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Published on: 09/10/2019
The p-block Elements
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1.
How is boron obtained from borax? Give chemical equations with reaction conditions.
2.
Explain the differences in properties of diamond and graphite based upon their structures.
3.
When metal X is treated with sodium hydroxide, a white precipitate (A) is obtained, which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble in dilute HCl to form compound (C). The compound (A) when heated strongly gives (D), which is used to extract metal. Identify (X), (A), (B), (C) and (D). Write suitable equations to support their identities.
4.
Aluminium dissolves in mineral acids and aqueous alkalies and thus shows amphoteric character.A piece of aluminum foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning matchstick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas.The same activity when performed with concentrated nitric acid, reaction doesn't proceed, Explain the reason.
5.
A colorless aqueous solution on adding water and on heating gave a white NH4Cl and NH4OH in excess resulted in the dissolution of some of the precipitate and a gelatinous precipitate is obtained.what is the hydroxide formed in aqueous solution?
6.
Carbon form covalent compounds whereas lead form ionic compounds.why?
7.
What happens when boric acid is added to water?
8.
Complete the following reactions
\({ SiO }_{ 2 }+NaOH\longrightarrow \)
9.
Complete the following reactions
\({ CaCO }_{ 3 }(aq)+{ CO }_{ 2 }(excess)\longrightarrow \)
10.
Among group 14 elements name the elements having tendency to from \(p\pi -p\pi \) bonds.
11.
Among group 14 elements name most metallic element
1.
Na2B4O7 .10H2O + H2SO4 (conc.)\(\rightarrow\) Na2SO4 + H2B4O7 + 10H2O
Borax
H2B4O7 + 5H2O \(\rightarrow\) 4H3BO3
Boric acid
2H3BO3 \(\xrightarrow[]{Heat}\) B2O3 + 3H2O
Boric oxide
B2O3 + 3Mg \(\xrightarrow[]{\triangle}\)2B + 3MgO
2.
| Diamond | Graphite |
| Diamond is the hardest substance on earth. | Graphite is soft and slippery |
| In diamond carbon is Sp3- hybridized | In Graphite carbon is Sp2- hybridized |
| Since all the electrons in diamond are firmly held in C-C,6 bonds there are no free electrons in diamond crystal Therefore diamond is bad conductor of electricity | Since only three electrons of each carbon are used in making hexagonal rings of graphite, fourth valence electron is free to move thus graphite is a good conductor of electricity |
| Because of high refractive index diamond can reflect and refract the light. | Graphite is a black substance and possess a metallic lustre |
3.
The given metal X gives a white precipitate with sodium hydroxide and the precipitate dissolves in excess of sodium hydroxide. Hence, X must be aluminium.
The white precipitate (compound A) obtained is aluminium hydroxide. The compound B formed when an excess of the base is added is sodium tetrahydroxoaluminate(III).
\(2 \mathrm{Al}+3 \mathrm{NaOH} \ \longrightarrow \mathrm{Al}(\mathrm{OH})_{3} \downarrow+3 \mathrm{Na}^{+}\\ Aluminium (X) Sodium hydroxide White ppt.(A) \)
\(\mathrm{Al}(\mathrm{OH})_{3}+\mathrm{NaOH} \longrightarrow \ \mathrm{Na}^{+}\left[\mathrm{Al}(\mathrm{OH})_{4}\right]\\ (A) \ Sodium tetrahydroxoaluminate (III) ( Soluble complex B)\)
Now, when dilute hydrochloric acid is added to aluminium hydroxide, aluminium chloride (compound C) is obtained.
\(\mathrm{Al}(\mathrm{OH})_{3}+3 \mathrm{HCl} \longrightarrow \mathrm{AlCl}_{3}+3 \mathrm{H}_{2} \mathrm{O} \)
(A) (B)
Also, when compound A is heated strongly, it gives compound D. This compound is used to extract metal X. Aluminium metal is extracted from alumina. Hence, compound D must be alumina.
4.
Aluminium being amphoteric in nature dissolves both in acids and alkalies evolving H2 gas which burns with a pop sound.
\(2Al+6HCl\longrightarrow { 2AlCl }_{ 3 }+3{ H }_{ 2 }\)
\(2Al+NaOH+{ 2H }_{ 2 }O\longrightarrow { 2NaAlO }_{ 2 }+3{ H }_{ 2 }\)
But when Al is treated with conc.HNO3.a thin protective layer of
Al2O3 is formed on its surface which prevents further action.
\(2Al+6{ HNO }_{ 3 }\longrightarrow { Al }_{ 2 }{ O }_{ 3 }+{ 6NO }_{ 2 }+{ 3H }_{ 2 }O\)
5.
The hydroxide formed in aqueous solution is Al(OH)3
6.
Carbon form covalent compounds because of two reasons.
i) Carbon cannot lose electrons to form C4+ because the ionization energy required is very high
ii) It cannot gain electrons to form C4- because it is energetically not favorable.
But on moving down the group, the I, E, decrease. Pb, being the last element has so low I.E. that it can lose electrons to form ionic compounds.
7.
Boric acid is sparingly soluble in cold water but fairly soluble in hot water. It acts as a weak monobasic acid. It is not a protonic acid but it acts as aLewis acid by accepting a hydroxide ion of water and releasing a proton into the solution.
H-OH + B(OH)3\(\rightarrow\) [B(OH)4]- +H+
8.
\({ SiO }_{ 2 }+2NaOH\longrightarrow { Na }_{ 2 }{ SiO }_{ 3 }+{ H }_{ 2 }O\)
9.
\({ CaCO }_{ 3 }(aq)+{ CO }_{ 2 }+{ H }_{ 2 }O\longrightarrow Ca{ ({ HCO }_{ 3 }) }_{ 2 }\)
Calcium bicarbonate (soluble)
10.
Carbon have the tendency to from \(p\pi -p\pi \) bonds.
11.
Lead is the most metallic element (as down the group metallic character increases)
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