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Published on: 03/10/2019
Carbon and Its Compounds
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1.
State the reason why carbon can neither form C4+ cations for C4- anions, but forms covalent compounds. Also state reasons to explain why covalent compounds:
(a) are bad conductors of electricity?
(b) have low melting and boiling points
2.
Explain isomerism. State any four characteristics of isomers. Draw the structures of possible isomers of butane, C4H10
3.
An organic compound A on heating with concentrated H2SO4 forms a compound B which on addition of one mole of hydrogen in presence of Ni forms a compound C. One mole of compound C on combustion forms two moles of CO2 and 3 moles of H2O. Identify the compounds A, B and C and write the chemical equations of the reactions involved.
4.
Draw the possible isomers of the compound it molecular formula C3H6O and also give their electron dot structures.
5.
How would you bring about the following conversions? Name the process and write the reaction involved.
a) Ethanol to ethene.
b) Propanol to propanoic acid
6.
Esters are sweet-smelling substances and are used in making perfumes. Suggest some activity and the reaction involved for the preparation of an ester with well labeled diagram.
7.
Name the reaction which is commonly used in the conversion of vegetable oils to fats. Explain the reaction involved in detail.
8.
a) What are hydrocarbons? Give examples
b) Give the structural differences between saturated and unsaturated hydrocarbons with two example each.
c) What is a functional group? Give example of four different functional groups.
9.
A salt X is formed and a gas is evolved when ethanoic acid reacts with sodium hydrogen carbonate. Name the salt X and the gas evolved. Describe an activity and draw the diagram of the apparatus to prove that the evolved gas is the one which you have named. Also, write chemical equation of the reaction involved.
1.
Carbon atoms have 4 electrons in their outcomes shell. So need to gain or lose electrons to attain noble gas configuration.
(i) It could gain four electrons forming c4- anion. But it would be difficult for the nucleus with six protons to hold on to ten electrons.
(ii) It could lose four electrons forming C4+ cations. But it would require a large amount energy to remove four electrons from its outermost shell.
Because of these reasons, carbon shares its valence electrons to complete its octet with other atoms to form covalent bonds.
(a) Covalent compounds are bad conductors of electricity because they do not contain ions.
(b) Covalent compounds have usually low melting and boiling because they are made up of electronically neutral molecule. So the force of attraction between the molecules of a covalent compound is very weak. Only a small amount of heat energy is required to break these weak molecular forces, due to which covalent compounds have low melting and boiling points.
2.
Isomerism is a phenomenon due to which some compounds have same molecular formula but different structural formulae .
Characteristics:
(i) They differ in structural formula
(ii) They differ in melting point
(iii) They differ in boiling point
(iv) They differ in solubility in same solven.
3.
i) Since compound C on combustion forms two moles of CO2 and 3 moles of H2 O, therefore compound C must contain two carbon atoms and six hydrogen atmos. Thus compound C must be C2H6 (ethane)
\(\underset{Ethene(C)}{2C_2H_6}+\underset{Oxygen}{7O_2}\xrightarrow{Heat}\underset{Carbon\ dioxide}{4CO_2}+\underset{Water}{6H_2O}\)
ii) Since compound (C) is obtained by addition of 1 mole of H2 in presence of Ni to compound (B), therefore (B) must be ethane.
\(\underset{Ethene(B)}{CH2}=CH_2+H_2\xrightarrow{Ni/Heat}\underset{Ethene(C)}{CH_3-CH_3}\)
iii) Since compound (B) is formed by heating compound (A) with cone. H2SO4 therefore compound (A) must be ethanol.
\(\underset{Ethanol(A)}{CH_3CH_2OH}\xrightarrow{Conc. H_2SO_4,443K}CH_2=CH_2+\underset{Ethene(B)}{H_2O}\)
4.
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5.
a)\(\underset{Ethanol}{CH_3CH_2OH}\xrightarrow{Conc.H_2SO_4.170^0C}CH_2=\underset{Ethene}{CH_2}+H_2O\)
b)\(\underset{Propanol}{CH_3CH_2CH_2OH+2[O]}\xrightarrow[or\ Aci.K_2Cr_2O_7,\Delta]{AlK.KMnO_4, \Delta}\underset{Propanoic\ acid}{CH_3CH_2COOH}+H_2O\)
6.
Carboxylic acid reacts with alcohols to form ester. For example, when ethanoic acid is warmed with ethanol in presence of a few drops of concentrated sulphuric acid as catalyst, an ester (ethyl ethanoate, commonly called ethyl acetate) and water are formed.
\(\underset{Acetic\ or\ ethanoic\ acid}{CH_COOH}+\underset{Ethanol}{C_2H_5OH}\xrightarrow{Conc. H_2SO_4}\underset{Ethyl\ ethanoate}{CH_3COOC_2H_5}+\underset{Water}{H_2O)}\)
Ester are sweet -smelling substances. So they are widely used in making perfumes and flavoring agents. Further, the reaction between a carboxylic acid and an alcohol to form a sweet ester is used as a test for alcohols as well as carboxylic acids.
7.
Addition of hydrogen to understand hydrocarbons in presence of a catalyst such as nickel or palladium to form saturated hydrocarbons is called hydrogenation. For example,
\(\underset { Ethyne }{ CH } \equiv CH+{ H }_{ 2 }\xrightarrow [ ]{ Ni/473K} \underset { Ethene }{ { CH }_{ 2 } } ={ CH }_{ 2 }+{ H }_{ 2 }\xrightarrow [ ]{Ni/473K } { CH }_{ 3 }-\underset { Ethane }{ { CH }_{ 3 } } \)
8.
a) Compounds of carbon and hydrogen only are called hydrocarbons. For example
methane (CH4), ethane (C2H6), ethene (C2H4), ethyne (C2H2), cydohexane
(C6H12), benzene (C6H6) etc.

b) Saturated hydrocarbons contains only C - C and C - H single covalent bonds while
unsaturated hydrocarbons contain at least one C = C double bond (besides C - C
and C - H single covalent bonds) or one triple bond.

c) That portion of the organic molecule which largely determine its chemical properties is called the functional group. For example, -OH (alcoholic group),
(keto group) - CHO (aldehyde group), -COOH (carboxyl group).
9.
\(\underset{Ethanoic\ acid}{CH_3COOH} + \underset {Sodium\ hydrogen\\ Carbonate}{NaHCO_3} \rightarrow \underset{sodium\ ethanoate}{CH_3COONa}+ \underset{Cabon\ dioxide}{CO_2} + \underset{Water}{H_2O}\)
Activity to show that ethanoic acid reacts with metal hydrogen carbonate to liberate carbon dioxide.
Procedure:
i) Take two test tubes and label them as A and B.
ii) Now, take few grams of sodium carbonate in test tube A.
iii) Take few grams of sodium hydrogen carbonate in test tube B.
iv) Now, add ethanoic acid to both the test tubes.
v) Note your observation.
vi) Pass the gas liberated in test tube A and B through lime water or calcium hydroxide solution.
vii) Record your observation.
Observation
a) A brisk effervescence is formed.
b) The lime water turns milky in both the test tubes.

When carboxylic acids react with sodium carbonate or sodium bicarbonates, it liberates carbon dioxide gas which turns lime water milky.
\(\underset{Calcium\ hydroxide\\ (Lime\ wate)}{Ca(OH)_2(aq)}+\underset{Carbon\ dioxide}{CO_2(g)}\rightarrow \underset{Calcium\ carbonate\\ (White \ ppt)}{CaCO_3(s)\downarrow}+\underset{Water}{H_2O(l)}\)
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