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Published on: 21/10/2025
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1.
Which of the following compounds will show cis-trans isomerism?
CH2= CBr2
2.
On complete combustion, 0.246 g of an organic compound gave 0.198g of carbon dioxide and 0.1014g of water. Determine the percentage composition of carbon and hydrogen in the compound.
3.
Convert the following into basic units. 15.5 \(\mu s\)
4.
Calculate \(\triangle _{ r }G^{ \ominus }\) for conversion of oxygen to ozone, 3/2 O2(g) \(\rightarrow \) O3(g) at 298 Kp. If Kp for this conversion is 2.47 x 10-29.
5.
In Carius method of estimation of halogen, 0.15 g of an organic compound gave 0.12 g of AgBr. Find out the percentage of bromine in the compound.
6.
The density of 3 M solution of Na Cl is 1.25 g mL-1. Calculate molality of the solution.
7.
Calculate
(5.7 x 10-5) \(\div \) (4.2 x 10-3)
8.
How will you distinguish between LiCl and KCl
9.
Reema takes milk every day . She also take curd and other milk products.She takes green leafy vegitables and fruits also. An adult body contains about 25g of magnesium and 1200 g of calcium and 5 g of iron .these elements must be a part of our diet. All enzymes that utilize ATP in phosphate transfer required magnesium as co-factor. the main pigment for the absorption of light in plants is chlorophyll, which contains magnesium. were as Anita does not like milk and takes lot of junk food.
Write some rich sources of calcium?
10.
In India, there is the shortage of drinking water. Thus, projects like rainwater harvesting are used by Green Park Association to increase the amount of underground water. Rainwater is the almost pure form of water after the heavy shower as it is, in fact, the distilled water. The first shower contains dissolved gases from the atmosphere. Being a good solvent, when it flows on the surface of the earth, it dissolves many salts in the form of hydrogen carbonate, chloride and sulphate in water which make it hard Give the values possessed by the office bearer of Green Park Association?
11.
Which of the following species, do not show disproportionation reaction and why ?
\(CI{ O }^{ - },Cl{ O }_{ 2 }^{ - },Cl{ O }_{ 3 }^{ - }\) and \(ClO_{ 4 }^{ - }\)
Also write reaction for each of the species that disproportionates
12.
An organic substance containing carbon, hydrogen and oxygen gave the percentage composition as C = 40.687 % , H = 5.05 %. The vapour density of the compound is 59. Calculate the molecular formula of the compound.
13.
Assuming the density of water to be 1g/cm3, calculate the volume occupied by one molecule of water.
1.
For exhibiting cis-trans (or geometrical isomerism, a molecule must fulfil the following condition.
The groups attached to each double bonded carbon atom must be different.
2.
Percentage of carbon =\(\frac { 12\times 0.198\times 100 }{ 44\times 0.246 } =21.95%\) %
Percentage of hydrogen =\(\frac { 2\times 0.1014\times 100 }{ 18\times 0.246 } =4.58%\) %
3.
The basic units for length is meter (m), for time is second(s) and for mass is kilogram (kg)
\(15.15\mu s\frac { { 10 }^{ -12 }s }{ 1\mu s } =1.515\times { 10 }^{ -5 }s\)
4.
\(\text{ we know } \triangle _{ r }G^{ \ominus }=-2.303 \ RT \ \log { { K }_{ P } }\) \(and R=8.314 \ JK^{ -1 }mol^{ -1 }\)
\(\text{ therefore,}\triangle _{ r }G^{ \ominus }=-2.303(831JK^{ -1 }mol^{ -1 })\times (298K)(\log { 2.47\times { 10 }^{ -29 }) }\)
= 163000 J mol–1
= 163 kJ mol–1.
5.
Molar mass of AgBr = 108 + 80 = 188 g mol-1
188 g AgBr contains 80 g bromine
0.12 g AgBr contains \(= \frac{80 \times 0.12}{188}\) g bromine
Percentage of bromine \(=\frac { 80\times 0.12\times 100 }{ 188\times 0.15 } =34.04\%\)
6.
M = 3 mol L-1
Mass of NaCl in 1 L soution = x 58.5 = 175.5 g
Mass of 1 L solution =1000 x 1.25 = 1250 g
(since density = 1.25 g mL-1)
Mass of water soultion = 1250 - 175.5
= 1074.5 g = 1.0745 kg.
Molality = \(\frac { \text{ number of moles of solute} }{\text{ mass of solvent in kg} } =\frac { 3mol }{ 1.0745kg } =2.79 \ m\)
Often in a chemistry laboratory, a solution of a desired concentration is prepared by diluting a solution of known higher concentration. The solution of higher concentration is also known as stock solution. Note that the molality of a solution does not change with temperature since mass remains unaffected with temperature.
7.
Given, (5.7 x 10-5) \(\div \) (4.2 x 10-3)
(5.7 \(\div \) 4.2) x (10-5-(-3)) = 23.94 x 10-2
8.
LiCl is soluble in organic solvent but KCl does not. THis is because exceptionaloly small size of Li+ ion and high polarising power, which develops covalent character in the lithium compounds ( Fajan's Rule ) .whereas , KCl is ionic in nature .So, it is soluble in water.
9.
Milk, Yogurt and milk products are rich sources of calcium
10.
The value possessed by the office bearer of Green Park Association are best to use of rainwater, saving water for drinking irrigation, domestic purpose etc.
11.
Among the oxoanions of chlorine listed above, \(Cl{ O }_{ 4 }^{ - }\) does not disproportionate because in this oxoanion chlorine is present in its highest oxidation state that is, +7. The disproportionation reactions for the other three oxoanions of chlorine are as follows:
\(\overset { +1 }{ 3ClO^{ - } } \longrightarrow \overset { -1 }{ 2Cl^{ - } } +\overset { +5 }{ ClO_{ 3 }^{ - } }\)
\( \overset { +3 }{ 6Cl{ O }_{ 2 }^{ - } } \overset { hv }{ \longrightarrow } \overset { +5 }{ 4Cl{ O }_{ 3 }^{ - }+ } \overset { -1 }{ 2C } l^{ - }\)
\(4\overset { +5 }{ ClO_{ 3 }^{ - } \longrightarrow \overset { { -1 }^{ - } }{ Cl } } +3\overset { +7 }{ Cl } _{ 4 }^{ - }\)
12.
Step I : To calculate empirical formula of the compound.
Here, % of O = 100 - ( 40.687 + 5.085 )
= 54.228%
\(\therefore\) Empirical formula is C2HO2
Step II : To calculate empirical formula mass. The empirical formula of the compound is C2H3O2.
\(\therefore\) Empirical formula mass = ( 2\(\times\)12 ) + ( 3\(\times\)1 ) + ( 2\(\times\)16 )
= 59
Step III : To calculate the molecular mass of the salt.The vapour density of the compound = 59 ( Given )
Using the relation between vapour density and molecular mass.
We have molecular mass = 2 \(\times\) vapour density
= 2\(\times\)59 = 118
Step IV : To calculate the value of n = \(\frac{molecular \ mass}{emphirical \ formula \ mass}\)
= \(\frac{118}{59}\)
= 2
Step V : To calculate the molecular formula of the salt , Molecular formula = n \(\times\) emphirical formula
= 2C2H3O2
= C4H6O4
Thus, the molecular formula is C4H6O4.
| Element | Symbol | Percentage of element | Atomic mass of elemnt | Mass of the element = \(\frac{Percentage }{Atomic mass}\) | Simplest molar ratio | Simplest whole number molar ratio |
| Carbon | C | 40.687 | 12 | \(\frac{40.687}{12}\) =3.390 | \(\frac{3.390}{3.389}\) = 1 | 2 |
| Hydrogen | H | 5.085 | 1 | \(\frac{5.0885}{1} \)= 5.085 | \(\frac{5.085}{ 3.389 } \)= 1.5 | 3 |
| oxygen | O | 54.228 | 16 | \( \frac{54.228}{16} \)= 3.389 | \(\frac{3.389}{3.389}\) = 1 | 2 |
13.
1 mole of H2O = 18 cm3
( \(\because\) density of H2O = 1g / cm3)
= 6.022\(\times\)1023 molecules of H2O
Thus, 6.022\(\times\)1023 molecules of H2O have volume
= 18 cm3
\(\therefore\) 1 molecule of H2O will have volume
= \(\frac{18}{6.022\times10^{23}} \)
= 2.989\(\times\)10-23 cm3
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