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Published on: 21/09/2019
Chemical Bonding and Molecular Structure
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1.
Explain why BeH2 molecule has a zero dipole moment although the Be–H bonds are polar.
2.
Define Hybridisation. Explain Sp3 hybridisation with suitable example.
3.
What is an electrovalent (or ionic) bond? Explain its formation with two examples.
4.
Indicate the type of bonds present in NH4No3 and state the mode of hybridisation of two N-atoms in it.
5.
Predict the hybridisation of each carbon in the molecule of organic compound given below. Also indicate the total number of \(\sigma \ and \ \pi \)-bonds in this molecule.

6.
On the basis of molecular orbital theory what is similarly between (a) \({ F }_{ 2 },{ O }_{ 2 }^{ 2- }\) ,(b) CO,N2,NO+
1.
The Lewis structure for BeH2 is as follows:
H: Be: H
There is no lone pair at the central atom (Be) and there are two bond pairs. Hence, BeH2 is of the type AB2. It has a linear structure.
\(\nrightarrow \nleftarrow \)
H------Be-----H
Dipole moments of each H - Be bond are equal and are in opposite directions. Therefore, they nullify each other. Hence, BeH2 has a zero dipole moment.
2.
Hybridisation: It is the phenomenon of intermixing of atomic orbitals of slightly different energies to form new hybrid orbitals of equivalent energy. Formation of water. In water (H20), the atomic number of oxygen is 8 and its orbitals electronic configuration is 1s2 2s2 \({ 2 }_{ x }^{ 2 }{ \ 2p }_{ y }^{ 1 }{ \ 2p }_{ z }^{ 1 }\) . The oxygen atom is also Sp3 hybridised. However, in this case, the two orbitals with one electron each (half filled) are involved in overlap with the hydrogen orbitals.

3.
When a cheroical bond is fonned by the complete transfer of electrons from one atom to another, so as to complete their outermost shell and therefore, aquire the stable noble gas configuration, the bond fanned is called ionic bond or electrovalent bond.
\(\underset { 2,8,1 }{ Na } \longrightarrow \underset { 2,8 }{ Na } ^{ + }+{ e }^{ - }\)
\(CI \ + \ { e }^{ - }\longrightarrow \left[ \underset { 2,8,8 }{ CI } \right] ^{ - }\)
\(\overset { 2,8,7 }{ Na } +{ CI }^{ - }\longrightarrow \left[ { Na }^{ + } \right] \left[ CI \right] ^{ - } \)

Formation of magnesium oxide (MgO)

4.

\({ NH }_{ 4 }^{ + }\) ion contains covalent and dative bonds. (It is formed by donation of lone pair of electrons on N in NH3 to H+ ion). \({ NO }_{ 3 }^{ - }\) ion also contains covalent and davite bonds.
Bond between \({ NH }_{ 4 }^{ + }\) and \({ NO }_{ 3 }^{ - }\) ions is ionis.
N of \({ NH }_{ 4 }^{ + }\) ion is sp3 hydridised and is tetrahedral.
N of \({ NO }_{ 3 }^{ - }\) ion is sp2 hybridised and is planar.
5.

6.
(a) same bond order and bond length.
(b) Same bond order and bond length.
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