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Published on: 28/11/2025
Download Tamil Nadu 12th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Natural rubber has _______.
alternate cis- and trans-configuration
random cis- and trans-configuration
all cis-configuration
all trans-configuration
2.
Glucose is an aldose. Which one of the following reactions is not expected with glucose?
It does not form oxime
It does not react with Grignard reagent
It does not form osazones
It does not reduce tollens reagent
3.
When is reduced with Sn / HCl the pair of compounds formed are _______.
Ethanol, hydrozylamine hydrochloride
Ethanol, ammonium hydroxide
Ethanol, NH2OH
C3H5NH2, H2O
4.
The IUPAC name of
but – 3- enoicacid
but – 1- ene-4-oic acid
but – 2- ene-1-oic acid
but -3-ene-1-oicacid
5.
6.
Which one of the following is correctly matched?
Emulsion - Smoke
Gel - butter
foam - Mist
whipped cream - sol
7.
8.
The solubility of AgCl (s) with solubility product 1.6 × 10-10 in 0.1M NaCl solution would be _______.
1.26 × 10-5M
1.6 × 10-9M
1.6 × 10-11M
Zero
9.
For a first order reaction, the rate constant is 6.909 min-1 the time taken for 75% conversion in minutes is _______.
\(\left( \frac { 3 }{ 2 } \right) { \log 2 }\)
\(\left( \frac { 2 }{ 3 } \right) \log2\)
\(\left( \frac { 3 }{ 2 } \right) \log\left( \frac { 3 }{ 4 } \right) \)
\(\left( \frac { 2 }{ 3 } \right) \log\left( \frac { 4 }{ 3 } \right) \)
10.
The crystal with a metal deficiency defect is ________.
NaCl
FeO
ZnO
KCl
11.
Which of the following is paramagnetic in nature?
[Zn(NH3)4]2+
[Co(NH3)6]3+
[Ni(H2O)6]2+
[Ni(CN)4]2-
12.
Which one of the following is not correct?
La(OH)3 is less basic than Lu(OH)3
In lanthanoid series ionic radius of Ln3+ ions decreases
La is actually an element of transition metal series rather than lanthanide series
Atomic radii of Zr and Hf are same because of lanthanide contract
13.
The correct order of the thermal stability of hydrogen halide is_______.
HI > HBr > HCl > HF
HF > HCl > HBr > HI
HCl > HF > HBr > HI
HI > HCl > HF > HBr
14.
The basic structural unit of silicates is _______.
\(\left( SiO_{ 3 } \right) ^{ 2- }\)
\(\left( SiO_{ 4 } \right) ^{ 2- }\)
\(\left( Sio \right) ^{ - }\)
\(\left( SiO_{ 4 } \right) ^{ 4- }\)
15.
Wolframite ore is separated from tinstone by the process of________.
Smelting
Calcination
Roasting
Electromagnetic separation
1.
(c)
all cis-configuration
2.
(b)
It does not react with Grignard reagent
3.
(a)
Ethanol, hydrozylamine hydrochloride
4.
5.
(c)
6.
(b)
Gel - butter
7.
(c)
8.
AgCl(s) ⇌ Ag+(aq) + Cl-(aq)
NaCl → Na+ +Cl-
0.1M 0.1M 0.1M
Ksp = 1.6 × 10-10
Ksp = [Ag+][ Cl-]
Ksp = (s) (s + 0.1)
0.1 >>> s
∴ s + 0.1 = 0.1
∴ s = 1.6 × 10-10/ 0.1 = 1.6 × 10-9
9.
\(k=\frac { 2.303 }{ t } \log\frac { \left[ { A }_{ 0 } \right] }{ \left[ A \right] } \)
[A0] = 100: [A] = 25
\(6.909=\frac { 2.303 }{ t } \log\frac { \left[ {100 } \right] }{ \left[ 25\right] } \)
\(t =\frac { 2.303 }{ 6.909 } \log(4)\)
\(t =\frac { 1 }{ 3 } \log(2^2)\)
\(= \left( \frac { 2 }{ 3 } \right) \log2\)
10.
(b)
FeO
11.
a) Zn2+ (d10 ⇒ diamagnetic)
b) Co3+ (d6 Low spain ⇒ t2g6 e0g ; diamagnetic)
c) Ni2+ (d8 Low spain ⇒ t2g6 e2g ; paramagnetic)
d) [Ni(CN)4]2+ (dsp2 ; square planar, diamagnetic)
12.
(a)
La(OH)3 is less basic than Lu(OH)3
13.
(b)
HF > HCl > HBr > HI
14.
(d)
\(\left( SiO_{ 4 } \right) ^{ 4- }\)
15.
(d)
Electromagnetic separation
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