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Published on: 14/09/2019
Acids, Bases and Salts
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1.
While constructing a house, a builder selects marble flooring and marble table tops for the kitchen where vinegar and juice of lemon, tamarind etc. are more often used for cooking. Will you agree to this selection and why?
2.
(i) What would be the colour of the solution when copper oxide and dilute hydrochloric acid are mixed?
(ii) Write a chemical equation which represents that the effect of a base is nullified by an acid and vice-versa.
3.
The colour of copper sulphate solution changes when an iron nail is dipped in it. State the reason giving chemical equation for the reaction involved.
4.
HCl and HNO3 show acidic characteristics in aqueous solution while alcohol and glucose solutions do not. Give reasons.
5.
Two solutions A and B have pH values of 5 and 8 respectively. Which solution will be basic in nature?
6.
What is the colour of litmus in a solution of ammonium hydroxide?
7.
Write the chemical formula for washing soda. How may it be obtained from baking soda? Name an industrial use of washing soda other than washing clothes.
8.
What happens when nitric acid is added to egg shell?
9.
A milkman adds a very small amount of baking soda to fresh milk.
(i) Why does he shift the pH of the fresh milk from 6 to slightly alkaline?
(ii) Why does this milk take a long time to set as curd?
10.
Write word equations and then balanced equations for the reaction taking place when
(a) dilute sulphuric acid reacts with zinc granules.
(b) dilute hydrochloric acid reacts with magnesium ribbon
(c) dilute sulphuric acid reacts with aluminium powder
(d) dilute hydrochloric acid reacts with iron filings.
11.
Write an equation to show the reaction between plaster of paris and water.
12.
How is the concentration of hydroxide ions (OH-) affected when excess base is dissolved in a solution of sodium hydroxide?
13.
How is the concentration of hydronium ions H3O+ affected when a solution of an acid is diluted?
1.
No, the substance like vinegar, tamarind etc. contain acids which when accidentally fall on marble will react with the marble causing discoloration etc.
2.
(i) It is blue green
(ii) NCIOH + HCI \(\longrightarrow\) NCICI + H2O
3.
\(\underset{(Blue)}{CuSO_4}+Fe\longrightarrow \underset{(Green)}{FeSO_4}+Cu\)
Iron is more reactive than copper. Hence it displaces copper from copper sulphate and due to formation of FeSO4, the colour changes from blue to green.
4.
HCl and HNO3 produce H+ in aqueous solution. Hence, they show acidic character.
Alcohol and glucose do not produce H+ in aqueous solution, hence they do not show acidic character.
5.
B will be basic nature, with pH = 8.
6.
Red litmus turns blue in solution of ammonium hydroxide.
7.
The chemical formula of washing soda is \(Na_2CO_3.10H_2O.\)
Washing soda. On heating, baking soda gives sodium carbonate, carbon dioxide and water. Consequently, the recrystallisation of sodium carbonate gives washing soda. The chemical equations involved in the process are:
\(\underset{Baking\ soda}{2NaHCO_3}\rightarrow \underset{Sodium\ carbonate}{Na_2CO_3}+\underset{Carbon\ dioxide}{CO_2}+\underset{Water}{H_2O}\)
\(Na_2CO_3\rightarrow10H_2O\xrightarrow {Recrystallization}\underset{Washing\ soda}{Na_2CO_3.10H_2O}\)
Washing soda is used in glass, soap and paper industries.
8.
Egg shells contain calcium carbonate When nitric acid is added to it, carbon dioxide gas is evolved. The reaction can be given as
\(CaCO_3+2HNO_3\rightarrow Ca(NO_3)_2+H_2O+CO_2\)
9.
(i) Alkaline medium does not allow milk to turn sour easily.
(ii) When milk is set to curd, the presence of alkali does not allow it to become acidic easily. Hence, this milk take a longer time to set as a curd.
10.
(i) Dilute sulphuric acid + Zinç Granules \(\rightarrow\) Zinc sulphate + Hydrogen gas
H2SO4(aq) + Zn(s) \(\rightarrow\) ZnSO4 (aq) + H2(g)
Dilute Granulated
(ii) Dilute hydrochloric acid + Magnesium \(\rightarrow\) Magnesium chloride + Hydrogen gas
2HCI(aq) + Mg(s) \(\rightarrow\) MgCl2(aq) + H2(g)
Dilute
(iii) Dilute sulphuric acid + Aluminium \(\rightarrow\) Aluminium sulphate + Hydrogen gas
3H2SO4 (aq) + 2Al(s) \(\rightarrow\) Al2(SO4)3(aq) + 3H2(g)
Dilute
(iv) Dilute hydrochloric acid + Iron \(\rightarrow\) Iron (II) chloride +Hydrogen gas
2HCI(aq)+ Fe (s) \(\rightarrow\)FeCl2(aq)+ H2(g)
Dilute
11.
CaSO4. \(\frac{1}{2}\) H2O (s) + 1\(\frac{1}{2}\)H2O(l) \(\rightarrow\) CaSO4 . 2H2O(s)
Plaster of Paris Gypsum
or (CaSO4)2. H2O(s) + 3H2O(l) \(\rightarrow\) 2CaSO4 . 2H2O(s)
12.
Sodium hydroxide is a strong base. When excess base is dissolved in the solution of NaOH, the concentration of hydroxide ions (OH-) per unit volume increases due to dissociation of NaOH as well as the other base in aqueous solution.
NaOH \(\overset{H_{2}O}{\rightleftharpoons}\) Na+ + OH-
Any other base
e.g. M(OH)x \(\overset{H_{2}O}{\rightleftharpoons}\) M+ + xOH-
13.
An acid dissociates into hydronium ions (H3O+) and anions when dissolved in water. When a solution is diluted, the volume of the solution increases but the number of ions remains the same, so concentration of hydronium ions (H3O+) per unit volume decreases.
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