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Published on: 28/11/2025
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Sodium metal crystallizes in bcc structure with the edge length of the unit cell 4.3 x 10-8 cm. Calculate the radius of sodium atom.
2.
3.
Differentiate crystalline solids and amorphous solids.
4.
Give the limitations of Ellingham diagram.
5.
Aluminium crystallizes in a cubic close packed structure. Its metallic radius is 125pm. calculate the edge length of unit cell.
6.
Explain briefly seven types of unit cell.
1.
For bcc structure \((r)=\frac{\sqrt{3}}{4} a\)
a = 4.3 \(\times\) 10-8 cm, r = ?
\(=\frac{1.732 \times 4.3 \times 10^{-8}}{4}\)
\(r=1.86 \times 10^{-8} \mathrm{~cm}\)
2.
3.
| S. No | Crystalline Solids | Amorphous Solids |
| 1. | Long range orderly arrangement of constituents. | Short range, random arrangement of constituents. |
| 2. | Definite shape | Irregular shape |
| 3. | Anisotropic in nature | They are "isotropic" like liquids |
| 4. | They are true solids | They are considered as pseudo solids (or) super cooled liquids |
| 5. | Definite Heat of fusion | Heat of fusion is not definite |
| 6. | They have sharp melting points. | Gradually soften over a range of temperature and so can be moulded. |
| 7. | Eg: NaCl, diamond etc. | Eg: Rubber, plastics, glass etc. |
4.
(i) Ellingham diagram is constructed based only on thermodynamic considerations. It gives information about the thermodynamic feasibility of a reaction. It does not tell anything about the rate of the reaction. More over, it does not give any idea about the possibility of other reactions that might be taking place.
(ii) The interpretation of \(\triangle\)G is based on the assumption that the reactants are in equilibrium with the product which is not always true.
5.
For cubic closed packed structure
\(r =\frac{a \sqrt{2}}{4} \)
\(\therefore a =\frac{4 r}{\sqrt{2}} \)
\(=\frac{4 \times 1.25 \times 10^{-8}}{1.414}=3.53 \times 10^{-8} \mathrm{~cm} \)
= 353 pm
6.
There are seven types of unit cell, Cubic, tetragonal, orthorhombic, hexagonal, monoclinic, triclinic and rhombohedral. They differ in the arrangement of their crystallographic axes and angles.
i) Cubic: a = b = c; α = β = ૪ = 90o.
ii) Tetragonal: a = b ≠ c; α = β = ૪ = 90°.
iii) Orthorhombic: a ≠ b ≠ c; α = β = ૪ = 90°.
iv) Hexagonal: a = b ≠ c; α = β = 90o, ૪ = 120o.
v) Monoclinic: a ≠ b ≠ c; α = ૪ = 90o, β ≠ 90o,
vi) Triclinic: a ≠ b ≠ c; α ≠ β ≠ ૪ ≠ 90o.
vii) Rhombohedral: a = b = c; α = β = ૪ ≠ 90o.
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