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Published on: 27/08/2019
Transition and Inner Transition Elements
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1.
The trend in ionisation enthalpy of a transition element is not regular because,_______.
removal of one electron alters the relative energies of 4s and 3d orbitals
due to different electronic configuration (stability)
Poor screening of 3p-orbital
due to decrease in effective nuclear charge
2.
Identify the paramagnetic species.
Cu+
Cr+
MnO4
Zn2+
3.
The highest possible oxidation state shown by osmium in its compound is_______.
+4
+6
+8
+10
4.
Hybridisation of chromium ions and dichromate ions is ________.
Sp2
Sp3d
both (a) and (b)
None of these
5.
Which of the following is wrong with respect to lanthanide contraction?
Decrease in ionic radii
Increase in tendency to act as reducing agents
Decrease in basic character
Resembles second and third row of d-block elements
6.
Which of the following statements is not true?
on passing H2S, through acidified K2Cr2O7 solution, a milky colour is observed
Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis
K2Cr2O7 solution in acidic medium is orange in colour
K2Cr2O7 solution becomes yellow on increasing the PH beyond 7
7.
8.
The alloy of copper that contain Zinc is________.
Monel metal
Bronze
bell metal
brass
9.
The correct order of increasing oxidizing power in the series _______.
VO2+ < Cr2O72- < MnO4-
Cr2O72- < VO2+ < MnO4-
Cr2O72- < MnO4- < VO2+
MnO4- < Cr2O72- < VO2+
10.
Sc (Z = 21) is a transition element but Zinc (z = 30) is not because _______.
both Sc3+ and Zn2+ ions are colourless and form white compounds
In case of Sc, 3d orbital are partially filled but in Zn these are completely filled
last electron as assumed to be added to 4s level in case of zinc
both Sc and Zn do not exhibit variable oxidation states
11.
f - block elements
12.
Metallothermic
13.
Lanthanide
14.
Zr and Hf
15.
Oxocations
1.
(a)
removal of one electron alters the relative energies of 4s and 3d orbitals
2.
(b)
Cr+
3.
(c)
+8
4.
(b)
Sp3d
5.
(b)
Increase in tendency to act as reducing agents
6.
(b)
Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis
7.
(b)
8.
(d)
brass
9.
+5 +6 +7
VO2+ < Cr2O72- < MnO4-
Greater the oxidation state, higher is the oxidising power.
10.
(b)
In case of Sc, 3d orbital are partially filled but in Zn these are completely filled
11.
Rare earth elements
12.
Lanthanide-thermic process
13.
Monazite sand
14.
Similar size
15.
Actinides
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