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Published on: 18/09/2019
Thermodynamics
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1.
Can the temperature of a system be increased without heating it?
2.
A piece of lead is hammered. Does its internal energy increase? Does the heat enter the lead from outside?
3.
Can mechanical work be completely converted into heat? Is reverse also possible?
4.
Why does a gas get heated on compression?
5.
How is the efficiency of a Carnot engine affected by the nature of the working substance?
6.
A sample of an ideal gas in a cylinder is compressed adiabatically to 1/3 rd of its volume. Will the final pressure be more or less titan 3 times the initial pressure
7.
Is it possible to convert internal energy into work or mechanical energy?
8.
Is coefficient of performance of a refrigerator constant?
9.
What is the change in internal energy of an ideal gas which is compressed/ expanded isothennally? Why?
10.
A Carnot engine is operating between 600 K and 200K. Consider that the actual energy produced is 2kJ per kilocalorie of heat absorbed.Compare the real efficiency with the efficiency of Carnot engine.
11.
Why is it theoretically not possible to have a device which create no thermal pollution?
12.
Is the coefficient of performance of a refrigerator, a constant quantity?
13.
The efficiency of a heat engine is more in hilly area than in plain.Explain it.
14.
What amount of heat must be supplied to 2.0 × 10–2 kg of nitrogen (at room temperature) to raise its temperature by 45 °C at constant pressure ? (Molecular mass of N2 = 28, R = 8.3 J mol-1 K-1)
15.
A person of mass 60 kg wants to lose 5 kg by going up and down a 10 m high stairs. Assume he burns twice as much fat while going up than coming down. If 1kg of fat is burnt on expending 7000 kcal calories, how many times must he go up and down to reduce his weight by 5 kg?
1.
Yes, for example in adiabatic compression
2.
Yes, internal energy of lead increases. No heat energy from outside enters the lead
3.
The mechanical work can be completely converted into heat, but heat extracted from some body cannot be completely converted into useful work.
4.
Because work done in compressing the gas increases the internal energy of the gas.
5.
The efficiency is independent of the nature of the working substance.
6.
Change in pressure will be more than 3 times the initial pressure.
7.
Yes, for example in an adiabatic expansion and explosion of a bomb (chemical energy is converted into K.E.).
8.
No, the coefficient of performance of refrigerator decreases with decrease in its inside temperature.
9.
Zero, because for an ideal gas internal energy is wholly kinetic and it is a function of temperature. As temperature remains constant in an isothermal process, hence, internal energy of an ideal gas remains constant.
10.
Given, T1 = 600K, T2 = 200K
Efficiency of Carnot engine,
\(\eta =\frac { { T }_{ 1 }-{ T }_{ 2 } }{ { T }_{ 1 } } =\frac { 600-200 }{ 600 } \)
\(=\frac { 400 }{ 600 } =\frac { 2 }{ 3 } =66\)
\(Real\ efficiency=\frac { Energy\ output }{ Energy\ input } =\frac { 2 }{ 1\times 4.2 } =0.47=47%\)
\(\\ \therefore \frac { Real\ efficiency }{ Carnot\ engine\ efficiency } =\frac { 47 }{ 66 } =0.71\)
\(\therefore \frac { Real\ efficiency }{ Carnot\ engine\ efficiency } =\frac { 47 }{ 66 } =0.71\)
11.
According to the second law of thermodynamics whole of the heat cannot be converted completely into work. Some part of the heat that is not converted into work is released by the engine to the atmosphere /9as sink).
Thus, thermal pollution will always occur.
12.
No, it is not constant quantity, as inside, temperature of the refrigerator decreases, it is coefficient of performance also decreases.
13.
Because in the hilly area, temp of surrounding is lower than that of plains.
As \(\eta =1-\frac { { T }_{ 2 } }{ { T }_{ 1 } } \)
14.
Here, mass of gas, m = 2\(\times \)10-2 kg = 20g
Rise in temperature, \(\Delta \)T = 45oC
Heat required,\(\Delta \)Q = ?
Molecular mass, M =28
Number of moles, n =\(\frac { m }{ n } =\frac { 20 }{ 28 } =0.714\)
As nitrogen is a diatomic gas, molar specific heat at constant pressure is
\(C_{ p }=\frac { 7 }{ 2 } R=\frac { 7 }{ 2 } \times 8.3J\quad mol^{ -1 }K^{ -1 }\)
\(\\ As\ \Delta Q=nC_{ p }\Delta T\)
\(\\ \therefore \ \Delta Q=0.714\times \frac { 7 }{ 2 } \times 8.3\times 45J=933.4\ J\)
15.
Here, m = 60kg, g = 10m/s2, h = 10m
In going up and down once, number of kilocalories burnt
= (mgh + mgh/2) =\(\frac { 3 }{ 2 } \) mgh
\(=\frac { 3 }{ 2 } \times \frac { 60\times 10\times 10 }{ 4.2\times 1000 } =\frac { 15 }{ 7 } kcal\)
Total number of kilocalories to be burnt for losing 5 kg of weight = 5\(\times \)7000 = 35000 kcal
\(\therefore \) Number of times of the person has to go up and down the stairs
= \(\frac { 35000 }{ 15/7 } =\frac { 35\times 7 }{ 15 } \times { 10 }^{ 3 }\) = 16.3 x 103 times
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