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Published on: 14/09/2019
Chemical Reactions and Equations
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1.
Translate the following statement into chemical equation and then balance it: ''A metal in the form of ribbon burns with a dazzling white flame and changes into a white powder'.
2.
Give an example of a decomposition reaction. Describe an activity to illustrate such a reaction by heating.
3.
Why is photosynthesis considered as endothermic reaction?
4.
Zinc liberates hydrogen gas when reacted with dilute hydrochloric acid, whereas copper does not. Explain why.
5.
During the reaction of some metals with dilute hydrochloric acid, following observations were made.
(a) Silver metal does not show any change
(b) The temperature of the reaction mixture rises when aluminium (Al) is added.
(c) The reaction of sodium metal is found to be highly explosive
(d) Some bubbles of a gas are seen when lead (Pb) is reacted with the acid.
Explain these observations given suitable reasons.
6.
Write the balanced chemical equations for the following reactions and identify the type of reaction in each case.
(a) Thermite reaction, iron (III) oxide reacts with aluminium and gives molten iron and aluminium oxide.
(b) Magnesium ribbon is burnt in an atmosphere of nitrogen gas to form solid magnesium nitrate.
(c) Chloride gas is passed in an aqueous potassium iodide solution to form potassium chloride solution and solid iodine.
(d) Ethanol is burnt in air to form carbon dioxide, water and releases heat.
7.
A yellowish coloured compound 'A' is photosensitive material. On exposure to sunlight, it gives a greyish substance 'B' and brown fumes of a gas 'C'. Identify A, B and C. How will you obtain A from the nitrate salt of B?
8.
Why do we apply paint on iron articles?
9.
Write the balanced chemical equations for the following reactions.
(a) Calcium hydroxide + Carbon dioxide \(\rightarrow\) Calcium carbonate + Water
(b) Zinc + silver nitrate \(\rightarrow\) Zinc nitrate + Silver
(c) Aluminium + Copper chloride \(\rightarrow\) Aluminium chloride + Copper
(d) Barium chloride + Potassium Sulphate \(\rightarrow\) Barium sulphate + Potassium chloride
10.
Balance the following chemical equations.
(a) HNO3 + Ca(OH)2 \(\rightarrow\) Ca(NO3)2 + H2O
(b) NaOH + H2SO4 \(\rightarrow\) Na2SO4 + H2O
(c) NaCl + AgNO3 \(\rightarrow\) AgCl + NaNO3
(d) BaCl2 + H2SO4 \(\rightarrow\) BaSO4 + HCl
11.
Why does the colour of copper sulphate solution change when an iron nail is dipped in it?
12.
Why is the amount of gas collected in one of the test tubes (electrolysis of water) double of the amount collected in the other? Name this gas.
13.
Why should a magnesium ribbon be cleaned before burning in air?
1.
Magnesium combines with atmospheric oxygen to form magnesium oxide.
2Mg+O2 \(\rightarrow \) 2MgO
2.
Example of a decomposition reaction:
\(\underset { limestone }{ { CaCO }_{ 3 }(s) } \overset { heat }{ \rightarrow } \underset { quick\quad lime }{ CaO(s) } +C{ O }_{ 2 }(g)\)
Here, when limestone (calcium carbonate) is heated, it decomposes into quick lime (calcium oxide) and carbon di oxide (gas).
3.
Photosynthesis is a reaction in which energy is required to form glucose from carbon dioxide and water. Energy in the form of sunlight is also required to break the bonds of hydrogen and oxygen. hence it is termed as endothermic reaction.
4.
Reaction depends upon the reactivity of metals. Copper is less reactive than zinc. Copper is also known as noble metal along with gold, silver, etc. that are very less reactive under normal conditions. This is the cause that copper does not react with dilute hydrochloric acid and consequently does not liberate hydrogen gas while zinc does.
5.
(a) No change takes place because silver metal categorized as noble metal and does not react with hydrochloric acid in normal situations.
(b) The reaction between hydrochloric acid and aluminium is exothermic, thus the temperature of the reaction mixture rises when aluminium is added.
(c) Since, sodium is a highly reactive metal, thus it reacts with hydrochloric acid vigorously and produces, large amount of heat. Thus the reaction between
hydrochloric acid and sodium is highly explosive. Even sodium reacts with water vigorously.
(d) Bubbles of hydrogen gas are formed when lead reacts with dilute hydrochloric acid, which is seen in the course of reaction.
6.
(a) \(\underset{Iron(III)oxide}{Fe_2O_3}+\underset{Aluminium}{2Al} \rightarrow\underset{Iron}{2Fe}+\underset{Aluminium\ oxide}{Al_2O_3}+Heat+Light\)
It is an exothermic redox reaction.
(b) \(\underset{Magnesium}{3Mg(s)}+\underset{Nitrogen\ gas}{N_2}\rightarrow\underset{Magnesium\ nitride}{{}Mg_3N_2(s)}\)
It is a combination reaction.
(c) \(\underset{Potassium\ Iodide}{2K(aq)}+\underset{Chlorine}{Cl_2(g)}\rightarrow\underset{Potassium\ chloride}{2KCl(aq)}+\underset{Iodine}{I_2(s)}\)
It is a redox reaction.
Potassium chloride Iodine
(d)\(\underset{Ethanal}{C_2H_5OH}+\underset{Oxygen}{3O_2}\rightarrow\underset{Carbon\ dioxide}{2CO_2}+\underset{Water}{3H_2O}+Heat\)
It is an exothermic - redox reaction.
7.
The yellowish compound is silver bromide [AgBr].
When silver bromide is exposed to sun light, it produces a grey coloured silver metal.
\(2AgBr\longrightarrow2Ag+Br_2\)
Thus 'A' is silver bromide [AgBr], 'B' is silver metal [Ag] and 'C' is bromine [Br2]
The nitrate of 'B' is silver nitrate [AgNO3]
Silver nitrate when treated with sodium bromide, it forms silver bromide.
AgNO3+NaBr\(\rightarrow\)AgBr+NaNO3
8.
By applying paint on iron articles, they can be prevented from corrosion (rusting). Paint does not allow oxygen (from air) and water (moisture) to come in contact with the surface of iron.
9.
(a) Ca(OH)2 + CO2 \(\rightarrow\) CaCO3 + H2O
(b) Zn + 2AgNO3 \(\rightarrow\) Zn(NO3)2 + 2Ag
(c) 2Al + 3CuCl2 \(\rightarrow\) 2AlCl3 + 3Cu
(d) BaCl2 + K2SO4 \(\rightarrow\) BaSO4 + 2KCl
10.
(a) 2HNO3 + Ca(OH)2 \(\rightarrow\) Ca(NO3)2 + 2H2O
Nitric acid Calcium hydroxide Calcium nitrate Water
(b) 2NaOH + H2SO4 \(\rightarrow\) Na2SO4 + 2H2O
Sodium hydroxide Sulphuric acid Sodium sulphate Water
(c) NaCl + AgNO3 \(\rightarrow\) AgCl + NaNO3
Sodium chloride Silver nitrate Silver chloride Sodium nitrate
(d) BaCl2 + H2SO4 \(\rightarrow\) BaSO4 + 2HCl
Barium chloride Sulphuric acid Barium sulphate Hydrochloric acid
11.
The colour of copper sulphate solution changes when an iron nail is dipped in it because iron being more reactive than copper, displaces copper metal from aqueous copper sulphate solution. Thus, blue colour of copper sulphate fades away to give green colour solution of ferrous sulphate.
Fe (s) + CuSO4(aq) \(\rightarrow\) FeSO4(aq) + Cu(s)
Grey Blue Green Brown
12.
The composition of water, i.e. the chemical formula H2O, suggests that the molar ratio of hydrogen and oxygen is 2 : 1. Therefore, when water is electrically decomposed, the constituent gases hydrogen and oxygen are produced in the same molar ratio, 2 : 1. Thus, the amount (volume) of hydrogen gas is double than that of oxygen gas. So, this gas is hydrogen.
13.
Magnesium ribbon reacts with oxygen present in air to form a protective and inert layer of magnesium oxide on its surface. This layer is unreactive and prevents the ribbon from burning. Hence, it needs to be cleaned with sand paper before burning in air.
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