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Published on: 13/05/2022
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Questions + Answers key
Take MCQ Chemistry Test1.
Which metal in the 3d series exhibits +1 oxidation state most frequently and why?
2.
Which is stronger reducing agent Cr2+ or Fe2+?
3.
Why europium (II) is more stable than Cerium (II)?
4.
Predict which of the following will be coloured in aqueous solution Ti2+, V3+, Sc4+, Cu+, Sc3+, Fe3+, Ni2+ and Co3+
5.
Transition metals show high melting points. Why?
1.
Copper exhibits +1 oxidation state most frequently Cu (29) - electronic configuration 3d104s1 copper ready to lose outer most one electron to attain the stable full filled electronic configuration. Hence it exhibits +1 oxidisation state.
2.
Cr2+ is stronger reducing agent than Fe2+. The standard electrode potential (E0) of Cr2+ is -0.91 V and that of Fe2+ is only -0.44 V.
If the standard electrode potential of a metal is large and negative is a powerful reducing agent, because it loses electrons easily.
Hence Cr2+ is stronger reducing agent.
3.
\(Eu (63)-[\mathrm{Xe}] 4 \mathrm{f}^{7} 5 \mathrm{~d}^{0} 6 \mathrm{~s}^{2}, \mathrm{Eu}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^{7} \)
\(\mathrm{Ce}(58)-[\mathrm{Xe}] 4 \mathrm{f}^{1} 5 \mathrm{~d}^{1} 6 \mathrm{~s}^{2}, \mathrm{Ce}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^{1} 5 \mathrm{~d}^{1} \)
Eu2+ has exactly half filled stable electronic configuration. Hence Europium (II) is more stable than Cerium (II).
4.
(i) Only the ions that have unpaired electrons in d- orbital and in which d - d transition is possible will be coloured.
(ii) The ions in which d - orbitals are empty or completely filled will be colourless as no d -d transition is possible in those configurations.
(iii) From the above ions, it can be easily observed that only Sc3+ has an empty d - orbital and Cu+ has completely filled d-orbitals.
(vi) All other ions, except Sc3+ and Cu+, will be coloured in aqueous solution because of d - d transition.
5.
(i) Transition metals have number of unpaired electron. They are involved in metallic bonding. Hence they show high melting point.
(ii) As we move from left to right along the transition metal series melting point first increases reach a maximum value and then decreases as the d-electrons pair up and become less available for bonding.
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