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Published on: 01/11/2019
Download CBSE Class 11th Standard CBSE Chemistry question papers, sample papers, important questions, and previous year solved papers in PDF format. Get free study materials, NCERT solutions, and exam preparation resources for Class 11th Standard CBSE Chemistry
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1.
What happens when alkali metals are dissolved in ammonia?
2.
Insulin contains 4.5 % sulphur. Calculate the minimum molecular mass of sulphur.
3.
How many atoms of He are present in 52 \(\mu\) of He?
4.
Discuss the preparation of alkanes by Wurtz reaction. What is the limitation of the reaction?
5.
Explain the differences in properties of diamond and graphite based upon their structures.
6.
Predict the formulas of the stable binary compounds that would be formed by the combination of the following pairs of elements.
(a) Lithium and oxygen
(b) Magnesium and nitrogen
(c) Aluminium and iodine
(d) Silicon and oxygen
(e) Phosphorus and fluorine
(f) Element 71 and fluorine
7.
Find (a) the total number and (b) the total mass of protons in 34 mg of NH3 at STP. (Mass of 1p = 1.6726 x 10-27kg)
Will the answer change if the temperature and pressure are changed?
8.
Calcium carbonate reacts with aqueous HCI to give CaCL2 and CO2 according to the reaction given below CaCO3(s) + 2HCI(aq) \(\longrightarrow \)CaCl2(aq) + CO2(g) + H2O(l)
What mass of CaCl2 will be formed when 250 mL of 0.76 M HCI reacts with 1000 g of CaCO3? Name the limiting reagent. Calculate the number of moles of CaCL2 formed in the reaction.
1.
They form blue coloured solution. The solution is paramagnetic in nature.
2.
711\(\mu\)
3.
The atomic mass of each He is 4.003, to be precise. That means the group of each atom is 4.003 amu. Then the 52 u of He has 52/4.003, which is 12.99 means 13. So, 52 u of He has 13 atoms.
4.
Wurtz synthesis: Higher alkanes are prepared by heating an alkyl halide (RX) with sodium metal in dry ether solution.
R - X + 2Na + XR \(\overset { ether }{ \longrightarrow } \) R - R + 2NaX
CH3Br + 2Na + BrCH3\(\longrightarrow \) CH3-CH3 + 2NaBr
Limitations: Use of two different alkyl halides in Wurtz reaction always leads to a mixture of alkanes. The separation of these alkanes is difficult because there is only a little difference in their boiling points. Thus only symmetrical alkanes can be prepared by this method.
5.
| Diamond | Graphite |
| Diamond is the hardest substance on earth. | Graphite is soft and slippery |
| In diamond carbon is Sp3- hybridized | In Graphite carbon is Sp2- hybridized |
| Since all the electrons in diamond are firmly held in C-C,6 bonds there are no free electrons in diamond crystal Therefore diamond is bad conductor of electricity | Since only three electrons of each carbon are used in making hexagonal rings of graphite, fourth valence electron is free to move thus graphite is a good conductor of electricity |
| Because of high refractive index diamond can reflect and refract the light. | Graphite is a black substance and possess a metallic lustre |
6.
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (a) | Lithium | Group 1 | 1 | 1 | \({ Li }_{ 2 }O\) |
| Oxygen | Group 16 | 6 | 8 - 6 = 2 |
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (b) | Group 13 | Group 2 | 2 | 2 | \({ Mg }_{ 3 }{ N }_{ 2 }\) |
| Group 17 | Group 15 | 5 | 8 - 5 = 3 |
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (c) | Group 13 | 3 | 3 | \({ AI I}_{ 3 }\) | |
| Group 17 | 7 | 8 - 7 = 1 |
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (d) | Group 14 | 4 | 4 | \({ SiO }_{ 2 }\) | |
| 6 | 8 - 6 = 2 |
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (e) | Group 15 | 5 | 3 or 5 | PF3 or PF5. | |
| Group 17 | 7 | 8 - 7 = 1 |
| S.No | Element | Group number | Electrons in valence shell | Valency | Formulae of binary compound |
| (f) | Group 3 | Group 3 | 3 | 3 | \({ LuF }_{ 3 }\) |
| Group 17 | Group 17 | 7 | 8 - 7 = 1 |
a. Lithium is an alkali metal (Group1). It has only one electron in the valence shell, therefore, its valence is 1.Oxygen is a group 16 element with a valence of 2. Therefore, formula of the compound formed would be Li2O (lithium oxide).
b. Magnesium is an alkali earth metal (Group2). hence has a valence is 2.Nitrogen is a group 15 element with a valence of 8−5=3. Thus, the formula of the compound formed would be Mg3N2 (magnesium nitride).
c. Aluminium is group 13 elements with a valence of 3 while iodine is a halogen (group17) with a valence of 1. Therefore, the formula of the compound formed be AII3(Aluminium iodide.).
d. Silicon is group 14 elements with a valence of 4 while oxygen is a (group16) with a valence of (8−6=2). Hence, the formula of the compound formed be SiO2(silicon dioxide).
e. Phosphorus is a group 15 element with a valence of 3 or 5 while flurine is group 17 element with a valence of 1. Hence, the formula of the compound formed would be PF3 or PF5.
f. Element with atomic number 71 is a lanthanoid called lutetium (Lu). Its common valence is 3. Fluorine is a group 17 (halogen) element with a valence of 1. Therefore, the formula of the compound formed would be LuF3(lutetium fluoride).
7.
1 mole of NH3 =10 moles of protons
= \(6.022\times 10^{ 23 }\times 10 \ protons\)
1 mole of NH3 (or 17g) contains 6.022 x 1024 protons
34 mg or 34 x 10-3 g NH3 will contain
\(=\frac { 34\times { 10 }^{ -3 }\times 6.022\times { 10 }^{ 24 } }{ 17 }\)
\(=12.044\times 10^{ 21 } \ protons\)
\(=1.2044\times 10^{ 22 } \ protons\)
Mass of 1 proton = 1.6726x10-27kg
Mass of 1.2044 x 1022 x 1.6726 x 10-27kg
= 2.01447 x 10-5kg
8.
Number of moles of HCI
= 250 mL\(\times \frac { 0.76M }{ 1000 } =0.19 \ mol;\)
Number of moles of CaCo3 = \(\frac { 1000g }{ 100 \ g \ { mol }^{ -1 } } \)= 10 mol
For the 10 moles of CaCO3(s) number of moles of HCI
required would be \(10\times \frac { 2 }{ 1 } \) = 20 mol HCI (aq)
But we have only 0.19 mole HCI (aq), hence, HCI(aq) is the limiting reagent. Since, 2 moles HCI (aq) forms 1 mole
of CaCl2, therefore, 0.19 moles of HCI (aq) would give
\(0.19\times \frac { 1 }{ 2 } =0.095 \ mol\)
Mass of CaCI2 = 0.095 \(\times\) 111 = 10.54 g
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