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Published on: 02/09/2022
QB365 provides a detailed and simple solution for every Possible Book Back Questions in Class 12 Chemistry Subject - Surface Chemistry, English Medium. It will help Students to get more practice questions, Students can Practice these question papers in addition to score best marks.
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
Questions + Answers key
Take MCQ Chemistry Test

1.
Give three uses of emulsions.
2.
What are the factors which influence the adsorption of a gas on a solid?
3.
Differentiate physisorption and chemisorption.
4.
What is the difference between a sol and a gel?
5.
Write a note on catalytic poison
6.
Write a note on electro osmosis.
1.
(i) Emulsions are used in food industries. Food stuff like milk, cream, butter, etc., are emulsions.
(ii) Emulsions are very common in pharmaceutical industries. Many medicines are produced in the form of emulsions. Ex: Milk of magnesia is used for stomach troubles. Many lotions and ointments are emulsions.
(iii) Non ionic emulsions are most popular due to their low toxicity.
(iv) Cationic emulsions have anti microbial properties.
(v) In agriculture industry emulsions are used as delivery vehicles for insecticides, fungicides and pesticides.
(vi) In cosmetics, emulsions are the delivery vehicles for many hair and skin conditioning agents.
(v) The blood, protoplasm in plant and animal cells and fats in intestines are emulsions.
2.
Factors affecting adsorption
Qualitatively, the extent of surface adsorption depends on
(i) Nature of adsorbent
(ii) Nature of adsorbate
(iii) Pressure
(iv) Concentration at a given temperature.
1. Surface area of adsorbent:
As the adsorption is a surface phenomenon it depends on the surface area of adsorbent. i.e., higher the surface area, higher is the amount adsorbed.
2. Nature of adsorbate:
The nature of adsorbate can influence the adsorption. Gases like SO2, NH3, HCl and CO2 are easily liquefiable as have greater vander waal's force of attraction. On the other hand, permanent gases like H2, N2 and O2 cannot be liquefied easily. These permanent gases are having low critical temperature and adsorbed slowly, while gases with high critical temperature are adsorbed readily.
3. Effect of temperature:
When temperature is raised chemisorption first increases and then decreases. whereas physisorption decreases with increases in temperature.
4. Effect of Pressure:
Chemical adsorption is fast with increase in pressure, it cannot alter the amount of adsorption. In physisorption, the extend of adsorption increases with increase in pressure.
3.
| S.No | Physical adsorption or vander waals adsorption or Physisorption | Chemical adsorption or Chemisorption or Activated adsorption |
|---|---|---|
| 1. | It is instantaneous | It is very slow |
| 2. | It is non-specific | It is very specific depends on nature of adsorbent and adsorbate |
| 3. | In Physisorption, when pressure increases the amount of adsorption increases | Chemical adsorption is fast with increase pressure, it can not alter the amount. |
| 4. | Physisorption decreases with increase in temerature | When temperature is raised chemisorption first increases and then decreases |
| 5. | No transfer of electrons | Chemisorption involves transfer of electrons between the adsorbent and adsorbate |
| 6. | Heat of adsorption is low in the order of 40kJ/ mole. | Heat of adsorption is high i.e., from 40- 400kJ/mole. |
| 7. | Multilayer of the adsorbate is formed on the adsorbent. | Monolayer of the adsorbate is formed |
| 8. | It occurs on all sides | Adsorption occurs at fixed sites called active centres. It depends on surface area |
| 9 | Activation energy is insignificant. | Chemisorption involves the formation of activated complex with appreciable activation energy. |
4.
| S.no | Sol | Gel |
| (a) | The liquid state of collidal solution | The solid (or) semi solid stage of a colloidal solution. |
| (b) | Very low viscosity | Very high viscosity |
| (c) | It does not have definite structure. | It possesses definite structure. |
5.
(i) Certain substances when added to a catalysed reaction decreases or completely destroys the activity of catalyst and they are often known as catalytic poisons.
For example,
(ii) In the reaction, 2SO2 + O2 ⟶ 2SO3 with a Pt catalyst, the poison is As2O3
(iii) i.e., As2O3 destroys the activity of Pt. As2O3 blocks the activity of the catalyst. So, the activity is lost.
6.
A sol is electrically neutral. Hence the medium carries an equal but opposite charge to that of dispersed particles. When sol particles are prevented from moving, under the influence of electric field the medium moves in a direction opposite to that of the sol particles. This movement of dispersion medium under the influence of electric potential is called electro osmosis.
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