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Published on: 27/07/2018
From the chapter Some Basic Concept of Chemistry, some of the important questions are covered in this question paper.
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1.
A gold coloured metal object has a mass of 365 g and a volume of 22.12 cm3. Is the object composed of pure gold?
2.
Calculate the number of moles in the following mass."7.9 mg of Ca"
3.
Sulphuric acid reacts with sodium hydroxide as follows
\({ H }_{ 2 }{ SO }_{ 4 }+2NaOH{ \longrightarrow }{ Na }_{ 2 }{ SO }_{ 4 }+H_{ 2 }O\) When 1L of 0.1M sulphuric acid solution is allowed to react with 1L of 0.1 M sodium hydroxide solution, the amount of sodium sulphate formed and its molarity in the solution obtained is
4.
What is the difference between 5.0 g and 5.00 g ?
5.
Suppose the length of a cardboard has been reported to be 31.24 cm. What is the minimum uncertainty implied in this measurement ?
6.
How can you prove that red oxide of copper is not an element ?
7.
Why are the atomic mass most of the elements is fractional?
8.
Give an example of molecule in which the ratio of the molecular formula is six times the empirical formula.
9.
Calculate the number of gram molecules of water in a beaker conatining 576 g of water
10.
Compute the mass of one molecule and the molecular mass of \({ C }_{ 6 }H_{ 6 }\) (benzene) (atomic mass of C = 12\(\mu \), H = 1\(\mu \))
11.
\({ Fe }_{ 2 }({ SO }_{ 4 }{ ) }_{ 3 }\) is used in water and sewage treatment to aid the removal of suspended impurities. Calculate the mass percentage of iron and sulphur in this compound.
12.
Calculate the mass of a sample of iron metal that contains 0.250 moles of iron atoms.
13.
How many moles of atoms are present in 9.0 g of aluminum?
14.
Express the following number to three significant figures.
(a) "6.0263"
(b) "2.3652"
(c) "Sixty thousand"
(d) " 2.861×105 "
15.
Using the unit conversion factor, express 1.54mm s-1 into pm \(\mu \)s-1.
16.
Round up the following up to three significant figures:
(i) 34.216
(ii) 10.4107
(iii) 0.04597
(iv) 2808
17.
A Welding fuel gas contains carbon and hydrogen only. Buring a small sample of it in oxygen gives 3.38g carbon dioxide, 0.690 g of water and no other products. A volume 10.0 L (measured at STP) of this welding gas is found to weigh 11.6 g.
(a) Calculate. Molar mass of the gas.
(b) Calculate. molecular formula.
18.
\(9.7\times { 10 }^{ 17 }\) atoms of iron weigh as much as 1 cc of \({ H }_{ 2 }\) at STP. What is the atomic mass of iron?
19.
The mass of a liter of oxygen at standard conditions of temperature and pressure is 1.43g and that of a liter of \({ SO }_{ 2 }\)is 2.857 g. What are the molecular masses of \({ SO }_{ 2 }\) and \({ O }_{ 2\\ }\)respectively?
20.
The mass of a liter of oxygen at standard conditions of temperature and pressure is 1.43g and that of a liter of \({ SO }_{ 2 }\)is 2.857 g. What is the mass in gram of a single molecule of each gas?
1.
No
2.
7.9 mg of Ca = 7.9\( \times\)103 g of Ca
Atomic mass of Ca = 40.1
Moles of Al = \(\frac{ mass\ of\ Ca}{atomic\ mass}\)
= \( \frac{7.9\times10^{-3}}{40.1}\)
= 1.97\(\times \)104 mol
3.
For the reaction
\({ H }_{ 2 }{ SO }_{ 4 }+2NaOH{ \longrightarrow }{ Na }_{ 2 }{ SO }_{ 4 }+H_{ 2 }O\)
1L: of 0.1 M H2SO4 contains = 0.1 mole of H2SO4
1L of 0.1 M Na OH contains = 0.1 mole of NaOH
According to the reaction,1 mole of H2SO4 reacts with 2 moles of NaOH. Hence,0.1 mole of NaOH will react with 0.05 mole of H2SO4
(and 0.05 mole of H2SO4 will be left unreacted), i.e NaOH is the limiting reactant. Since, 2 moles of NaOH produces 1 mole of Na2SO4.
Hence,0.1 mole of NaOH will produces 0.05 mole of Na2SO4
Mass of Na2SO4 = moles \(\times \)molar mass
= 0.5\(\times \) (46 + 32 + 64)g = 7.10g
Volume of solution after mixing = 2L
Since only 0.05 mole of H2SO4 is left behind. as NaOH is completely used in the reaction.
Therefore,molarity of the given solution is calulated from moles of H2SO4.
H2SO4 left unreacted in the solution = 0.05 mole
\(\therefore \) Molarity of the solution \(=\frac { 0.05 }{ 2 } =0.025\)mol L-1
4.
Through the two values seem to be equivalent but scientifically they are different. 5.0 g has two significant figures and hence, its precision is 0.1 part in 5, i.e. 20 ppt 5.00 has three significant figures and hence, its precision is 0.01 parts in 5, i.e. 2 ppt. Hence, 5.00 g is more precise measurement than 5.0 g.
5.
The minimum uncertainty implies in this measurement is ± 0.01 cm.
6.
On heating red oxide of copper in the presence of hydrogen, its mass decreases and it forms shining metallic copper which is chemically different from the original compound.
Cu2O + H2 ⟶ 2Cu + H2O
7.
It is because most of the elements occur in nature as a miture of isotopes and their atomic masses are the average relative atomic masses of the isotopes depending on their abundance.
8.
The compound is glucose.Its molecular formula is C6H12O6 while empirical formula is CH2O.
9.
Molecular mass of H2O = 2 × 1 + 16 = 18 g mol-1
18g of water = 1 gram of molecule
∴ 576 g of water =1/18 × 576 = 32 gram molecule
10.
\(1.3\times { 10 }^{ -22 }g\)
11.
Fe = 28% ; s = 24%
12.
14 g
13.
0.33 mol
14.
(a) 5
(b) 5
(c) 1
(d) 4
15.
1.54 ×103pm μ s -1.
16.
Rounding off a number means that the digits which are not significant have to be dropped. The rules are as follows:
1. If the digit to be dropped is more than 5, then add 1 to the preceding significant figure. For e.g., in the number 11.06, the digit to be dropped is 6. Therefore, the preceding digit 0 is increased by one & the result is 11.1.
2. If the digit to be dropped is less than 5, then it is deleted as such without bringing any change in the preceding significant figure. For e.g., 43.123 is to report up to four significant figures, then the last digit 3 is dropped & the final answer is 43.12.
3. If the digit to be dropped is 5 then the preceding significant digit in the number may be left unchanged if it is even & may be increased by 1 in case it is odd. e.g., 1.6145, if reported up to four significant figures will become 1.614 after rounding off. Similarly, 1.6175 will become 1.618.
4. If during rounding off, more than one digit is to be dropped from a particular number, then they are dropped on at a time by following the above rules.
(i) 34.2
(ii) 10.4
(iii) 0.0460
(iv) 2810
17.
(a) Calculation for molar of the gas
10.0 L of the given gas at STP weigh = 11.6 g
\(\therefore \) 22.4 L of the given gas at STP will weigh
\(\frac { 11.6\times 22.4 }{ 10 } =25.984\quad g\)
Molar mass = 25.984 = 26 \({ mol }^{ -1 }\)
(b) Empirical formula mass (CH) = 12 + 1 = 13
\(\therefore \) \(n=\frac { molecular \ mass }{ empirical \ formula \ mass } =\frac { 26 }{ 13 } =2\)
Hence, molecular formula
\(=n\times CH=2\times CH={ C }_{ 2 }{ H }_{ 2 }\)
18.
A = 55.41\(\mu\)
19.
\(64\mu \) and \(32 \mu\)
20.
mass of \({ O }_{ 2\\ }\)molecule = \(=5.32\times { 10 }^{ -23 }g\) ;
mass of \({ SO }_{ 2 }\) molecule \(=1.06\times { 10 }^{ -22 }g\)
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