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Published on: 09/09/2022
QB365 provides a detailed and simple solution for every Possible Case Study Questions in Class 11 Chemistry Subject - Some Basic Concept of Chemistry, CBSE. It will help Students to get more practice questions, Students can Practice these question papers in addition to score best marks.
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1.
Chemistry play an important role in human needs for food, health care products and improving life. Cis platin and taxol are used in chemotherapy, AZT (Azidothymidine) is used for AIDS. SI units are international units of measurement. Matter is classified into elements, compounds and mixtures, which can be homogeneous as well as heterogeneous. A mixture can be separated by physical methods, compounds can be separated by chemical methods only. Atomic mass is average of masses of isotopes depending upon their natural abundance. Empirical formula is calculated with the help of percentage composition of elements in a compound and molecular mass helps to calculate molecular formula. A chemical equation must be balanced so as to follow laws of chemical combination.
(a) Express 2.54 mm into S.I units.
(b) Out of milk, diamond, air, petrol which is pure substance?
(c) Balance the equation: NO2 + H2 O \(\rightarrow\) HNO3 + NO
(d) What is percentage of Na in Na2CO3 ? (Na = 23u, C = 12, O = 16u)
(e) \({ }_{17}^{35} \mathrm{Cl} \text { and }{ }_{17}^{37} \mathrm{Cl}\) are in ratio of 3 : 1 in nature. What is atomic mass of CI?
(f) What is empirical formula of C6H12O6?
(g) Chlorophyll contains 2.68% magnesium atoms. Calculate mass of magnesium atoms in 2 g of chlorophyll.
2.
In the table given below to illustrate precision and accuracy. Study the table and answer the questions based on the table and related studied concepts.
Data to Illustrate Precision and Accuracy
| Measurement in g | I | II | III | Average |
| student A | 0.521 g | 0.515 g | 0.509 g | 0.515 g |
| student B | 0.516 g | 0.515 g | 0.514 g | 0.515 g |
| student C | 0.521 g | 0.520 g | 0.520 g | 0.520 g |
(a) What is meant by precision?
(b) What is accuracy?
(c) If actual mass of a piece of metal is 0.520 g, data for which student is neither precise nor accurate.
(d) Which student data is precise but not accurate?
(e) The data of which student is both precise and accurate?
(f) How many significant figures are in 0.520?
(g) What is scientific notation for 0.520?
3.
Stoichiometry is a section of chemistry that involves calculation based on chemical equations. Chemical equations are governed by laws of chemical combination. Mass of reactants is equal to mass of products. Compound obtained from different methods contain the same elements in the fixed ratio by mass. Mole is a counting unit, equal to 6.022 x 1023 particles.
One mole is also equal to molar mass expressed in grams. One mole of every gas at STP has volume equal to 22.4 L. The reacting species which are consumed in the reaction completely is called limiting reagent which decides amount of products formed. Concentration of solution is expressed in terms of molarity, molality and mole fraction.
(a) Calculate number of moles of NH3 formed by reaction of 2 moles of N2 and 2 moles of H2.
\(\mathbf{N}_{2}(g)+3 \mathbf{H}_{2}(g) \longrightarrow 2 \mathrm{NH}_{3}(g)\)
(b) Calculate number of electrons in 18 g of H2 O. [Atomic number of H = 1 ,O = 8]
(c) Calculate the molality of 1 M NaCI solution having density 1.10 g cm-3. (Molar mass = 58.5 g mol-1)
(d) Define mole fraction.
(e) In aqueous solution of glucose Xglucose = 0.1, what is XH2O = ?
1.
(a) 2.54 x 10- 3 m.
(b) Diamond.
(c) 3NO2 + H2O \(\rightarrow\) 2HNO3 + NO
(d) \(\% \text { of } \mathrm{Na}=\frac{\text { Total mass of } \mathrm{Na}}{\text { Molar mass }} \times 100\)
\(=\frac{46}{106} \times 100=43.39 \%\)
(e) \(\frac{3 \times 35+1 \times 37}{4}=35.5\)
(f) CH2O
(g) Mass of magnesium atoms \(=2 \times \frac{2.68}{100}\)
\(=\frac{5.36}{100}=0.0536 \mathrm{~g}\)
2.
(a) It refers to the closeness of the set of values obtained from identical measurements.
(b) It refers to the closeness of a single measurement to its true value.
(c) 'A' because the individual values differ widely and average value is not accurate.
(d) 'B'. The values deviate a little from each other but average is not equal to true value.
(e) 'C' because the value are close to each other as well as average is same as true value.
(f) 3
(g) 5.20 x 10- 3
3.
(a) 1 mole of N2 needs 3 moles of H2 ,
Therefore, 2 moles of N2 needs 6 moles of H2 .
But we have only 2 moles of H2 , so H2 is limiting reagent.
3 moles of H2 gives 2 moles of NH2.
2 moles of H2 gives \(\frac{2}{3} \times 2=1.33\) moles of NH3 .
(b) 18 g of water (1 mole) containing 10 x 6.022 x 1023 electrons = 6.022 x 1024 electrons.
[ \(\because\)1 molecule of H2O = 2 + 8 = 10 e)
(c) 'M is molarity
'd is density of solution
'm' is molality
\(m=\frac{M \times 1000}{1000 \times d-M \times \text { Molar mass }}\)
\(=\frac{1 \times 1000}{1000 \times 1.10-1 \times 58.5}\)
\(=\frac{1000}{1100-58.5}=\frac{1000}{1041.5}=m=0.96 \mathrm{~mol} / \mathrm{kg} .\)
(d) It is ratio of number of moles of solute (component) to the total number of moles of solute and solvent (all components).
(e) Xglucose + xH2O = 1
\(\Rightarrow\) XH2O = 1 - 0.1 = 0.9
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