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Published on: 14/09/2019
Structure of Atom
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Questions + Answers key
Take MCQ Chemistry Test

1.
What is the difference between the notations 1and L?
2.
Which orbital is non-directional?
3.
What is difference between the notations I and L?
4.
What type of metals are used in photoelectric cells? Give one example.
5.
Distinguish between a photon and quantum.
6.
What is common between d xy and dx2-y2 orbitals?
7.
Arrange X-rays, cosmic rays and radio waves according to frequency.
8.
Give the relation between wavelength and momentum of moving microscopic particle. What is the relation known as?
9.
An ion with mass number 37 possesses one unit of negative charge. If the ion conatins 11.1% more neutrons than the electrons, find the symbol of the ion.
10.
Give the number of electrons in the species H2+, H2 and O2+.
11.
Calculate the energy of one mole of the photons of a beam of light having wavelength 25.0 \(\mu \)m.
12.
Calculate wave number of the line having frequency 5 x 1016 Hz.
13.
In astronomical observations, signals observed from the distant stars are generally weak. If the photon detector receives a total of 3.15 × 10–18 J from the radiations of 600 nm, calculate the number of photons received by the detector.
14.
Calculate energy of one mole of photons of radiation whose frequency is 5 x 1014 HZ.
15.
Why does the charge to mass ratio of positive rays depend on the residual gas in the discharge tube? Why is the charge to mass ratio of all cathode rays are same?
1.
l represents the subshell and L represents shell.
2.
s-orbital.
3.
'1' signifies the secondary quantum number.
'L' signifies second energy level (n = 2).
4.
The metals with low ionisation enthalpies are used in photoelectric cells. Caesium (Cs), an alkali metal belonging to group 1 is the most commonly used metal.
5.
A quantum is a bundle of energy of a definite magnitude (E = hv) and it may be from any source. However, a photon is quantum of energy associated with light only.
6.
Both have identical shape consisting of four lobes.
7.
Cosmic rays> X-rays> radio waves.
8.
Relation:\(\lambda =\frac { h }{ mV } \)
The relation is known as de Broglie's relationship.
9.
Let the number of electrons in an ion = x
Number of neutrons, n \(=x+\frac { 11.1 }{ 100 } x=1.111x\)
(As the number of neutrons are 11.1% more than the number of electrons.)
Since, the ion carries -1 charge, the number of protons, p = x - 1
we know that, mass number = n + p = 37
or 1.111 x + x - 1 = 37 or 2.111 x = 37 + 1 = 38
\(x=\frac { 38 }{ 2.111 } =18.0009 \ \approx 18\)
Number of protons = atomic number = 18 - 1 = 17
Therefore, the symbol of the ion is \(_{ 17 }^{ 37 }{ CI^{ - } }\)
10.
\({ H }_{ 2 }=_{ 1 }H+_{ 1 }H=1+1=2{ e }^{ - }\)
\({ H }_{ 2 }^{ + }=2-1=1e^{ - }\)
\( { O }_{ 2 }=_{ 8 }O+_{ 8 }O=8+8=16{ e }^{ - }\)
\( { O }_{ 2 }^{ + }=16-1=15e^{ - }\)
11.
\( \lambda=25.0 \mu m=25.0 \times 10^{-6} \mathrm{~m} \)
\( v=\frac{c}{\lambda}=\frac{3.0 \times 10^8}{25.0 \times 10^{-6}}=1.2 \times 10^{13}\)
Energy of photon,
\( E=h v=6.626 \times 10^{-34} \times 1.2 \times 10^{13} \)
\( =7.96 \times 10^{-21} \mathrm{~J}\)
12.
1.67 x 108 m-1
13.
From the expression of energy of one photon (E),
E=hc/λ
Where, λ = wavelength of radiation
h = Planck’s constant
c = velocity of radiation
Substituting the values in the given expression of E:
E\(=\frac{(6.626×10^{−34}Js)(3×108ms^{−1})}{(600×10^{−9}m)}\)=3.313×10−19J
Energy of one photon = 3.313 × 10–19 J
Number of photons received with 3.15 × 10–18 J energy
\(= \frac{3.15×10^{−18}J}{3.313×10^{−19}J}\)=9.5≈10
14.
Energy (E) of one photon is given by E = hv
h = 6.626 x 10-34 Js.
v = 5 x 1014 s-1 (given)
E = (6.626 x 10-34 Js) x (5 x 1014s-1) = 3.313 x 10-19 J
Energy of one mole of photons
= (3.313 x 10-19 J) x (6.022 x 1023mol-1) = 199.51 KJ mol-1
15.
In case of positive rays, the ions remaining after the loss of electrons might have the same magnitude of charge but different masses. Hence they will have different charge to mass ratio. Cathode rays are made up of electrons and all electrons have same charge to mass ratio. That's why charge to mass ratio of all cathode rays is same.
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