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Published on: 02/06/2021
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Questions + Answers key
Take MCQ Chemistry Test1.
How are vitamins classified?
2.
Classify the following into monosaccharides, oligosaccharides and polysaccharides.
i) Starch
ii) fructose
iii) sucrose
iv) lactose
iv) maltose
3.
Why carbohydrates are generally optically active.
4.
Write a note on denaturation of proteins.
5.
What are reducing and non – reducing sugars?
1.
Vitamins are classified into two groups based on their solubility in water or in fat.
(a) Fat soluble vitamins:
These vitamins absorbed best when taken with fatty food and are stored in fatty tissues and livers. These vitamins do not dissolve in water. Hence they are called fat soluble vitamins. Vitamin A, D, E & K are fatsoluble vitamins.
(b) Water soluble vitamins:
Vitamins B (B1, B2, B3, B5, B6, B7, B9 & B12) and C are readily soluble in water. On the contrary to fat soluble vitamins, these can't be stored. The excess vitamins present will be excreted through urine and are not stored in our body. Hence, these two vitamins should be supplied regularly to our body.
2.
i) Starch - Polysaccharide
ii) fructose - monosaccharide
iii) sucrose - oligosaccharides
iv) lactose - oligosaccharides
iv) maltose - oligosaccharides
3.
(i) Almost all carbohydrates are optically active as they contain one or more chiral carbons.
(ii) The number of optical isomers depends upon the number of chiral carbons (ie) 2n isomers, where n = total number of chiral carbons.
(iii) Glucose has \(4{ }^{\star} \)C; ∴ It has 24 =16 isomers.
4.
(i) Each protein has a unique three-dimensional structure formed by interactions such as disulphide bond, hydrogen bond, hydrophobic and electrostatic interactions. These interactions cain be disturbed when the protein is exposed to a higher temperature, certain chemicals such as urea, alteration of pH, ionic strength etc., It leads to the loss of the three-dimensional structure partially or completely. The process of a losing its higher order structure without losing the primary structure, is called denaturation. When a protein denatures, its biological function is also lost.
(ii) Since the primary structure is intact, this process can be reversed in certain proteins. This can happen spontaneously upon restoring the original conditions or with the help of special enzymes called cheperons (proteins that help proteins to fold correctly).
(iii) Example: coagulation of egg white by action of heat.
5.
i) Reducing sugars:
1. Sugars which reduce Tollen's reagent or Fehling's solution or Benedict's solution are called reducing sugars.
2. These contain either α - hydroxyl ketone or cyclical hemi acetal or hemi ketal or structures in equilibrium with open chain forms having a free- CHO or C=O group.
3. E.g. a) All monosaccharide's like D - glucose, D - fructose (aldoses and ketoses)
b) Sugars like Lactose and maltose except sucrose.
ii) Non - reducing sugars:
1. Sugars which do not reduce either Tollen's reagent, Fehling's solution or Benedict's solution are called non-reducing sugars.
2. They contain a stable acetal or ketal structures which cannot be opened into a free carbonyl group.
E.g. Sucrose, starch, cellulose, glycogen, dextrin etc.
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