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Published on: 13/10/2020
12th Standard Chemistry English Medium Free Online Test Book Back 1 Mark Questions with Answer Key
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
Questions + Answers key
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1.
Which of the following is incorrect for physisorption?
reversible
increases with increase in temperature
low heat of adsorption
increases with increase in surface area
2.
Consider the following half cell reactions.
Mn2+ + 2e- ➝ Mn Eo = -1.18V
Mn2+ ➝ Mn3+ + e- Eo = -1.51V
The Eo for the reaction 3Mn2+➝ Mn + 2Mn3+, and the possibility of the forward reaction are respectively.
2.69V and spontaneous
-2.69 and non spontaneous
0.33V and Spontaneous
4.18V and non spontaneous
3.
Following solutions were prepared by mixing different volumes of NAOH of HCL different concentrations
1) 60 mL\(\frac{M}{10}\)HCl + 40mL\(\frac{M}{10}\)NaOH
2) 55 mL\(\frac{M}{10}\)HCl + 45mL\(\frac{M}{10}\)NaOH
3) 75 mL\(\frac{M}{5}\)HCl + 25mL\(\frac{M}{5}\)NaOH
4) 100 mL\(\frac{M}{10}\)HCl + 100mL\(\frac{M}{10}\)NaOH
pH of which one of them will be equal to 1?
(iv)
(i)
(ii)
(iii)
4.
A zero order reaction X ⟶ Product, with an initial concentration 0.02M has a half life of 10 min. if one starts with concentration 0.04M, then the half life is
10 s
5 min
20 min
cannot be predicted using the given information
5.
An ionic compound Ax By crystallizes in fcc type crystal structure with B ions at the centre of each face and A ion occupying corners of the cube the correct formula of Ax, By is ________.
AB
AB3
A3B
A8B6
6.
An excess of silver nitrate is added to 100ml of a 0.01M solution of Pentaaquachlorochromium (III)chloride. The number of moles of AgCl precipitated would be _______.
0.02
0.002
0.01
0.2
7.
Which of the following d block element has half filled penultimate d sub shell as well as half filled valence sub shell?
Cr
Pd
Pt
none of these
8.
Which is true regarding nitrogen?
least electronegative element
has low ionisation enthalpy than oxygen
d- orbitals available
ability to form pπ-pπ bonds with itself
9.
10.
Roasting of sulphide ore gives the gas (A).(A) is a colourless gas. Aqueous solution of (A) is acidic. The gas (A) is______.
CO2
SO3
SO2
H2S
1.
The incorrect statement is option (n)
Physisorption is an exothermic process. Hence increases in temperature decreases the Physisorption
2.
Mn2+ + 2e- ➝ Mn Eo = -1.18V
Mn2+ ➝ Mn3+ + e- Eo = -1.51V
3Mn2+➝ Mn3+ + 2Mn3+ Eocell = ?
Eocell = (Eoox )+ (Eored)
= 1.51 - 1.18 and non spontaneous
= -2.69V
Since E°is ve ΔG is +ve and the given forward cell reaction is non- spontaneous
3.
75 mL\(\frac{M}{5}\)HCl + 25mL\(\frac{M}{5}\)NaOH
No. of moles of HCI = 0.2 x 75 x 10-3 = 15 x 10-3
No. of moles of NaOH = 0.2 x 25 x 10-3
= 5 x 10-3
No. of moles of HCl after mixing
= 15 x 10-3 - 5 x 10-3
= 10 x 10-3
\(\therefore\) Concentration of HCI = No. of moles of HCI/Vol in litre
= 10 x 10-3/100 x 10-3 = 0.1 M
For (iii) solution. pH of 0.1 M HCI = -log10 (0.1) = 1
4.
for n ≠ 1 t1/2 = \(\frac{2^{n-1} -1}{(n- 1) k[A_{0}]^{-1}}\)
for n = 0; t1/2 = \(\frac{1}{2 k[A_{0}]^{-1}}\)
t1/2 = \(\frac{[A_{0}]}{2 k}\)
t1/2 α [A0] ...(1)
Given [A0] = 0.002 M; t1/2 = 10 min
[A0] = 0.04M; t1/2 = ?
Substitute in (1)
10 min α 0.02 M...(2)
t1/2 α 0.04M ....(3)
(3)(2)
⇒ t1/2 / 10 min
= 0.04 M/0.02 M
t1/2 = 2 x 10 min = 20 min
5.
Number of A ions = Nc/8 = 8/8 = 1
Number of B ions = Nf/2 = 6/2 = 3
Simplest formula = AB3
6.
The complex is [M(H2O)5Cl]Cl2
1000 ml of 1 M solution of the complex gives 2 moles of Cl- ions 1000 ml of 0.01 M solution of the complex will give
\(\frac{100 ml \times 0.01M \times 2Cl^-}{1000 ml \times 1M}\)
= 0.002 moles of Cl- ions
7.
Cr ⇒ [Ar]3d54s1
8.
(d)
ability to form pπ-pπ bonds with itself
9.
(d)
10.
(c)
SO2
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