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Published on: 13/05/2022
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Questions + Answers key
Take MCQ Chemistry Test1.
Justify the position of lanthanoids and actinoids in the periodic table.
2.
What are inner transition elements?
3.
Explain why compounds of Cu2+ are coloured but those of Zn2+ are colourless.
4.
Why Gd3+ is colourless?
5.
What are actinides? Give three examples.
1.
(i) The actual position of Lanthanides in the periodic table is at group number 3 and period number 6. However, in the sixth period after lanthanum, the electrons are preferentially filled in inner 4f sub shell and these fourteen elements following lanthanum show similar chemical properties.
(ii) Similarly the fourteen elements following actinium resemble in their physical and chemical properties. Hence they are placed separately bottom of the modern periodic table.
2.
(i) The elements in which the extra electron enters (n-2) f orbitals are called f-block elements. These elements are called as inner transition elements because they form a transition. Series within the transition elements.
(ii) The f-block elements are also called as rare earth elements. They are divided into lanthanoid series (4f block elements) and actinoid series (5f block elements).
3.
(i) The compounds of Cu2+ are coloured as it has one free electron its valence shell which absorb I radiation of visible region and get excited to emit its complementary colour.
(ii) Zn has no free electron it has fully filled shells. Due to extra stable orbitals electron can't be excited by radiations of visible light, hence its compounds are colourless.
4.
In Gd+3 there are 64 electrons. Hence electronic configuration will be [Xe]4f7 5d1 6s2. Hence no electrons are there in outer d - orbital. Due to this it is colourless.
5.
The fourteen elements following actinoids is from thorium to lawrencium are called actinides.
Examples: Uranium, Thorium, Neptunium
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