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Published on: 14/09/2019
Metals and Non-Metals
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1.
Mercury is the only metal found in the liquid state. It is largely used in thermometers to measure the temperature. But mercury is a very dangerous metal as its density is very high. What two precautions you would take while handling the equipment containing mercury?
2.
Explain why calcium metal after reacting With water starts floating on its surface. Write the chemical equation for the reaction.
3.
Name two metals that start floating after sometime when immersed in water and explain why they do so.
4.
An element forms an oxide A2O3 which is acidic in nature. Identify A as a metal are non-metal.
5.
A metal that exists as a liquid at room temperature is obtained by heating its sulphide in the presence of air. Identify the metal and its ore and give the reaction involved.
6.
Generally, when metals are treated with mineral acids, hydrogen gas is liberated but when metals (except Mn and Mg), treated with HNO3 , hydrogen is not liberated, why?
7.
Give reason for the following :
(i) Metals conduct electricity.
(ii) Reaction of nitric acid with metals generally does not evolve hydrogen gas.
(iii) For making gold ornaments, 22 carat gold is preferred to 24 carat gold.
8.
Metal sulphides occur mainly in rocks and the metal halides occur mostly in seas and lakes. What could be the reason for this difference in behaviour?
9.
What are amphoteric oxides? Give two examples of amphoteric oxides.
10.
What chemical process is used for obtaining a metal from its oxide?
11.
What would you observe when zinc is added to a solution of Iron (II) sulphate? Write the chemical reaction that takes place.
12.
Explain the meanings of malleable and ductile.
13.
Differentiate between metals and non-metals on the basis of their chemical properties.
14.
You must have seen tarnished copper vessels being cleaned with lemon or tamarind juice. Explain why these sour substances are effective in cleansing the vessels.
1.
Equipment containing mercury should be handled carefully.
If broken or discarded, their disposal should be done carefully.
Associated Value: The learners will handle and dispose such poisonous items more carefully.
2.
Calcium starts floating because the bubbles of hydrogen gas formed sticks to the surface of the metal.
Ca + 2H2O \(\rightarrow \) Ca(OH)2 + H2
3.
The two metals are:
(i) Calcium (Ca)
(ii) Magnesium (Mg)
They start floating because the bubbles of hydrogen gas which are formed during the reaction stick to the surface of the metal.
4.
Since an oxide of element is acidic in nature. therefore, the element A will be a non-metal
5.
Metals low in activity series can be obtained by reducing their sulphides or oxides by heating. Mercury is the only metal that exists as liquid at room temperature. It can be obtained by heating cinnabar (HgS), the sulphide ore of mercury. The reactions are follows:
\(2HgS+{ 3O }_{ 2 }\underrightarrow { Heat } 2HgO+{ 2SO }_{ 2 }\\ \quad \quad \quad 2HgO\underrightarrow { Heat } 2Hg+{ O }_{ 2 }\)
6.
It is because HNO3 is a strong oxidising agent. It oxidises the H2 produced to H2O.
7.
(i) Metals conduct electricity because they have electrons which are free to move. They offer little resistance to the flow of current. Silver and copper are the best conductors of electricity.
(ii) Reaction of metals with nitric acid does not evolve hydrogen gas; it is because HNO3 is a strong oxidizing agent. It oxidises H2 produced to water and is itself reduced to any of its oxides such as N2O, NO or NO2.
(iii) Pure gold is 24 carat and is very soft. Therefore it is not suitable for making jewellery. It is alloyed with Cu or Ag to make it hard. Generally 22 carat gold is used for making ornaments, which contains 22 parts pure gold and 2 parts of either Cu or Ag.
8.
Most of the metal sulphides are insoluble in water whereas metal halides are generally soluble. The metal halides (NaCl, MgCl2) are washed away with rain or river water in dissolved state and so the halide ores occur in lakes and seas.
9.
The metallic oxides which show the properties of acids as well as bases are called amphoteric oxides. It means that they react with both bases and acids to form salt and water.
e.g. ZnO and Al2O3
ZnO(s) + 2HCl(aq) \(\rightarrow\) ZnCl2 (aq) + H2O(l)
Zinc oxide (As a base) Hydrochloric acid Zinc chloride Water
ZnO(s) + 2NaOH(aq) \(\rightarrow\) Na2ZnO2(aq) + H2O(l)
Zinc oxide (As an acid) Sodium hydroxide Sodium zincare Water
10.
Metal is obtained from its oxide by reduction. This reduction can be done either by heating with carbon (coke) or by using highly reactive metals such as sodium, calcium, aluminium etc.
e.g. ZnO(s) + C(s) \(\rightarrow\) Zn(s) + CO(g)
Zinc oxide Coke Zinc Carbon monoxide
This reaction is highly exothermic. The heat produced is so large that metal is produced in the molten form.
11.
Zinc being more reactive than iron displaces iron from iron (II) sulphate solution. Thus, the green colour of the solution fades and iron metal gets deposited.
Zn(s) + FeSO4 (aq) \(\rightarrow\) ZnSO4 (aq) + Fe (s)
Zinc (Green) (Colourless) Iron (Deposited)
12.
Malleable A substance or material, which can be beaten into thin sheets is called malleable, e.g. metals like Ag (silver), Au (gold) etc.
Ductile A substance capable of being drawn into thin wires is called ductile, e.g, metals like Ag, Au etc.
13.
| Chemical Properties | Metals | Non-metals |
| Formation of ions | They are electropositive elements, lose electron(s) and form cations,e.g. Na \(\rightarrow\) Na+ + e- | They are electronegative elements, gain electron(s) and form anions. Cl + e- \(\rightarrow\) Cl- |
| Discharge of ions | Discharge at the cathode during electrolysis of their Compound. At cathode, Na+ + e- \(\rightarrow\) Na Cation |
Liberated at anode during electrolysis. |
| Reducing or Oxidising agent | They are reducing agents as they donate electrons during chemical reaction. | They are oxidising agents, as they accept electrons during chemical reaction. |
| Nature of Oxides | Metallic oxides are basic. Some of them dissolves in water forming alkaline solution,e.g.Basic oxide: K2O, Na2O, CaO, MgO and CuO Amphoteric oxide : Al2O3, PbO and ZnO |
Non-metallic oxides are acidic in nature. Acidic oxide : CO2,SO2, SO3, NO2 and P2O5 Neutral oxide: CO, NO, N2O and H2O |
| Reaction with acids | Active metals react with dil. HCl/H2SO4 to yield H2 gas and salts. M + 2HCl \(\rightarrow\) MCl2 + H2 \(\uparrow\) |
Non-metals do not react with dilute acids, as they cannot replace H+ ion from an acid to form salt. |
14.
A layer of basic copper carbonate is formed by the reaction of air on copper metal.
This layer being insoluble in water, cannot be cleaned with water alone. But, it is soluble in acids so lemon containing citric acid, tamarind containing tartaric acid or any other sour substance containing acid can be effective in cleaning the vessels. As these acids neutralises the basic copper carbonate and dissolves the layer. Hence, surface of copper vessels are cleaned with lemon or tamarind juice to give its characteristics lustre.
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