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TN 12th Computer Applications மின்னணு தரவு பரிமாற்றம் Sample Question Papers Study Material - QB365 Set A
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TN 12th Computer Applications மின்னணு செலுத்தல் முறைகள் Sample Question Papers Study Material - QB365 Set A
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TN 12th Computer Applications திறந்த மூல கருத்துருக்கள் Sample Question Papers Study Material - QB365 Set A
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TN 12th Computer Applications வலையமைப்பு வடமிடல் Sample Question Papers Study Material - QB365 Set A

Published on: 25/09/2019
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
Questions + Answers key
Take MCQ Chemistry Test1.
The half-life period of a first order reaction is 69.3 seconds. Its rate constant is ________.
10-2 s-1
10-4 s-1
10 s-1
102 s-1
2.
Activation energy is equal to _______.
Threshold energy + Energy of colliding molecules
Threshold energy
Threshold energy x Energy of colliding molecules
Threshold energy - Energy of colliding molecules
3.
Energy of activation of a reactant is reduced by ________.
reduced pressure
increased pressure
reduced temperature
increased temperature
4.
Rate law cannot be determined from balanced chemical equation if ______.
Reverse reactions is not involved
It is an elementary reaction
It is a sequence of elementary reactions
All of the reactants is in excess. Rate law can be determined from balanced chemical equation if it is an elementary reaction.
5.
In the graph showing Maxwell, Boltzmann distribution of energy _____.
area under the curve must not change with increase in temperature.
area under the curve increases in temperature.
area under the curve decreases with increase in temperature.
None of these above
6.
Which one of the following is an example of pseudo first order reaction?
Acid hydrolysis of ester
Decomposition of HI
Synthesis of NH3
All radioactive transformations
7.
If the initial concentration of the reactants is doubled, then rate _____.
remains constant
doubled
is reduced to half of its value
is increased by four times of initial rate
8.
Compound A reacts by first order kineties. At 25oC, the rate constant of the reaction is 0.60 sec. What is the half life of A?
1.15 sec
0.4158 sec
0.093 sec
1.29 sec
9.
For a reaction: aA ⟶ bB, the rate of reaction is doubled when the concentration of A is increased by four times. The rate of reaction is equal to _____.
k[A]a
\(k{ \left[ A \right] }^{ \frac { 1 }{ 2 } }\)
\(k{ \left[ A \right] }^{ \frac { 1 }{ a } }\)
K[A]
10.
The term A in Arrhenius equation is called as _____.
Probability factor
Activation energy
Collision factor
Frequency factor
11.
During decomposition of an activated complex.
energy is always released
energy is always absorbed
energy does not change
products may be formed.
12.
For the following reaction, identify the order of reaction and dimension of the rate constant.
H2O2(aq) +3I-(aq) + 2H+ ⟶ 2H2O(1) + I3- ; Rate = k[H2O2] [I]-
2, L mol-1 s-1
1. s-1
\(\frac { 3 }{ 2 } \), L1/2 mol-1/2 s-1
None of these
13.
2A ⟶ B + C. It would be a zero order reaction when ______.
The rate of reaction is proportional to square of conc. of A
The rate of reaction remains same at any conc. of A.
The rate of remains unchanged at any conc. of B and C
The rate of reaction doubles if conc. of B is increased to double.
14.
Which of the following does not affect the rate of reaction?
Amount of the reactant taken
Physical state of the reactant
∆H of reaction
Size of vessel
15.
What would be the activation energy of a reaction when the temperature is increased from 27oC to 37oC?
534 kJ mol-1
53.4 kJ mol-1
5.34 kJ mol-1
None of these
16.
The high reactivity of fluorine is due to________.
high ionisation energy
low bond dissociation energy
low electron affinity
high electro negativity
17.
Oxidation states of P in H4P2O5, H4P2O6, H4P2O7 are respectively _______.
+3, +4, +5
+3, +5, +4
+5, +3, +4
+5, +4, +3
18.
Repeated use of which one of the following fertilizers would increase the activity of the soil_______.
Ammonium sulphate
Superphosphate of lime
Urea
Potassium nitrate
19.
The incorrect statement regarding structure of ozone is______.
Bond angle is less than 120°
It is linear
The two oxygen-oxygen bond length in ozone are identical
Both (b) and (c).
20.
Orthophosphorus acid on heating gives______.
Hypophosphorous
Orthophosphoric acid
Phosphine gas
both (b) and (c)
21.
Least volatile hydrogen halide is ______.
HF
HCI
HBr
HI
22.
When Copper is heated with cone HNO3 it produces
Cu (NO3)2 and N2O
Cu (NO3)2 and NO2
Cu (NO3)2 and NO
Cu (NO3)2 NO and N2O
23.
Which is dibasic?
Orthophosphoric acid
Pyrophosphoric acid
Orthophosphorus acid
Hypophosphorous acid
24.
Catenation property of group 15 elements, follow the order _______.
N < P < As < Sb < Bi
P >> N > As > Sb > Bi
P < N < As < Sb < Bi
N>> P > As > Sb > Bi
25.
Which of the following is correct?
H3PO3 is dibasic and reducing
H3PO3 is dibasic and non-reducing
H3PO4 is tribasic and reducing
H3PO3 is tribasic and non-reducing
26.
Crystals of NaCI has yellow colour due the presence of_________.
cation vacancy
F centres
both (a) and (b)
neither (a) nor (b)
27.
If electrical conductivity is found to be same in all directions through a solid the substance is ________ solid and the property is called _________.
crystalline, isotropy
amorphous, isotropy
crystalline, anisotropy
amorphous, isotropy
28.
The seven primitive crystal systems differ in the _______ arrangement.
crystallographic axes
angles
both (a) and (b)
Neither (a) or (b )
29.
A crystal which has the same unit cell and contains the same lattice points throughout the crystal is_________.
perfect
imperfect
distorted
both (b) and (c)
30.
An example of covalent crystal is _________.
CsCl
NaCl
ice
diamond
31.
The number of cesium ion per unit cell in CsCI crystal system is________.
4
8
6
1
32.
In a face centred cubic cell, an atom at the face contributes to the unit cell_______.
\(\frac{1}{4}\)Part
1Part
\(\frac{1}{2}\)Part
\(\frac{1}{8}\)Part
33.
The number of chloride ions present per unit of CsCI are _______.
6
8
1
4
34.
In an hexagonal crystal _______.
a=b=c,∝ =β=૪=90°
a=b=c,∝ =β=૪≠90°
a=b≠c,∝ =β=૪=90°
a=b≠c,∝ =β=90°૪=120°
35.
Which one of the following statements is wrong about Frenkel defect?
An ion occupies an interstitial position
Anion is much larger in size than the cation
The crystal remains neutral
Non-stoichiometric compound is formed
36.
Which type of defect is found in transition metals that have variable valency?
Frenkel defect
Schottky defect
Line defect
Metal deficiency defect
37.
The defect arising due to an ion occupying interstitial position is called _______.
Schottky defect
Metal excess defect
Frenkel defect
Metal deficiency defect
38.
Which one of the following statements is not true?
The heat of vaporisation of ionic crystals are high
Ionic crystals are soluble in non-polar solvent
Ionic crystals are hard and brittle
Ionic crystals are conductors in solution state
39.
The wavelength of X-ray is in the order of _______.
10-8 cm
10-10 c
10-8 m
10-10 nm
40.
Pick out the example for covalent and molecular crystal.
Ice, Diamond
Diamond, Ice
NaCl, FeS
FeS, Ice
41.
In the Bragg's equation for diffraction of X-rays, 'n' represents _______.
The number of moles
Avogadro number
A quantum number
Order of reflection
42.
Three atoms P, Q and R crystallize in a cubic solid lattice having P atom at corners Q atom at body centre and R atom at the face centres. Identify formula of the compound _______.
PQR
PQR2
PQR3
P3QR
43.
Borax is _______.
Na2[B4O5(OH)4).8H2O
Na2[B4O5(OH)6).7H2O
Na2[B4O3(OH)8].6H2O
Na2[B4O2(OH)10).5H2O
44.
Silicones are ______.
ortho silicates
water repellent thermal insulators
both (a) and (b)
None of these
45.
The silicates which contain discrete tetrahedral units are _______.
ortho silicates
sheet silicates
pyrosilicates
three dimensional silicates
46.
Allotropy is due to ______.
difference in chemical properties
difference in the number of atoms in the molecules
difference in the arrangement of atoms in the molecules in the crystal
None of these
47.
If 'a' is the length of unit cell, then which one is correct relationship?
For simple cubic lattice, radius of metal atom =\(\frac{a}{2}\)
For bee lattice, radius of metal atom \(=\frac { \sqrt { 3a } }{ 4 } \)
For fcc lattice, radius of metal atom \(=\frac { a }{ 2\sqrt { 2 } } \)
All of these
48.
A solid with formula ABC3 would probably have, _______.
A at body centre, B at face centres and C at corners of the cube
A at corners of cube, B at body centre, C at face centre
A at corners of hexagon, B at centres of the hexagon and C inside the hexagonal unit cell
A at corner, B at face centre, C at body centre
49.
Group 14 elements have general electronic configuration _______.
ns2
ns2np4
ns2np6
ns2np2
50.
All elements except carbon have the tendency to show maximum covalency of six ______
due to presence of vacant d-orbitals
due to absence of vacant d-orbitals
due to presence of partially filled d-orbitals
due to presence of completely filled d-orbitals
51.
Boron compounds behave as Lewis acid, because of their _______.
ionisation property
acidic nature
covalent nature
electron deficient nature
52.
Which one is correct statement for zeolite?
Zeolites are aluminosilicates having three dimensional framework
Hydrate zeolites are used as ion exchangers in hardening of soft water
Zeolites are alumino silicates
all the above
53.
Chemical formula of phosgene is_______.
COCl2
CaOCl2
CaCO3
COCI
54.
Which one of the following compounds has similar structure to that of graphite?
Boron nitride
Boron Carbide
Aluminium Carbide
Aluminium Oxide
55.
A mixture of TiCl4 and trialkyl aluminium is _________
hydroformylation of obfine
Zeigler - Natta Catalyst
interstitial compounds
ferromagnetic
56.
The general electronic configuration of 4f series of elements can be written as ________.
[Xe]4f2-14 5d0-46s2
[Xe]4f2-145d0-46s1
[Xe] 4f1-14506s1
[Xe]4f2-145d0-46s1
57.
Equivalent weight of KMnO4 in acidic medium is _______.
3.16
31.6
158
52.67
58.
The electronic configuration of Sc is ______.
[Ar] 3d1 4s2
[Ar] 3d2 4S1
[Ar] 3d5 4S1
[Ar] 3d3 4S1
59.
In black and white photography, the developed film is fixed by washing with ______.
Hypo solution
AgBr solution
Na2S4O6 solution
FeC2O4 solution
60.
On oxidation with KMnO4 in acidic medium, SO2 is oxidised to _______.
SO2
H2SO4
SO32-
H2S
61.
Which of the following ions will exhibit colour in aqueous solutions?
SC3+(Z=21)
Ti3+(Z =22)
La3+(Z=57)
Lu3+(Z=71)
62.
Identify the correct reason for lanthanide contraction.
Decreasing nuclear charge
Decreasing screening effect
Increasing nuclear charge
Negligible screening effect
63.
The reaction of aqueous KMnO4 with H2O2 in acidic condition gives_______.
Mn4+ and MnO2
Mn4+ and O2
Mn2+ and O2
Mn2+ and O3
64.
Which of the following statement is correct for 3d-transition element?
All metals except Zn and Sc form 'MO' Oxide
All metals except Sc forms 'MO' Oxide
All metals except Zn forms 'MO' Oxide
All metals except Mn forms 'MO' Oxide
65.
What are the species X and Y in the following?
CrO3, CrO42-
CrO3, Cr2O3
CrO4-2, Cr2O72-
H2CrO4, H2Cr2O7
66.
The lanthanide contraction is responsible for the fact that _______.
Zr and Zn have the same oxidation state
Zr and Hf have almost the same radius
Zr and Nb have similar oxidation state
Zr and Y have similar radius
67.
The trend in ionisation enthalpy of a transition element is not regular because,_______.
removal of one electron alters the relative energies of 4s and 3d orbitals
due to different electronic configuration (stability)
Poor screening of 3p-orbital
due to decrease in effective nuclear charge
68.
The highest possible oxidation state shown by osmium in its compound is_______.
+4
+6
+8
+10
69.
Most of the transition metal ions are coloured, because of the ________.
presence of unpaired electrons
energy gap between two energy levels is very small
both (a) and (b)
neither (a) nor (b)
70.
Galena is_______.
PbS
ZnS
Ag2S
FeS2
71.
The percentage of carbon in high carbon steel is_________.
0.5 - 1%
0.15 - 1.5%
0.15 - 1.5%
0.15 - 0.3%
72.
\({ Zn }_{ (s) }+2\left[ Au(CN)_{ 2 } \right] ^{ - }_{ (aq) }\longrightarrow \left[ Zn(CN)_{ 4 } \right] ^{ 2- }_{ (aq) }+2A{ { u }_{ (s) } }\) In the above equation the oxidation state of metallic gold is_______
1
0
+2
-2
73.
Na[Ag(CN)2] is _________.
Sodium aurocyanide
Sodium meta aluminate
Aluminosilicate
Sodium dicyanoargentate
74.
Malachite has______ composition.
2CuCO3.Cu(OH)2
CuCO3.Cu(OH)2
Cu2O
Cu2S
75.
Pick out the alloy that contains a non-metal as a constituent in it ________.
Brass
Bronze
Steel
Invar
76.
\(\Delta { G }^{ o }\) vs T plot in the Ellingham's diagram slopes downward the reaction ________.
\(Mg+\frac { 1 }{ 2 } { O }_{ 2 }\longrightarrow MgO\)
\(C+\frac { 1 }{ 2 } { O }_{ 2 }\longrightarrow CO\)
\(2Ag+\frac { 1 }{ 2 } { O }_{ 2 }\longrightarrow { Ag }_{ 2 }O\)
\(2Ag+\frac { 1 }{ 2 } { O }_{ 2 }\longrightarrow { Ag }_{ 2 }O\)
77.
The blistered appearance of Cu obtained from the reverberatory furnace is due to evolution of________.
CO2 gas
SO2 gas
NO2
Due to evaporation of volatile materials
78.
Sodium magnesium and aluminum can be obtained from their ore by________.
electro metallurgy
pyro metallurgy
hydro metallurgy
smelting
79.
Identify the decreasing order of carbon content in different forms of iron________.
Wrought iron > Pig iron > cast iron
Cast iron > Pig iron > Wrought iron
Pig iron > Cast iron > Wrought iron
Cast iron > Wrought iron > Pig iron
80.
The structure of hexaaquatitanium (III) ion is _______.
[Ti(H2O)6]3+
[Ti(H2O)6]3-
[Ti(H2O)5]H2O
[Ti(H2O)6]
81.
Magnetic moment is given by the formula _______.
\(\sqrt { n(n+1) } \)
\(\sqrt { n(n+2) } \)
\(\sqrt { (n+2) } \)
\(\sqrt { { n }^{ 2 }+(n+2) } \)
82.
The chemical formula for diammine silver (I) chloride is _______.
[Ag(NH3)2] Cl
[Ag(NH3)]Cl
[Ag(NH2)2]Cl
[Ag(NH4)2]Cl
83.
In co-ordination complexes, ligand ammonia is written as _______.
ammine
amine
ammonal
none of these
84.
Crystal field stabilization energy for high spin d4 octahedral complex is ______.
- 0. 6 \({ \triangle }_{ 0 }\)
- 1. 8 \({ \triangle }_{ 0 }\)
- 1. 6 \({ \triangle }_{ 0 }\)
- 1. 4 \({ \triangle }_{ 0 }\)
85.
An example of ambidentate ligand is _________.
cyano
nitro
chloro
triphenylphosphine
86.
The ligand capable of coordinating in two or more ways with the central metal ion are called _______ ligands.
didentate
tridentate
ambidentate
none of the above
87.
The coordination polyhedron of the complex [Cr(H2O)6]CI3 is________.
square planar
tetrahedral
trigonal
octahedral
88.
The ionisation isomer of [Cr(H2O)4CI(NO2)]Cl is _________.
[Cr(H2O)4Cl2(NO)2]
[Cr(H2O)4Cl2]NO2
[Cr(H2O)4Cl(ONO)]
both (a) and (b)
89.
A 'd' block metal ion has a magnetic moment of 1.732 BM. The number of unpaired electrons are _______.
1
2
3
4
90.
The coordination number of Ni(II) in [Ni(CN)4]2- is _______.
2
4
5
0
91.
The geometry of [Cu(NH3)4]2+ complex ion _______.
Linear
Tetrahedral
Square planar
Angular
92.
An example of a complex compound having coordination number 4 _______.
K4[Fe(CN)6]
[Co(en)3]Cl
[Fe(H2O)6]Cl3
[Cu(NH3)4]Cl2
93.
Which is a double salt?
K2SO4AI2(SO4)324H2O
NaCI
K4[Fe(CN)6]
KCl
94.
Which of the following will exhibit linkage isomerism?
[Co(NH3)5 (NO2)]2+
[Co(H2O)5CO)]3+
[Fe(en)2CI2]+
all the above
95.
Coordination compounds are stabilised by Chelate effect. Which among the following is the most stable complex?
[Fe(CN)6]3-
[Fe(Co)5]
[Fe(NH3)6]3+
[Fe(C2O4)3]3-
96.
Predict the geometry and hybridisation of Fe(Co)5 _______.
Trigonal planar, dsp3
Trigonal bipyramidal, dsp3
Square planar dsp2
Octahedral d2sp3
97.
The hypothetical complex triamminediaqua chloridocobalt (III)chloride can be represented as _______.
[Co(NH3)3(H2O)2Cl]Cl2
[Co(NH)3(H2O)Cl3]
[Co(NH2)3(H2O)2Cl]
[Co(NH3)3(H2O)3]Cl3
98.
Among the following complexes the one which shows zero crystal field stabilisation energy is _______.
[Mn(H2O)6]3+
[Fe(H2O)6]3+
[CO(H2O)6]2+
[CO(H2O)6]3+
99.
The total number of electrons donated by ligands to platinum ion in [Pt(en)2CI2] is _______.
8
10
12
14
1.
(a)
10-2 s-1
2.
(a)
Threshold energy + Energy of colliding molecules
3.
(d)
increased temperature
4.
(c)
It is a sequence of elementary reactions
5.
(a)
area under the curve must not change with increase in temperature.
6.
(a)
Acid hydrolysis of ester
7.
(d)
is increased by four times of initial rate
8.
(a)
1.15 sec
9.
(b)
\(k{ \left[ A \right] }^{ \frac { 1 }{ 2 } }\)
10.
(d)
Frequency factor
11.
(a)
energy is always released
12.
(a)
2, L mol-1 s-1
13.
(b)
The rate of reaction remains same at any conc. of A.
14.
(c)
∆H of reaction
15.
(d)
None of these
16.
(b)
low bond dissociation energy
17.
(a)
+3, +4, +5
18.
(a)
Ammonium sulphate
19.
(b)
It is linear
20.
(d)
both (b) and (c)
21.
(a)
HF
22.
(b)
Cu (NO3)2 and NO2
23.
(c)
Orthophosphorus acid
24.
(b)
P >> N > As > Sb > Bi
25.
(a)
H3PO3 is dibasic and reducing
26.
(b)
F centres
27.
(b)
amorphous, isotropy
28.
(c)
both (a) and (b)
29.
(a)
perfect
30.
(d)
diamond
31.
(d)
1
32.
(c)
\(\frac{1}{2}\)Part
33.
(c)
1
34.
(d)
a=b≠c,∝ =β=90°૪=120°
35.
(d)
Non-stoichiometric compound is formed
36.
(d)
Metal deficiency defect
37.
(c)
Frenkel defect
38.
(b)
Ionic crystals are soluble in non-polar solvent
39.
(a)
10-8 cm
40.
(b)
Diamond, Ice
41.
(d)
Order of reflection
42.
(c)
PQR3
43.
(a)
Na2[B4O5(OH)4).8H2O
44.
(c)
both (a) and (b)
45.
(b)
sheet silicates
46.
(c)
difference in the arrangement of atoms in the molecules in the crystal
47.
(d)
All of these
48.
(b)
A at corners of cube, B at body centre, C at face centre
49.
(d)
ns2np2
50.
(a)
due to presence of vacant d-orbitals
51.
(d)
electron deficient nature
52.
(d)
all the above
53.
(a)
COCl2
54.
(a)
Boron nitride
55.
(b)
Zeigler - Natta Catalyst
56.
(a)
[Xe]4f2-14 5d0-46s2
57.
(b)
31.6
58.
(a)
[Ar] 3d1 4s2
59.
(a)
Hypo solution
60.
(b)
H2SO4
61.
(b)
Ti3+(Z =22)
62.
(d)
Negligible screening effect
63.
(c)
Mn2+ and O2
64.
(b)
All metals except Sc forms 'MO' Oxide
65.
(a)
CrO3, CrO42-
66.
(b)
Zr and Hf have almost the same radius
67.
(a)
removal of one electron alters the relative energies of 4s and 3d orbitals
68.
(c)
+8
69.
(c)
both (a) and (b)
70.
(a)
PbS
71.
(b)
0.15 - 1.5%
72.
(b)
0
73.
(d)
Sodium dicyanoargentate
74.
(b)
CuCO3.Cu(OH)2
75.
(c)
Steel
76.
(b)
\(C+\frac { 1 }{ 2 } { O }_{ 2 }\longrightarrow CO\)
77.
(b)
SO2 gas
78.
(a)
electro metallurgy
79.
(c)
Pig iron > Cast iron > Wrought iron
80.
(a)
[Ti(H2O)6]3+
81.
(b)
\(\sqrt { n(n+2) } \)
82.
(a)
[Ag(NH3)2] Cl
83.
(a)
ammine
84.
(a)
- 0. 6 \({ \triangle }_{ 0 }\)
85.
(b)
nitro
86.
(c)
ambidentate
87.
(d)
octahedral
88.
(b)
[Cr(H2O)4Cl2]NO2
89.
(a)
1
90.
(b)
4
91.
(c)
Square planar
92.
(d)
[Cu(NH3)4]Cl2
93.
(a)
K2SO4AI2(SO4)324H2O
94.
(a)
[Co(NH3)5 (NO2)]2+
95.
(d)
[Fe(C2O4)3]3-
96.
(b)
Trigonal bipyramidal, dsp3
97.
(a)
[Co(NH3)3(H2O)2Cl]Cl2
98.
(b)
[Fe(H2O)6]3+
99.
(c)
12
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