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TN 12th Computer Applications வலையமைப்பு வடமிடல் Sample Question Papers Study Material - QB365 Set A

Published on: 13/10/2020
12th Standard Chemistry Ionic Equilibrium English Medium Free Online Test One Mark Questions 2020 - 2021
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Which one of the following relationship is correct?
\(pH=\frac { 1 }{ [{ H }^{ + }] } \)
\(pH={ \log }_{ 10 }[{ H }^{ + }]\)
\({ \log }_{ 10 }pH=[{ H }^{ + }]\)
\(pH={ \log }_{ 10 }\frac { 1 }{ [{ H }^{ + }] } \)
2.
Which one of the following formula represents Ostwald's dilution law for a binary whose degree of dissociation is a and concentration C.
\(K=\frac{(1-α)C}{α}\)
\(K=\frac{α^2C}{1-a}\)
K = \(\frac{(1-a)C}{a^2}\)
K = \(\frac{α^2C}{(1-α)c}\)
3.
When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid _______.
increases
decreases
dose not change
becomes zero
4.
\({ X }_{ m }{ Y }_{ n(s) }\overset { { H }_{ 2 }O }{ \rightleftharpoons } { mX }_{ (aq) }^{ n+ }+{ nY }_{ (aq) }^{ m- }\)
\({ [{ X }^{ n+ }] }^{ m }{ [Y^{ m- }] }^{ n }\)
\({ [X }^{ n+ }][{ Y }^{ m- }]\)
\({ [{ X }^{ n+ }] }^{ m }/{ [Y^{ m- }] }^{ n }\)
\({ [X }^{ n+ }]/[{ Y }^{ m- }]\)
5.
The buffer present in human blood is _______.
CH3COOH + CH3COONa
NH4OH + NH4CI
H2CO3 + H\({ CO }_{ 3 }^{ - }\)
CH3COOH + CH3COONa and NH4OH + NH4CI
6.
pH of buffer depends upon concentration of _______.
acid (H+)
Conjugate base (OH-)
Salt
acid (H+) and Conjugate base (OH-)
7.
The pH of pure water at 25°C is _______.
0
1
7
14
8.
An aqueous solution with pH value zero is _______.
acidic
basic
amphoteric
neutral
9.
Ionic product of water increases when _______.
Pressure decreases
H+ ions are added
OH- ions are added
temperature increases
10.
HCl is a strong acid since _______.
It can be easily oxidised
It can be easily ionised
It dissociates completely to give H+ ions in solution
It can be easily oxidised and It can be easily ionised
11.
Dissociation constant of NH4OH is 1.8 x 10-5 the hydrolysis constant of NH4Cl would be _______.
1.8 × 10-19
5.55 × 10-10
5.55 × 10-5
1.80 × 10-5
12.
Which of the following can act as Lowery – Bronsted acid well as base?
HCl
SO42−
HPO42−
Br-
13.
What is the pH of the resulting solution when equal volumes of 0.1M NaOH and 0.01M HCl are mixed?
2.0
3
7.0
12.65
14.
Using Gibb’s free energy change, ∆Go=57.34 kJ mol-1, for the reaction, X2Y(s)⇌2X++Y2- (aq), calculate the solubility product of X2Y in water at 300 K_______. (R = 8.3 J K-1Mol-1)
10-10
10-12
10-14
can not be calculated from the given dat
15.
The solubility of AgCl (s) with solubility product 1.6 × 10-10 in 0.1M NaCl solution would be _______.
1.26 × 10-5M
1.6 × 10-9M
1.6 × 10-11M
Zero
16.
The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5NH) in a 0.10M aqueous pyridine solution _______.(Kb for C5H5N = 1.7×10-9) is
0.006%
0.013%
0.77%
1.6%
17.
What is the decreasing order of strength of bases
OH, NH2- H - C ≡ C and CH3 - CH2-
OH->NH2- >H-C≡C >CH3-CH2-
NH2->OH->CH3-CH2- >H-C≡C
CH3-CH2->NH2->H-C≡C->OH-
OH->H-C ≡ C->CH3-CH2- >NH2-
18.
Which of the following fluro compounds is most likely to behave as a Lewis base?
BF3
PF3
CF4
SiF4
19.
Conjugate base for Bronsted acids H2O and HF are _______.
OH- and H2FH+, respectively
H3O+ and F-, respectively
OH- and F-, respectively
H3O+ and H2F+, respectively
20.
Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.24 ×10-4mol L-1 solubility product of Ag2C2O4 is_______.
2.42 × 10-8mol3L-3
2.66 × 10-12mol3L-3
4.5 × 10-11mol3L-3
5.619 × 10-12mol3L-3
1.
(d)
\(pH={ \log }_{ 10 }\frac { 1 }{ [{ H }^{ + }] } \)
2.
(b)
\(K=\frac{α^2C}{1-a}\)
3.
(b)
decreases
4.
(c)
\({ [{ X }^{ n+ }] }^{ m }/{ [Y^{ m- }] }^{ n }\)
5.
(c)
H2CO3 + H\({ CO }_{ 3 }^{ - }\)
6.
(d)
acid (H+) and Conjugate base (OH-)
7.
(c)
7
8.
(a)
acidic
9.
(d)
temperature increases
10.
(c)
It dissociates completely to give H+ ions in solution
11.
\(K_h= { \frac { { K }_{ w } }{ K_b } } = \frac{1 \times 10^{-14}}{1.8 \times 10^{-5}}\)
= 0.55 x 10-9 = 5.5 x 10-10
12.
HPO42− can have the ability to accept a proton to form H2PO4-
It can also have the ability to donate a proton to form PO4-3
13.
x ml of 0.1 M NaOH + x mL of 0.01 M HCI
No. of moles of NaOH = 0.1 x X x 10-3
= 0.1 X x 10-3
No. of moles of HCI = 0.01 x X x 10-3
= 0.01 X x 10-3
No. of moles of NaOH after mixing
= 0.1 X x 10-3 - 0.01 X x 10-3
= 0.09 X x 10-3
Concentration of NaOH\(= (\frac{0.09x \times 10^{-3}}{2x \times 10^{-3}}) = 0 .045\)
[OH-] = 0.045
pOH =-log (4.5 x 10-2)
= 2 -log 4.5
= 2 - 0.65 = 1.35
pH = 14 - 1.35 = 12.65
14.
(a)
10-10
15.
AgCl(s) ⇌ Ag+(aq) + Cl-(aq)
NaCl → Na+ +Cl-
0.1M 0.1M 0.1M
Ksp = 1.6 × 10-10
Ksp = [Ag+][ Cl-]
Ksp = (s) (s + 0.1)
0.1 >>> s
∴ s + 0.1 = 0.1
∴ s = 1.6 × 10-10/ 0.1 = 1.6 × 10-9
16.
C5H5N + H-OH ⇌ C5H5 +NH + OH-
\(\frac { { \alpha }^{ 2 }{ C } }{ 1-\alpha } =K_b\)
\(\alpha\)2C \(\approx\) Kb
\(\alpha = \sqrt {\frac{K_b} C} = \sqrt {\frac{1.7 \times 10^{-9}} {0.1}}\)
\(= \sqrt{1.7} \times 10^{-4}\)
Percentage of dissociation =\(= \sqrt{1.7} \times 10^{-4}\) x 100
= 1.3 x 10-2 = 0.013%
17.
(c)
CH3-CH2->NH2->H-C≡C->OH-
18.
BF3 → electron deficient → Lewis acid
PF3 → electron rich → Lewis base
CF4 → neutral → neither Lewis acid nor base
SiF4 → neutral → neither Lewis acid nor base
19.
H2O + H2O ⇌ H3O+ + OH-
acid 1 base 1 acid 2 base 2
HF + H2O ⇌ H3O+ + F-
acid 1 base 1 acid 2 base 2
∴ Conjugate bases are OH- and F- respectively.
20.
\(\mathrm{Ag}_{2} \mathrm{C_2O_4} \rightleftharpoons 2 \mathrm{Ag}_{}^{+}+\mathrm{C_2O}_{4{}}^{2-}\)
\(\left[\mathrm{Ag}^{+}\right]=2 .24 \) ×10-4mol L-1
\(\mathrm{C_2O}_{4{}}^{2-} = \frac {2.24 \times 10 ^{-4}}{2}\) mol L-1
= 1.12 ×10-4mol L-1
Ksp = [Ag]2 [C2O42-]
= (2.24 ×10-4mol L-1) (1.12 ×10-4mol L-1)
= 5.619 × 10-12mol3L-3
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