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Published on: 31/10/2019
Carbonyl Compounds
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1.
Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their ________.
more extensive association of carboxylic acid via van der Waals force of attraction
formation of carboxylate ion
formation of intramolecular H-bonding
formation of intermolecular H – bonding
2.
Which one of the following undergoes reaction with 50% sodium hydroxide solution to give the corresponding alcohol and acid.
Phenylmethanal
ethanal
ethanol
methanol
3.
Which one of the following reduces tollens reagent
formic acid
acetic acid
benzophenone
none of these
4.
Benzoic acid \(\overset { i){ NH }_{ 3 } }{ \underset { ii)\Delta }{ \longrightarrow } } A\overset { NaOBr }{ \longrightarrow } B\overset { NaN{ O }_{ 2 }/HCl }{ \longrightarrow } \) C 'C' is ______.
anilinium chloride
O – nitro aniline
benzene diazonium chloride
m– nitro benzoic acid
5.
In the following reaction, \(HC\equiv CH \overset { { H }_{ 2 }{ SO }_{ 4 } }{ \underset { HgS{ O }_{ 4 } }{ \longrightarrow } } X\) Product ‘X’ will not give _______.
Tollen’s test
Victor meyer test
Iodoform test
Fehling solution test
6.
7.
Derive the relation between f and R for a spherical mirror.
8.
Give the characteristics of image formed by a plane mirror.
9.
State the laws of reflection.
10.
What is the action of HCN on
(i) propanone
(ii) 2,4-dichlorobenzaldehyde
iii) ethanal
11.
How will you convert benzaldehyde into the following compounds?
(i) benzophenone
(ii) benzoic acid
(iii) α-hydroxyphenylaceticacid.
12.
How is propanoic acid is prepared starting from
(a) an alcohol
(b) an alkylhalide
(c) an alkene
13.
Complete the following reaction
\({ CH }_{ 3 }-{ CH }_{ 2 }-{ CH }_{ 2 }-\underset { \overset { || }{ O } }{ C } -{ CH }_{ 3 }\overset { HO-{ CH }_{ 2 }-{ CH }_{ 2 }-OH }{ \underset { { dry }{ HCl} }{ \longrightarrow } } ?\)
14.
Write the structure of the major product of the aldol condensation of benzaldehyde with acetone.
1.
(d)
formation of intermolecular H – bonding
2.
3.
4.
5.
6.
(d)
7.
(i) C be the centre of curvature of the mirror.
(ii) Consider a light ray parallel to the principal axis is incident on the mirror at M and passes through the principal focus F after reflection. An.
(iii) The line CM is the normal to the mirror at M. Let i be the angle of incidence and the same will be the angle of reflection.
(iv) If MP is the perpendicular from M on the principal axis, then from the geometry.
(v) The angles ∠MCP = i and ∠MFP = 2i
(vi) From right -angle triangles ΔMCP and ΔMFP,
\(tani=\cfrac { PM }{ PC } \) and \(tan2i=\cfrac { PM }{ PF } \)
(vii) As the angles are small, tan i≈i
\(i=\cfrac { PM }{ PC } \) and \(2i=\cfrac { PM }{ PF } \)
(viii) Simplifying
\(2\cfrac { PM }{ PC } =\cfrac { PM }{ PF } ;2PF=PC\)
8.
(i) The image formed by a plane mirror is virtual, erect, and laterally inverted.
(ii) The size of the image is equal to the size of the object.
(iii The image distance far behind the mirror is equal to the object distance in front of it.
(iv) If an object is placed between two plane mirrors inclined at an angle e, then the number of images n formed is as,
\(n=\left( \cfrac { 360 }{ \theta } -1 \right) \)
9.
According to law of reflection,
(i) The incident ray, reflected ray and normal to the reflecting surface all are coplanar (i.e: lie in the same plane).
(ii) The angle of incidence i is equal to the angle of reflection r.
i = r
10.
(ii) 2,4-dichlorobenzaldehyde.
(iii) ethanal
11.
(ii) benzoic acid
(iii) α - hydroxyphenylaceticacid.
12.
An alcohol:
An alkylhalide:
An alkene:
13.
2- Pentanone.
14.
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