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Published on: 23/09/2019
Some Basic Concept of Chemistry
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1.
Arrange the following in order of their increasing masses in gram one gram of iron
2.
Copper sulphate crystals contain 25.45% Cu and 36.07% H2O. If the law of constant proportions is true then calculate the weight of Cu requires to obtain 40g of crystalline CuSo4.
3.
A lady purchases a ring from a jeweller with diamonds embedded into it. The jeweller tells that total diamond used in the ring is five carat. How much weight he should subtract from the weight of the ring to get the weight of gold?
4.
How many atoms of He are present in 52 \(\mu\) of He?
5.
The density of the water at room temperature is 0.1 g / mL. How many molecules are there in a drop of water if its volume is 0.05 mL?
6.
A compound made up of two elements A and B has A = 70%, B = 30%. Their relative number of moles in the compound are 1.25 and 1.88. Calculate molecular formula of the compound, if its molecular mass is found to be 160.
7.
Commercially available sulphric acid contains 93% acid by mass and has density of 1.84 gm-1.Calculate the molarity of the solution
1.
Mass of iron = 1.0 g.Hence, the required order of increasing masses is one atom of silver
2.
The chemical formula of copper sulphite crystals is CuSO4 .5H2O .
According to the data, Percentage of Cu = 25.45 % , Percentage of H2O = 36.07 %
Percentage of SO4 = 100 − ( 25.45 + 36.07 ) = 100 − 61.52 = 38.48 %
Since the law of constant composition is true, the percentage composition of the other sample of copper sulphite crystals must also remais the same Now, 100 g of copper sulphate crystals contain Cu = 25.45 g.
∴ 50 g of copper crystals contain \(C u=\frac{(25.45 g)}{(100 g)} \times(40 g)=10.18 g .\)
3.
1 carat = 200 mg,
∴ 5 carat = 1000 mg = 1g
Hence, he should subtract 1 g from the weight of the ring to get the weight of gold.
4.
The atomic mass of each He is 4.003, to be precise. That means the group of each atom is 4.003 amu. Then the 52 u of He has 52/4.003, which is 12.99 means 13. So, 52 u of He has 13 atoms.
5.
Volume of a drop of water = 0.05 mL
Mass of a drop of water = volume \(\times\) density
= ( 0.05 mL ) \(\times\)(1.0g / mL)
= 0.05 g
Gram molecular mass of water ( H2O ) = 2\(\times\)1 + 16 = 18 g ;
18 g of water = 1 mol
\(\therefore\) 0.05 g of water = \(\frac{1 mol}{(18 g)}\)\(\times\) ( 0.05 g )
= 0.0028 mol
\(\because\) 1 mole of water conmtains molecules = 6.022 \(\times\)1023
0.0028 mole of water will contain molecules
= 6.022 \(\times\)1023\(\times\)0.0028 = 1.68 \(\times\)1021 molecules
6.
Calculation of molecular formula
Empirical formula mass =
\(2\times 56+3\times 16=160\)
\(n=\frac { molecular \ formula }{ empirical \ formula \ mass } =\frac { 160 }{ 160 } =1\)
\(\therefore Molecular\ formula={ A }_{ 2 }{ B }_{ 3 }\)
7.
OK, assuming it is 93% by mass then we should work with 100 g of solution a 93% by mass solution will have 93 g of H2SO4 and 7 g of H2O
moles H2SO4 = mass / molar mass = 93 g / 98.086 g/mol = 0.948148 moles
mass H2O = 7 g = 0.007 kg
molality = moles solute / kg solvent
= 0.948148 mol / 0.007 kg
= 135 m ~ 140 m (2 sig figs)
Now
total volume of 100 g of solution = mass / density
= 100 g / 1.84 g/ml
= 54.35 ml
= 0.05435 L
molarity = moles solute / litres solution
= 0.98148 mol / 0.05435 L
= 18 M
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