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Published on: 14/08/2019
Periodic Classification of Elements
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1.
Nitrogen (atomic number 7) and phosphorus (atomic number 15) belong to group 15 of the Periodic Table. Write the electronic configuration of these two elements. Which of these will be more electronegative? Why?
2.
How could the Modern Periodic Table remove various anomalies of Mendeleev's Periodic Table?
3.
What were the limitations of Newlands' Law of Octaves?
4.
Table given below shows a part of the Periodic Table.
| H | He | ||||||
| Li | Be | B | C | N | O | F | Ne |
| Na | Mg | Al | Si | P | S | Cl | Ar |
Using this table explain why?
(a) Li and Na are considered as active metals.
(b) Atomic size of Mg is less than that of Na.
(c) Fluorine is more reactive than Chlorine.
5.
What physical and chemical properties of elements were used by Mendeleev in creating his periodic table? List two observations which posed a challenge to Mendeleev's Periodic Law.
6.
Write the number of periods the modern periodic table has. How do the valency and metallic character of elements vary on moving from left to right in a period? How do the valency and atomic size of elements vary down a group?
7.
(a) Lithium, sodium, potassium are all metals that react with water to liberate hydrogen gas. Is there any similarity in the atoms of these elements?
(b) Helium is an unreactive gas and neon is a gas of extremely low reactivity. What, if anything, do their atoms have in common?
8.
What were the criteria used by Mendeleev in creating his Periodic Table?
9.
On moving from left to right in a period in the periodic table, the size of the atom.
increases
decreases
does not change appreciably
first decreases and then increases
10.
Arrange the following elements in the order of their increasing nonmetallic character : Li, O, C, Be, F
F<O<C<Be<Li
Li<Be<C<O<F
F<O<C<Be<Li
F<O<Be<C<Li
11.
Which of the following elements does not lose an electron easily?
Na
F
Mg
Al
12.
Which of the following gives the correct increasing order of the atomic radii of O, F and N?
O,F,N
N,F,O
O,N,F
F,O,N
13.
An element which is an essential constituent of all organic compounds belong to
group 1
group 14
group 15
group 16
14.
Which of the following statements about the Modern Periodic Table is correct:
It has 18 horizontal rows known as Periods
It has 7 vertical columns known as Periods
It has 18 vertical columns known as Groups
It has 7 horizontal rows known as Groups.
15.
In Mendeleev's Periodic Table, gaps were left for the elements to be discovered later. Which of the following elements found a place in the periodic table later
Germanium
Chlorine
Oxygen
Silicon
16.
Which of the following statements is not a correct statement about the trends when going from left to right across the periods of periodic Table?
The elements become less metallic in nature.
The number of valence electrons increases.
The atoms lose their electrons more easily.
The oxides become more acidic.
17.
(a) Why do we classify elements?
(b) What were the two criteria used by Mendeleev in creating his Periodic Table?
(c) Why did Mendeleev leave some gaps in his Periodic Table?
(d) In Mendeleev's Periodic Table, why was there no mention of Noble gases like Helium, Neon and Argon?
(e) Would you place the two isotopes of chlorine, Cl-35 and Cl-37 in different slots because of their different atomic masses or in the same slot because their chemical properties are the same? Justify your answer.
18.
Explain the trends in the modern Periodic Table of various properties like valency, atomic size, metallic and non-metalic properties of the atoms of elements.
19.
Give an account of the process adopted by Mendeleev for the classification of elements. How did he arrive at "Periodic Law"?
20.
Which group of elements could be placed in Mendeleev's Periodic Table without disturbing the original order? Give reason
21.
An element A which is a yellow solid at room temperature shows catenation and allotropy. A forms two oxides which are also formed during the thermal decomposition of ferrous sulphate crystals and are the major air pollutants.
(a) Identify the element A
(b) Write the electronic configuration of A
(c) Write the balanced chemical equation for the thermal decomposition of ferrous sulphate crystals?
(d) What would be the nature (acidic/ basic ) of oxides formed?
(e) Locate the Position of the element in the Modern Periodic Table.
22.
Atomic number of a few elements are given below 10, 20, 7, 14
(a) Identify the elements.
(b) Identify the Group number of these elements in the Periodic Table.
(c) Identify the Periods of these elements in the Periodic Table.
(d) What would be the electronic configuration for each of these elements?
(e) Determine the valency of these elements.
23.
(a) What property do all elements in the same column of the Periodic Table as boron have in common?
(b) What property do all elements in the same column of the Periodic Table as fluorine have in common?
24.
How many vertical columns are there in the modern periodic table and what are they called?
25.
Lithium, sodium and potassium form a Dobereiner's triad. The atomic masses of lithium and potassium are 7 and 39 respectively. Predict the atomic mass of sodium.
1.
(a) Atomic number of Nitrogen is 7 and electronic configuration is 2, 5. Atomic number of Phosphorus is 15 and electronic configuration is 2, 8, 5.
(b) Phosphorus will be more electronegative because phosphorous and nitrogen both are non-metals. Phosphorous is situated in the lower side than Nitrogen. In non-metals, as we go top to bottom the electronegativity is increased.
2.
(a) The positions of certain elements were justified.
(b) The position of isotopes has been justified.
(c) The prediction of properties of elements.
3.
(a) Newlands' Law of Octaves was applicable only up to calcium. After calcium the eighth element did not possess properties similar to that of the first.
(b) Newlands assumed that only 56 elements existed in nature and no more elements would be discovered in the future.
(c) Newlands' Octaves contains only few elements having similar properties.
4.
(a) They can lose electrons easily due to bigger size, energy required to remove electron is less.
(b) It is because of greater effective nulear charge on Mg, i.e. more number of protons attract more number of electrons than Na.
(c) 'F' can form F- more easily than Cl due to smaller atomic size. F- is more stable than Cl- . Therefore, fluorine is more reactive than chlorine.
5.
Atomic mass as a physical property and nature and formulae of oxide and hydride formed, and chemical property was used by Mendeleev.
Observations :
(i) Increasing order of atomic weights could not be maintained while matching chemical properties. Chemical properties do not depend atomic mass.
(ii) Isotopes have different atomic mass but same chemical properties.
6.
(a) There are seven periods in the modern periodic table.
(b) On moving from left to right in a period, the valency of elements increases from 1 to 4 and then decreases to 0.
(c) On moving from left to right in a period, the metallic characters of elements decreases as the electropositive character of elements decreases on moving from left to right in a period.
(d) All the elements in a group have same valency, because the number of valence electrons in a group is same.
(e) On going down in a group of the periodic table, the size of atoms increases because a new shell of electrons is added to the atoms at every step on moving down in a group.
7.
(a) Lithium, Sodium and Potassium atoms have same number of electrons in their outermost shell and have same valency.
(b) Helium and Neon both have their outermost shell filled.
8.
The criteria for Mendeleev periodic table was the use of atomic masses. Mendeleev arranged the elements in increasing order of their atomic masses and according to their chemical properties.
9.
(b)
decreases
10.
(b)
Li<Be<C<O<F
11.
(b)
F
12.
(d)
F,O,N
13.
(b)
group 14
14.
(c)
It has 18 vertical columns known as Groups
15.
(a)
Germanium
16.
(c)
The atoms lose their electrons more easily.
17.
(a) As different elements were being discovered, scientists gathered more information about the properties of these elements. It was observed that it was difficult to organise all the information or properties of these elements. So scientists started discovering some pattern in their properties to classify all the known elements to make their study easier.
(b) Atomic mass and similarity of chemical properties (compounds formed by elements with oxygen and hydrogen) were the two criteria used by Mendeleev in his Periodic Table.
(c) Mendeleev left some gaps in his Periodic Table as he predicted the existence of some elements that had not been discovered at that time.
(d) Noble gases like helium, neon, argon etc. were not mentioned in Mendeleevs Periodic Table because these gases were discovered later as they are very inert and present in extremely low concentrations in our atmosphere. After the discovery of noble gases they could be placed in a new group without disturbing the existing order of the Periodic Table.
(e) The two isotopes of chlorine CI-35 and CI-37 would be placed in different slots of Mendeleevs Periodic Table as both have different atomic masses. But the two isotopes have same chemical properties so would also be placed in the same slot. This is a contradiction. Thus position of isotopes of an element is not defined in Mendeleevs Periodic Table.
18.
(1) Valency. Elements belonging to same group have same number of valence electrons and thus same valency.
Valency in a particular period from left to right first increases as positive valency and then decreases as negative valency.
Example, in elements of 2nd period:
Li has 1+ valency, then Be2+ , C4+ covalency, N3- valeI!cy, then 02- and F(-) valency.
(2) The atomic size or atomic radius increases as we move down in a group and it decreases as we move from left to right in a period. Atomic size increases down a group due to increase in the number of shells. Atomic size decreases along a period due to increase in the nuclear charge which tends to pull the electrons closer to the nucleus and reduces the size of the atom.
(3) Metallic and non -metallic properties. In the modern periodic table metals are on the left size and non-metals are on the right size. A zigzag line of metalloids separates metals from non-metals. Metallic character decreases from left to right in a period and increases while going down in a group. Non-metallic character increases from left to right in a period due to increase in the electron-negativity and this character decreases from topo to bottom in a group due to decrease in the electro-negativity of atoms while going down in a group.
19.
When the various elements were arranged in order of their increasing atomic masses, elements having similar properties fell under on another in the same vertical column called the group. He further observed that repetition of elements with similar physical and chemical properties occurred after certain regular intervals. On the basis of these observations, Mendeleev proposed his periodic law which states that the physical and chemical properties of elements are a periodic function of their atomic masses.
20.
At the time when Mendeleev's gave his periodic table, noble gases such as helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe) and radon (Rn) were not known. When these gases were discovered much later, these were placed in a new group called the zero group without disturbing the original order.
21.
(a) The element A which is a yellow solid at room temperature and shows catenation and allotropy is sulphur (S).
(b) The atomic number of sulphur is 16. Therefore, its electronic configuration is 2, 8, 6.
(c) \(\underset { Ferroussulphate }{ { 2FeSO }_{ 4 } } \underrightarrow { Heat } \underset { Ferricoxide }{ { Fe }_{ 2 }{ O }_{ 3 } } +\underset { Sulphurdioxide }{ { SO }_{ 2 } } +\underset { Sulphurtrioxide }{ { SO }_{ 3 } } \)
Both SO2 and SO3 are major air pollutions.
(d) Since sulphur is a non-metal, therefore both S02 and S03 are acidic oxide since they dissolve in water to form the corresponding acids.
\(\underset { Sulphurdioxide }{ { SO }_{ 2 } } +\underset { Water }{ { H }_{ 2 }O } \rightarrow \underset { Sulphurousacid }{ { H }_{ 2 }{ SO }_{ 3 } } \\ \underset { Ferroustrioxide }{ { SO }_{ 3 } } +\underset { Water }{ { H }_{ 2 }O } \rightarrow \underset { Sulphuricacid }{ { H }_{ 2 }{ SO }_{ 4 } } \)
(e) Since sulphur contains six valence electrons, therefore it lies in group 6 + 10 = 16.Further, since atomic number of sulphur (S) is 16. It lies in the 3rd period.
22.
| Atomic No. | Electronic Configuration | Group No. | Period No. | Valency | Element |
| 10 | 2,8 | 18 | 2nd | Zero | Neon |
| 20 | 2,8,8,2 | 2 | 4th | 2 | Calcium |
| 7 | 2,54 | 15 | 2nd | 3 | Nitrogen |
| 14 | 2,8,4 | 14 | 3rd | 4 | Silicon |
23.
(a) The properties of all elements in the boron family
(i) All the elements show valency of 3.
(b) The properties of all the elements in halogen family
(i) All the elements possess seven electrons in the valence shell.
24.
( )
There are 18 vertical columns in the modern periodic table and they are called groups.
25.
( )
Atomic mass of Na = 7+39 / 2 = 46 / 2 = 23
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