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Published on: 31/07/2018
From the chapter The s-Block Elements, some of the important questions are covered in this question paper. The questions are covers from the book back and the previous year questions.
Download CBSE Class 11th Standard CBSE Chemistry question papers, sample papers, important questions, and previous year solved papers in PDF format. Get free study materials, NCERT solutions, and exam preparation resources for Class 11th Standard CBSE Chemistry
Questions + Answers key
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1.
What is magnesia cement? Give its composition.
2.
What is epsom salt? What is the action of heat on it?
3.
Why do hydrides and halides of Be polymerise?
4.
Name an element from group 2 which forms an amphoteric oxide and a water soluble sulphate.
5.
The second ionisation enthalpy of calcium is more that of first and yet calcium forms MgCI2 not MgCL. why?
6.
Potassium carbonate cannot be prepared by Solvay process. Why?
7.
Which colours are imparted to flame when the following elements are introduced in the flame one by one?
Barium
8.
Lithium is the only alkali metal that forms nitride directly on reaction with air. Explain.
9.
Why does the solubility of alkaline earth metal carbonnates and sulphate in water decrease down the group?
10.
What happens when magnesium reacts with CO2
11.
Explain why can alkali and alkaline earth metals not be obtained by chemical reduction methods?
12.
In the Solvay process, can we obtain sodium carbonate directly by treating the solution containing (NH4)2CO3 with sodium chloride? Explain.
13.
The stability of peroxide and superoxide of alkali metals increase as we go down to group. Explain by giving reason.
14.
Why are alkali metals soft and have low melting points ?
15.
Why cannot sodium and potassium ne prepared by the electrolysis of their aqueous solutions ?
16.
Explain the Aluminium alloys are used to make aircraft body.
17.
Name the groups which constitute s-block elements.
18.
Write the balanced equations for the reactions between Na2 O2 and water.
19.
What happens when Sodium metal is dropped in water?
20.
Sodium peroxide is a yellow solid, but when it exposed to air it becomes white. Why?
1.
( )
When a satured solution of magnesium chloride is mixed with magnesium oxide, it sets to a hard mass. This hard mass is known as magnesia cement . Its composition is MgCI2 . 5 MgO . H2O.
2.
( )
MgSO4 . 7 H2O;
\(Mg{ SO }_{ 4 }.7{ H }_{ 2 }O\xrightarrow [ 423K ]{ -6{ H }_{ 2 }o } Mg{ SO }_{ 4 }.{ H }_{ 2 }O\)
\(\\ \xrightarrow [ 573k ]{ -{ H }_{ 2 }O } Mg{ SO }_{ 4 }\xrightarrow [ Heat ]{ . } MgO+S{ O }_{ 3 }\)
3.
( )
Since BeH2 and BeCl2 have only four electrons in the valence shell, therefore, they are electron deficient molecules.
To make up their electron deficiency, each Be atom forms four, three - center two-electron bonds or banana bonds. Thus, it is due to electron deficiency that BeH2 and BeCl2 have polymeric structures.
4.
( )
Due to small size and high ionisation enthalpy of Be, BeO is amphoteric in nature, i.e. it reacts with both acids and bases. Further due to small size, the hydration enthalpy of Be2+ ions is much higher than the lattice enthalpy of BeSO4.As a result, BeSO4 is highly soluble in water.
5.
( )
This is because, after removing two electrons from Mg, it acquire stable noble gas configuration or in other words, the higher enthalpy of lattice formation of Mg2+ is more than compensates the second ionisation enthalpy requires for the formation of divalent Mg2+ ions.
6.
( )
Potasium carbonate is soluble in water and does not precipitates when carbon dioxide is passed. Therefore solvay process is not used for the preperetion of potassium carbonate.
7.
( )
Barium-grassy green
8.
( )
Li+ ion being small in size can easily stablize small nitride ion N3-,however other alkali metal ions because of their larger size cannot stablise smaller nitride ion.Thus,only lithium forms nitride.
9.
Since, the anion is common in all and its size being much larger compared to constant within a particular group. Only the hydration enthalpies derease down the group, which results decrease in the solubility in same direction.
10.
2 Mg + CO2 \(\underrightarrow { \Delta } \) MgO + C
11.
(i) Alkali and alkaline earth metals are themselves strong reducing agents. Therefore, these metals cannot be obtained by chemical reduction of their oxides and other compounds.
(ii) These metals are highly electropositive in nature.So these cannot be displaced from the aqueous solutions of their salts by other metals.
12.
No, (NH4)2CO3 reacts with NaCl as
(NH4)2CO3 + 2NaCl \(\leftrightharpoons \) Na2CO3 + 2NH4Cl
Because the products obtained Na2CO3 and NH4Cl are highly soluble and the equilibrium will not shift in forward direction. That's why in the Solvay process, we cannot obtain sodium carbonate directly by treating the solution containing (NH4)2CO3 with sodium chloride.
13.
The stability of peroxide or superoxide increases as the size of metal ion increases i.e.
KO2 < RbO2 < CsO2
The reactivity of alkali metals toward oxygen to form different oxides is due to string positive field around each alkali metal cation. Li+ is the smallest. it does not allow O2- ion to react with O2 further. Na+ is larger than Li, its positive field is weaker than Li+.
It cannot prevent the conversion of O2- into O22-. The large ions such as K+, Rb+ and Cs+ permit O22- ion to react with O2 forming superoxide ion O2-
\({ O }_{ 2 }^{ 2- } \overset { \frac { 1 }{ 2 } { O }_{ 2 } }{ \longrightarrow } O^{2-} \overset { { O }_{ 2 } }{ \longrightarrow } 2 { O }_{ 2 }^{ - }\)
Furthermore, increased stability of the peroxide or superoxide with increase in the size of metal ion is due to the stabilisation of large anions by larger cations through lattice energy effect.
14.
Alkali metals have only one valence electron per metal atom. As a result, the binding energy of alkali metal ions in the close-packed metal lattices are weak. Therefore these are soft and have low melting points.
15.
The electrode potential, i.e. reduction potential of Na (-2.71 V) or K (-2.92) is much lower than that of H2 O
(-0.83 V), therefore, upon electrolysis, water gets reduced in preference to Na+ or K+ ions. In other words, sodium and potassium cannot be obtained by electrolytic reduction of Na+ and K+ ions in aqueous solution.
16.
Aluminium alloys such as duralumin is light, tough and resistant to corrosion and hence, it is used in making aircraft body
17.
s-block contains only two groups; group 1 (alkali metals) and group 2 (alkaline earth metals)
18.
Na2 O2 (s) + 2 H2 O (l) \(\longrightarrow \) 2 NaOH (aq) + H2 O2 (aq)
19.
H2 gas is evolved which catches fire due to the liberation of extreme heat in the reaction.
2 Na (s) + 2 H2 O(l) \(\longrightarrow \) 2 NaOH (aq) + H2 (g)
20.
Because in presence of moisture and CO2 (which is present in air ), Na2O2 is converted top NaOH and Na2Co3 respectively both which are white in colour .
Na2O2 + H2O \(\rightarrow\) 2NaOH + H2O2
2Na2O2 + 2CO2 \(\rightarrow\) 2Na2CO3 + O2
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