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Published on: 16/09/2019
The s-Block Elements
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Questions + Answers key
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1.
What is soda ash?
2.
Which alkaline earth metals do not impart colour to the flame?
3.
What is the general name for elements of group 1?
4.
Arrange the following in the increasing order of solubility in water MgCl2, CaCl2,SrCI2, BaCl2
5.
Name the alkaline earth metals whose salt do not impart colour to a non-luminous flame.
6.
Which electrolyte is used to obtain sodium in Castner's process?
7.
Name the compounds used for the manufacture of washing soda by Solvay process
8.
How would you explain BaO is soluble but BaSO4 is insoluble in water.
9.
How would you explain BeO is almost insoluble but BeSO4 is soluble in water.
10.
What happens when magnesium is burnt in air
11.
When alkali metals dissolves in liquid ammonia, the solution can acquire different colours.Explain the reason for. this type of colour change.
12.
What happens when magnesium reacts with SO2 gas ?
13.
Explain why can alkali and alkaline earth metals not be obtained by chemical reduction methods?
14.
Write the Lewis structure of O2- ion and find out oxidation state of each oxygen atom? What is the average oxidation state of oxygen in this ion?
15.
A white solid X is a compound of alkali metal. A piece of red litmus paper turns white when it is dipped into a freshly made aqueous solution of the white solid. Identify the white solid X.
1.
Soda ash is anhydrous sodium carbonate (Na2CO3).
2.
Be and Mg
3.
Alkali metals
4.
BaCl2 < SrCI2 < CaCl2 < MgCl2
5.
Beryllium does not impart colour to a non-luminous flame
6.
Fused NaOH
7.
NaCl, CaCO3 and NH3
8.
Both BaO and BaSO4 are ionic compounds but the hydration energy of BaO is higher than the lattice energy therefore it is soluble in water.
9.
Lattice energy of BeO is compartively higher than the hydration energy. Therefore, it is almost insoluble in water. Whereas BeSO4 is ionic in nature and its hydration energy dominates the lattice energy.
10.
2Mg(s) + O2(g)\(\overset { \triangle }{ \longrightarrow } \)2MgO(s)
11.
Alkali metals dissolve in liquid ammonia and give deep blue solutions which are conducting in nature because ammoniated electrons absorb energy in the visible region of light and impart blue colour.
M + (x + y)NH3 \(\longrightarrow \)[M(NH3)x]+ + \(\underset { Ammoniated\\ \quad electrons }{ (NH_{ 3 })_{ y } } \)
12.
2 Mg + CO2 \(\underrightarrow { \Delta } \) MgO + \(\frac { 1 }{ 8 } { S }_{ 8 }\)
13.
(i) Alkali and alkaline earth metals are themselves strong reducing agents. Therefore, these metals cannot be obtained by chemical reduction of their oxides and other compounds.
(ii) These metals are highly electropositive in nature.So these cannot be displaced from the aqueous solutions of their salts by other metals.
14.
The Lewis structure of O2 is : \(\overset { .. }{ \underset { .. }{ O } } \) --- \(\overset { .. }{ O }\):
Oxygen atom carrying no charge has six electrons, so its oxidation number is zero. But oxygen atom carrying -1 charge has 7 electrons, so its oxidation number is -1.
Average oxidation number of each oxygen atom = \(\frac { 1 }{ 2 } \)
\({ O }_{ 2 }^{ - }\) = 2x = -1
\(\Longrightarrow \) x = -\(\frac { 1 }{ 2 } \)
15.
The substance is Na2O2. When Na2O2 is dissolved in water, it forms NaOH along with H2O2. NaOH is a strong base while H2O2 is a weak acid.
Na2O2 + 2 H2 O \(\longrightarrow \) 2 NaOH + H2O
H2O2 turns colour of red litmus paper white due to its bleaching action (which is due to its oxidising character).
H2O2 \(\longrightarrow \) H2 O + [O]
Na2 O + H2 O \(\longrightarrow \) 2 NaOH
NaOH solution turns colour of red litmus paper into blue due to its stronger alkaline character.
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