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Published on: 11/10/2019
The p-block Elements
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1.
How is boron obtained from borax? Give chemical equations with reaction conditions.
2.
Explain the differences in properties of diamond and graphite based upon their structures.
3.
Write suitable chemical equations to show their nature.
4.
what happens when does NaBH4 react with iodine?
5.
What happens when BF3 is reacted with ammonia?
6.
What happens when aluminium is treated with dilute NaOH?
7.
Complete the following reactions
\({ CaCO }_{ 3 }(aq)+{ CO }_{ 2 }(excess)\longrightarrow \)
8.
Complete the following reactions
\(CO+{ H }_{ 2 }\xrightarrow [ ZnO,{ Cr }_{ 2 }{ O }_{ 3 } ]{ 200 \ atm, \ 675K } \)
9.
What happens when borax is heated strongly?
10.
What are the allotropes? Sketch the structure of two allotropes of carbon namely diamond and graphite.What is the impact of structure on physical properties of two allotropes?
1.
Na2B4O7 .10H2O + H2SO4 (conc.)\(\rightarrow\) Na2SO4 + H2B4O7 + 10H2O
Borax
H2B4O7 + 5H2O \(\rightarrow\) 4H3BO3
Boric acid
2H3BO3 \(\xrightarrow[]{Heat}\) B2O3 + 3H2O
Boric oxide
B2O3 + 3Mg \(\xrightarrow[]{\triangle}\)2B + 3MgO
2.
| Diamond | Graphite |
| Diamond is the hardest substance on earth. | Graphite is soft and slippery |
| In diamond carbon is Sp3- hybridized | In Graphite carbon is Sp2- hybridized |
| Since all the electrons in diamond are firmly held in C-C,6 bonds there are no free electrons in diamond crystal Therefore diamond is bad conductor of electricity | Since only three electrons of each carbon are used in making hexagonal rings of graphite, fourth valence electron is free to move thus graphite is a good conductor of electricity |
| Because of high refractive index diamond can reflect and refract the light. | Graphite is a black substance and possess a metallic lustre |
3.
(a) Being acidic B2O3,Sio2 and CO2 react with alkalis to form salts
\(B_{ 2 }O_{ 3 }+2NaOH\rightarrow 2NaBO_{ 2 }+H_{ 2 }O\\ Boric\quad \quad \quad \quad \quad \quad sodium\quad metaborate\\ anhydride\)
\(SiO_{ 2 }+2NaOH\underrightarrow { D } Na_{ 2 }CO_{ 3 }+H_{ 2 }O\)
\(\\ Silica\quad \quad \quad \quad \quad \quad \quad \quad \quad Sodium\quad carbonate\\ CO_{ 2 }+2NaOH\rightarrow Na_{ 2 }CO_{ 3 }+H_{ 2 }O\\ Carbon\quad dioxide\quad \quad \quad sodium\quad carbonate\quad \quad \quad \quad \)
(b) Being amphotric, Al2O3 and PbO2 react with both acids and bases.
\(Al_{ 2 }O_{ 3 }+3H_{ 2 }SO_{ 4 }\rightarrow Al_{ 2 }(SO)_{ 4 }+3H_{ 2 }O\)
\( Al_{ 2 }O_{ 3 }+2NaOH\overset { fuse }{ \rightarrow } \ 2NaAlO_{ 2 }+H_{ 2 }O\)
\(\\ Alumina\quad \quad \quad \quad \quad \quad \quad sodium\quad metaaluminate\\ 2PbO_{ 2 }+2H_{ 2 }SO_{ 4 }\rightarrow 2PbSO_{ 4 }+2H_{ 2 }O+O_{ 2 }\)
\(\\ PbO_{ 2 }+2NaOH\rightarrow Na_{ 2 }PbO_{ 3 }+H_{ 2 }O\\ Lead \ dioxide\quad \quad Sodium \ plumbate\)
(c) Being basic,Tl2O3 reacts with acid
\(Tl_{ 2 }O_{ 3 }+6HCl\rightarrow 2TICl_{ 3 }+3H_{ 2 }O\)
4.
In this reaction, diborane is obtained
aNaBH4 +I2\(\rightarrow\)B2H6 + 2NaI + H2
5.
BF3 being a Lewis acid accepts a pair of electrons from NH3 to form the corresponding complex.
F3B NH3\(\rightarrow\) F3B\(\leftarrow\)NH3
Lewis acid Lewis base Complex
6.
When aluminium is treated with dilute Naoh dihydrogen is evolved.
2Al(s) + 2NaOH(aq) + 6H2O(l)\(\rightarrow\)2Na+[Al(OH)4]-(aq) + 3H2(g)
7.
\({ CaCO }_{ 3 }(aq)+{ CO }_{ 2 }+{ H }_{ 2 }O\longrightarrow Ca{ ({ HCO }_{ 3 }) }_{ 2 }\)
Calcium bicarbonate (soluble)
8.
\(CO+{ H }_{ 2 }\xrightarrow [ ZnO,{ Cr }_{ 2 }{ O }_{ 3 } ]{ 200 \ atm,\ 675K } { CH }_{ 3 }OH\)
methanol
9.
When borax is heated strongly, a transparent glassy bead which consists of sodium metaborate and boric anhydride is formed.
Na2B4O7.10H2O\(\overset { heat}{ \rightarrow } \)Na2B4O7 + 10H2O
Anhydrous (swollen white mass)
Na2B4O7\(\overset { heat }{ \rightarrow } \)\(\underbrace { 2Na{ BO }_{ 2 }\quad \quad \quad \quad \quad \quad \quad \quad +\quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad { B }_{ 2 }{ O }_{ 3 }\\ Sodium\quad metaborate \ Boric \ anhydride }_{ Transparent \ glassy \ bead } \)
10.
The phenomenon of existence of an element in two or more forms which differ in physical properties but have almost same chemical nature is known as allotropy and the different forms of the element are known as allotropes.
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