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Published on: 13/05/2022
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Questions + Answers key
Take MCQ Chemistry Test1.
What are stoichiometric defects in ionic solids? Explain
2.
Explain the following: Similarities and differences between metallic and ionic crystals.
3.
An element with molar mass 2.7 x 10-2 kg mol forms a cubic unit cell with edge length 405 pm. If its density is 2.7 x 103 kg m-3, What is the nature of the cubic unit cell?
4.
What are the general characteristics of solids?
5.
Ionic solids, which have anionic vacancies due to metal excess defect, develop colour. Explain with the help of a suitable example.
1.
Schottky defect:
(i) Schottky defect arises due to the missing of equal number of cations and anions from the crystal lattice.
(ii) This effect does not change the stoichiometry of the crystal.
(iii) Ionic solids in which the cation and anion are of almost of similar size show schottky defect. Ex: NaCl.
(iv) Presence of large number of schottky defects in a crystal, lowers its density.
Frenkel defect:
(i) Frenkel defect arises due to the dislocation of ions from its crystal lattice.
(ii) The ion which is missing from the lattice point occupies an interstitial position.
(iii) This defect is shown by ionic solids in which cation and anion differ in size.
(iv) Unlike Schottky defect, this defect does not affect the density of the crystal.
(v) For example AgBr, in this case, small Ag+ ion leaves its normal site and occupies an interstitial position.
2.
(i) Similarities between ionic and metallic crystals:
(a) Ionic and metallic crystals have electrostatic forces of attraction.
(b) Both the crystals exhibit high melting point.
(c) The bonds in metallic and ionic crystals are non-directional.
(ii) Differences between ionic and metallic crystals:
| Property | Ionic Crystals | Metallic Crystals |
| Electrical conductivity | They conduct electricity in the molten state or in aqueous solution but not in solid state. | They conduct electricity in solid state as well as in molten state. |
| Binding forces | It is strong due to electrostatic forces of attraction. | It may be weak or strong depending upon the number of valence electrons. |
| Physical nature | Ionic crystals are hard but brittle | Metallic crystals are usually hard and malleable. |
3.
Density of the element, d = 2.7 x 103 kg m-3
Molar mass, M = 2.7 x 10-2 kg mol-1
Edge length, a = 405 pm
= 405 x 10-12 m
= 4.05 x 10-10 m
Avogadro's number, NA= 6.022 x 1023 mol-1
\(\therefore d=\frac { Z\times M }{ { a }^{ 3 }\times { N }_{ A } } \)
\(\Rightarrow Z=\frac { d\times { a }^{ 3 }{ N }_{ A } }{ M } \)
\(=\frac { 2.7\times { 10 }^{ 3 }kg\quad { m }^{ -3 }{ (4.05\times { 10 }^{ -10 }m) }^{ 3 }\times 6.022\times { 10 }^{ 23 }{ mol }^{ -1 } }{ 2.7\times { 10 }^{ -2 }kg\quad { mol }^{ -1 } } \)
= 4.004 = 4.
This implies that four atoms of the element are present per unit cell. Hence the unit cell is face centred cubic.
4.
(i) Solids have definite volume and shape
(ii) Solids are rigid and incompressible
(iii) Solids have strong cohesive forces.
(iv) Their constituents have fixed positions and can only oscillate about their mean positions.
5.
(i) The colour develops because of the presence of electrons in the 8 anionic sites.
(ii) These electron absorb energy from the visible region of radiation and get excited.
(iii) For example when crystals of NaCl are heated in an atmosphere of sodium vapours, the sodium atoms get deposited on the surface of the crystal and the deposited Na atoms.
(iv) During this process, the Na atoms on the surface lose electrons to form Na+ ions
(v) These electrons get excited by absorbing energy from the visible light and impart yellow colour to the crystals.
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