {} }{ \longrightarrow } }\)  B \(\overset { {Sn} /{HCL} }{ \underset {{} }{ \longrightarrow } }\)  (C) \(\overset { {NaNo_2}/ {HCL} }{ \underset { {O^o}C }{ \longrightarrow } }\)  D \(\overset { {CuCN} }{ \underset { {}}{ \longrightarrow } }\) E

A dibromo derivative (A) on treatment with KCN followed by acid hydrolysis and heating gives a monobasic acid (B) along with liberation of CO₂ . (B) on heating with liquid ammonia followed by treating with Br₂ /KOH gives (c) which on treating with NaNO₂ and HCl at low temperature followed by oxidation gives a monobasic acid (D) having molecular mass 74. Identify A to D.

Account for the following
i. Aniline does not undergo Friedel – Crafts reaction
ii. Diazonium salts of aromatic amines are more stable than those of aliphatic amines
iii. pK_b of aniline is more than that of methylamine
iv. Gabriel phthalimide synthesis is preferred for synthesising primary amines.
v. Ethylamine is soluble in water whereas aniline is not
vi. Amines are more basic than amides
vii.Although amino group is o – and p – directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m – nitroaniline.

How will you distinguish between primary secondary and tertiary alphatic amines.

Identify compounds A, B and C in the following sequence of reactions.
i) \({ C }_{ 6 }{ H }_{ 5 }NO_{ 2 }\overset { Fe/HCL }{ \longrightarrow } A\overset { HN{ O }_{ 2 } }{ \underset { 273K }{ \longrightarrow } } B\overset { { C }_{ 6 }{ H }_{ 5 }OH }{ \longrightarrow } C\)
ii) \({ C }_{ 6 }{ H }_{ 5 }N_{ 2 }cl\overset { CuCN }{ \longrightarrow } A\overset { H_{ 2 }O/H^{ + } }{ \longrightarrow } B\overset { NH_3 }{ \longrightarrow } C\)
iii) \({ C }{ H }_{ 3 }{ C }{ H }_{ 2 }I\overset { NaCN}{ \longrightarrow } A\overset {OH^-}{ \underset {Partial hydrolysis}{ \longrightarrow } } B\overset {NaOH+Br_2 }{ \longrightarrow } C\)
iv) \({ C }{ H }_{ 3 }NH_{ 2 }\overset { CH_3 Br }{ \longrightarrow } A\overset { CH_{ 3 }COCl}{ \longrightarrow } B\overset { B_2H_6 }{ \longrightarrow } C\)
v) \({ C }_{ 6 }{ H }_{ 5 }NH_{ 2 }\overset { (CH_{ 3 }CO)_{ 2 }O }{ \underset { Pyridine }{ \longrightarrow } } A\overset { HNO_{ 3 } }{ \underset { H_{ 2 }SO_{ 4 },288K }{ \longrightarrow } } B\overset { { H }_{ 2 }O/{ H }^{ + } }{ \longrightarrow C } \)
vi) 

vii) \({ C }{ H }_{ 3 }CN_{ 2 }NC\overset { HgO }{ \longrightarrow } A\overset { H_{ 2 }O }{ \longrightarrow } B\overset { i) NaN{ O }_{ 2 }/HCL }{ \underset { ii){ H }_{ 2 }O }{ \longrightarrow } } \)

How will you convert nitrobenzene into
i. 1,3,5 - trinitrobenzene
ii. o and p- nitrophenol
iii. m – nitro aniline
iv. azoxybenzene
v. hydrozobenzene
vi. N – phenylhydroxylamine
vii. aniline

How will you prepare propan – 1- amine from
i) butane nitrile
ii) propanamide
ii) 1- nitropropane

Identify A,B and C
\(\overset{SOCl_2}\longrightarrow A \overset{NH_3}\longrightarrow B\overset{LiAlH_4}\longrightarrow (C)\)