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Published on: 30/08/2019
Some Basic Concept of Chemistry
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Questions + Answers key
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1.
Why are the atomic mass most of the elements is fractional?
2.
Give an example of molecule in which the ratio of the molecular formula is six times the empirical formula.
3.
What will be the mass of one 12C atom in g?
4.
One mole of oxygen gas at STP is equal to?
5.
What is the SI unit of mass? How is it defined?
6.
What will be the molality of the solution contaning 18.25g of HCI gas in 500 g of water?
7.
If the concentration of glugose (C6H12O6) in blood is 0.9 g L-1, what will be the molarity of glugose blood?
8.
Perform the following calculation to proper number of significant figures.
(a) 108/7.2
(b) (1.6 ×102)2
(c) (1.0042 - 0.0034) (1.23)
9.
Calculate the percentage composition of the various elements in \({ MgSO }_{ 4 }\)
10.
Using the unit conversion factor, express 1.54mm s-1 into pm \(\mu \)s-1.
11.
The mass of a liter of oxygen at standard conditions of temperature and pressure is 1.43g and that of a liter of \({ SO }_{ 2 }\)is 2.857 g. What is the mass in gram of a single molecule of each gas?
12.
The mass of a liter of oxygen at standard conditions of temperature and pressure is 1.43g and that of a litre of \({ SO }_{ 2 }\)is 2.857 g.
(a) How many molecules of each gas are there in this volume?
(b) What is the mass in gram of a single molecule of each gas?
(c) What are the molecular masses of SO2 and O2 respectively?
13.
A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is 98.96 g. What are its empirical and molecular formulas?
14.
What is the weight in pounds of a gold bar 12.0 inch. long, 6.00 inch wide and 3.00 inch thick? The density of gold is 19.3 g cm-3. (Given 1 inch = 2.54 cm, 1lb = 453.6 g).
15.
A measured temperature on Fahrenheit scale is 200o F. What will this reading be on Celsius scale?
16.
Convert the following temperatures into degree Fahrenheit.
(a) 25o C, physiological (human body) temperature.
(b) 35o C, the room temperature.
17.
The mass of an atom of nitrogen is _______.
\(\frac { 14 }{ { { 6.023\times 10 }^{ 23 } } } \)
\(\frac { 28 }{ { { 6.023\times 10 }^{ 23 } } } \)g
\(\frac { 1 }{ { { 6.023\times 10 }^{ 23 } } } \)g
14 amu
18.
The number of grams of oxygen in 0.10 mol of Na2CO3· 10H2O is _______.
20.8 g
18 g
108 g
13 g
19.
The number of significant figures in 0.0101 is _______.
3
2
4
5
20.
The empirical formula of sucrose is _______.
CH2O
CHO
C12H22 O11
C(H2 O)2
1.
It is because most of the elements occur in nature as a miture of isotopes and their atomic masses are the average relative atomic masses of the isotopes depending on their abundance.
2.
The compound is glucose.Its molecular formula is C6H12O6 while empirical formula is CH2O.
3.
1 mole of carbon atoms = 6.023 × 1023 atoms of carbon
Mass of 1 atom of 12C =Atomic mass of C/Avogadro′s number
\(= \frac{ 12}{6.022×10^{23}} g\)
= 1.9927 ×10-23 g
4.
1 mole of O2 gas at STP = 6.022 ×× 1023 molecules of O2
( Avogadro number ) = 32 g of O2
Hence, 1 mole of oxygen gas is equal to molecular weight of oxygen as well as Avogadro number.
5.
The SI unit of mass is kilogram kg.
The kilogram is the unit of mass; it is equal to the mass of the international prototype of the kilogram.
6.
Molality is defined as the number of moles of solute present in 1kg of solvent. It is denoted by m.
Thus Molality (m)
\(=\frac { moles\ of\ solute }{ mass\ of\ solvent } \)
Given that, Mass of solvent (H2O)
= 500g
= 0.5kg
Weight of HCI
= \(1\times 1+1\times 35.5=36.5g\)
Molar of HCI(solute)
\(=\frac { 18.25 }{ 36.5 } =0.5\)
\(m=\frac { 0.5 }{ 0.5 } =1m\)
7.
In the given question 0.9g L-1 means that 1000 mL solution contains 0.9 g of glugose
Number of moles = 0.9g glucose = \(\frac { 0.9 }{ 180 } \)mol glugose
= \(5\times { 10 }^{ -3 }\)mol glugose.
(where molecular mass of glugose(C2H12O6) = \(12\times 6+12\times 1+6\times 16=180u)\)
i.e IL solution contains 0.05 mole glugose or the molarity of glucose is 0.005M.
8.
(a) Steps:
108 Ã⋅7.2 = 14.5833
Three S.F. Two S.F.
Here answer should have two significant figures. Therefore, correct answer, after rounding off two significant figures is 15.
(b) Steps: 2 x 1.6 x 102
2 x 163.2 = 326.4 = 300
(c) Steps: (1.0042 - 0.0034) x 1.23
1.0008 x 1.23 = 1.230984
= 1.23
9.
Molecular mass of \(\mathrm{MgSO}_4\)
=24+32+4 \times 16=120
Mass of \(\mathrm{Mg}=24\)
Mass percentage of \(\mathrm{Mg}=\frac{24}{120} \times 100=20 \%\)
Mass of \(\mathrm{S}=32\)
mass percentage of \(S=\frac{32}{120} \times 100=26.67 \%\)
Mass of \(\mathrm{O}=4 \times 16=64\)
Mass of percentage of \(\mathrm{O}=\frac{64}{120} \times 100=53.33 \%\)
10.
1.54 ×103pm μ s -1.
11.
mass of \({ O }_{ 2\\ }\)molecule = \(=5.32\times { 10 }^{ -23 }g\) ;
mass of \({ SO }_{ 2 }\) molecule \(=1.06\times { 10 }^{ -22 }g\)
12.
\(1 \mathrm{LO}_2 \text { or } \mathrm{SO}_2=\frac{1}{22.4} \mathrm{~mol}=\frac{1}{22.4} \times 6.02 \times 10^{23}\)
molecules \(=2.688 \times 10^{22}\) molecules
Mass of 1 molecule of \(O_2=\frac{1.43}{2.688 \times 10^2}=1.0629 \times 10^{-23} g\)
Gram Molecular mass of
\(\mathrm{O}_2=\text { Mass of } 22.4 \mathrm{~L} \text { at STP }=1.43 \times 22.4=32.032 g\)
Molecular mass of O2=32.032 u
Similarly, molecular mass of SO2 can be calculated.
(i) \({ 2.69\times 10 }^{ 22 }\) molecules of each
(ii) mass of \({ O }_{ 2\\ }\)molecule = \(=5.32\times { 10 }^{ -23 }g\) ;
mass of \({ SO }_{ 2 }\) molecule \(=1.06\times { 10 }^{ -22 }g\)
(iii) O2 = 32.032 u and SO2 = 63.997 u
13.
Step 1. Conversion of mass per cent to grams : Since we are having mass per cent, it is convenient to use 100 g of the compound as the starting material. Thus, in the 100 g sample of the above compound, 4.07g hydrogen, 24.27g carbon and 71.65g chlorine are present.
Step 2. Convert into number moles of each element : Divide the masses obtained above by respective atomic masses of various elements. This gives the number of moles of constituent elements in the compound
Moles of hydrogen = \(\frac{4.07 \mathrm{~g}}{1.008 \mathrm{~g}}=4.04\)
Moles of carbon = \(\frac{24.27 \mathrm{~g}}{12.01 \mathrm{~g}}=2.021\)
Moles of chlorine = \(\frac{71.65 \mathrm{~g}}{35.453 \mathrm{~g}}=2.021\)
Step 3. Divide each of the mole values obtained above by the smallest number amongst them : Since 2.021 is smallest value, division by it gives a ratio of 2:1:1 for H:C:Cl. In case the ratios are not whole numbers, then they may be converted into whole number by multiplying by the suitable coefficient.
Step 4. Write down the empirical formula by mentioning the numbers after writing the symbols of respective elements : CH2Cl is, thus, the empirical formula of the above compound.
Step 5. Writing molecular formula : (a) Determine empirical formula mass by adding the atomic masses of various atoms present in the empirical formula.
For CH2Cl, empirical formula mass is
12.01 + (2 x 1.008) + 35.453
= 49.48 g
(b) Divide Molar mass by empirical formula mass
\(\frac{\text { Molar mass }}{\text { Empirical formula mass }}=\frac{98.96 \mathrm{~g}}{49.48 \mathrm{~g}}\)
= 2 = (n)
(c) Multiply empirical formula by n obtained above to get the molecular formula
Empirical formula = CH2Cl, n = 2. Hence molecular formula is C2H4Cl2.
14.
Weight in pounds = 12.0 in x 6.00 in \(\times 3.00 \text { in } \times \frac{2.54 \mathrm{~cm}}{1 \mathrm{in}} \times \frac{2.54 \mathrm{~cm}}{1 \mathrm{in}} \times \frac{2.54 \mathrm{~cm}}{1 \mathrm{in}} \times \frac{19.3 \mathrm{~g}}{1 \mathrm{~cm}^3} \times \frac{1 \mathrm{lb}}{453.6 \mathrm{~g}}\)
\(=150.60491 \mathrm{lb}=151 \mathrm{lb} \)(after rounding off because least precise term has 3 significant figures)
15.
There are three common scales to measure temperature oC (degree celsius), oF(degree Fahrenheit) and K (kelvin). The K is the SI unit.
The temperature on two scales are related to each other by the following relationship \(^{ 0 }F=\frac { 9 }{ 5 } t^{ 0 }C+32\)
Putting the values in above equation.
\(200-32=\frac { 9 }{ 5 } t^{ 0 }C\Rightarrow \frac { 9 }{ 5 } t^{ 0 }C=168\)
\(\Rightarrow \ t^{ 0 }C=\frac { 168\times 5 }{ 9 } =93.3^{ 0 }C\)
16.
(a) Given, C = 25o C
\(^{ 0 }F=\frac { 9 }{ 5 } C^{ 0 }+32=\frac { 9 }{ 5 } \times 25+32=45+32=77^{ 0 }F\)
(b) Given, C = 35o C
\(^{ 0 }F=\frac { 9 }{ 5 } C^{ 0 }+32=\frac { 9 }{ 5 } \times 35+32=63+32=95^{ 0 }F\)
17.
(b)
\(\frac { 28 }{ { { 6.023\times 10 }^{ 23 } } } \)g
18.
(a)
20.8 g
19.
(a)
3
20.
(c)
C12H22 O11
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