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Published on: 06/09/2019
The s-Block Elements
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1.
The second ionisation enthalpy of calcium is more that of first and yet calcium forms MgCI2 not MgCL. why?
2.
State as to why a solution of Na2CO3 is alkaline?
3.
When alkali metals dissolves in liquid ammonia, the solution can acquire different colours.Explain the reason for. this type of colour change.
4.
Identify A, B, C, and D and give their chemical formulae.
B + NaCl\( \rightarrow\) C + NH4Cl
5.
Give one important one of sodium and potassium element.
6.
A white solid X is a compound of alkali metal. A piece of red litmus paper turns white when it is dipped into a freshly made aqueous solution of the white solid. Identify the white solid X.
7.
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals. Nitrates
8.
Discuss the general characteristics and gradation in properties of alkaline earth metals.
9.
Differentiate between slaked lime
10.
Explain the Aluminium utensils should not be kept in water overnight.
11.
Present a comparative account of the alkali and akaline earth metals with respect to the following characteristics.
formation of oxosalts
12.
Explain the significance of sodium, potassium, magnesium and calcium in biological fluids.
13.
Starting with sodium chloride how would you proceed to prepare? Sodium carbonate.
14.
Reema takes milk every day . She also take curd and other milk products.She takes green leafy vegitables and fruits also. An adult body contains about 25g of magnesium and 1200 g of calcium and 5 g of iron .these elements must be a part of our diet. All enzymes that utilize ATP in phosphate transfer required magnesium as co-factor. the main pigment for the absorption of light in plants is chlorophyll, which contains magnesium. were as Anita does not like milk and takes lot of junk food.
Which vitamin is essential for absorption of calcium ?
15.
Give reson for the following CuCl is more covalent than NaCl
16.
Explain why?
A piece of burning magnesium continues to burn in SO2
17.
Which one of the following alkaline earth metal carbonates is thermally most stable
MgCO3
CaCO3
SrCO3
BaCO3
18.
Which one of the following alkali metals give hydrated salts?
Li
Na
K
Cs
19.
Which of the alkali metal is having least melting point?
Na
K
Rb
Cs
1.
( )
This is because, after removing two electrons from Mg, it acquire stable noble gas configuration or in other words, the higher enthalpy of lattice formation of Mg2+ is more than compensates the second ionisation enthalpy requires for the formation of divalent Mg2+ ions.
2.
( )
Na2CO3 is a salt of a weak acid (H2CO3) and a strong base (NaOH) therefore, it undergoes hydrolysis to produce strong base, NaOH and hence, its aqueous solution is alkaline in nature.
Na2CO3(s) + H2O(l)\(\rightarrow \) 2NaOH(aq) + H2CO3(aq)
Strong base Weak acid
3.
Alkali metals dissolve in liquid ammonia and give deep blue solutions which are conducting in nature because ammoniated electrons absorb energy in the visible region of light and impart blue colour.
M + (x + y)NH3 \(\longrightarrow \)[M(NH3)x]+ + \(\underset { Ammoniated\\ \quad electrons }{ (NH_{ 3 })_{ y } } \)
4.
NH4HCO3 + NaCl \( \rightarrow\) NH4Cl + NaHCO3
Thus ,C is sodium bicarbonate
5.
Sodiun : NaCl
Pottassium : KCl
6.
The substance is Na2O2. When Na2O2 is dissolved in water, it forms NaOH along with H2O2. NaOH is a strong base while H2O2 is a weak acid.
Na2O2 + 2 H2 O \(\longrightarrow \) 2 NaOH + H2O
H2O2 turns colour of red litmus paper white due to its bleaching action (which is due to its oxidising character).
H2O2 \(\longrightarrow \) H2 O + [O]
Na2 O + H2 O \(\longrightarrow \) 2 NaOH
NaOH solution turns colour of red litmus paper into blue due to its stronger alkaline character.
7.
Nitrates of both group 1 and group 2 elements are soluble in water because hydration energy is more than the lattice energy.
Nitrates of both group 1 and group 2 elements are thermally unstable but they decompose differently except LiNO3 e.g.
2NaNO3 \(\overset { heat }{ \longrightarrow } \) 2NaNO2 + O2
2KNO3 \(\overset { \triangle }{ \longrightarrow } \) 2KNO2 + O2
4LiNO3 \(\overset { \triangle }{ \longrightarrow } \) 2Li2O + 4NO2 + O2
2Mg(NO3)2 \(\overset { \triangle }{ \longrightarrow } \) 2MgO + 4NO2 + O2
8.
(i) Atomic size goes on increasing down the group
(ii) Ionisation energy goes on decreasing down the group.
(iii) They are harder than alkali metals
(iv) They are less electropositive than alkali metals
(v) Electropositive character increases on going down the group.
9.
Slaked lime is calcium hydroxide, Ca(OH)2.
\(CaO+{ H }_{ 2 }O\longrightarrow Ca(OH{ ) }_{ 2 }\)
10.
Because aluminium reacts with water and oxygen (dissolved in ) to form a thin layer of toxic aluminium oxide on the surface of utensils.
2Al(s) + O2(g) + H2O(l)\(\rightarrow\)Al2O3(s) + H2(g)
11.
| Alkali metals | Alkaline earth metals |
| An alkali metals from oxosalts such as carbonate, sulphates and nitrates | An alkali metals from oxosalts such as carbonate, sulphates and nitrates |
12.
Sodium ions:
(i) Na+ ions participate in the transmission of nerve signals, in regulating the flow of water across cell membranes.
(ii) In the transport of sugars and amino acids into cell.
Potassium ions:
(i) They activate many enzymes.
(ii) Participate in the oxidation of glucose to produce ATP.
Magnesium ions:
(i) All enzymes that utilise ATP in phosphate transfer require magnesium as a cofactor.
(ii) Mg is the main pigment for the absorption of light in plants.
Calcium:
(i) Ca2+ ions are present in bones.
(ii) plays important roles in neuromuscular function
13.
Sodium carbonate It is obtained by Solvay ammonia process
when CO2 is passed through a concentrated solution of brine (aqeuous solution of NaCl) saturated with ammonia, NaHCO3 gets precipitated.NaHCO3 on Subsequent hetaing gives Na2CO3.
NaCl + NH3 + H2O\(\xrightarrow{\Delta}\) NaHCO3 + NH4Cl
2NaHCO3\(\xrightarrow{\Delta}\) Na2CO3 + CO2 + H2O
14.
Vitamin D
15.
CuCl is more covalent because Cu+ ion have pseudo noble gas confgration , which have more polarising power than NA+ ion
16.
This is because magnesium react with sulphur to from MgO(magnesium oxide) and s (sulphur). TYhis reaction is exothermic and keeps the piece of magnesium burning 2Mg + SO2 \(\rightarrow\) 2Mgo + S
17.
(d)
BaCO3
18.
(a)
Li
19.
(d)
Cs
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