Give the structures and IUPAC names of monohydric phenols of molecular formula C₇H₈O.

Arrange the following sets of compounds in order of their increasing order of their acid strength:
Propan-1-ol, 2,4,6-trinitrophenol, 3-nitro-phenol, 3,5-dinitrophenol, phenol, 4-methyl-phenol.

Suggest a reagent for the following conversion.

Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.
(ii) Oxidation of a primary alcohol to an aldehyde.
(iii) Bromination of phenol to 2,4,6-tribromophenol.
(iv) Benzyl alcohol to benzoic acid.
(v) Dehydration of propan-2-ol to propene.
(vi) Butan-2-one to butan-2-ol.

How are the following conversions carried out?
(i) Propene \(\longrightarrow \) Propan-2-ol
(ii) Ethyl magnesium chloride\(\longrightarrow \) Benzyl alcohol
(iii) Ethyl magnesium chloride \(\longrightarrow \) Propan-1-ol.
(iv) Methyl magnesium bromide\(\longrightarrow \) 2-Methylpropan-2-ol.

Write equations of the following reactions:
(i) Friedel-Crafts reaction - alkylation in anisole,
(ii) Nitration of anisole
(iii) Bromination of anisole in ethanoic acid medium,
(iv) Friedel- Crafts acetylation of anisole.

The C-O-C bond angle in the ether molecule is

Phenol, when it first reacts with concentrated sulphuric acid and then with concentrated nitric acid, gives

Which of the above compound(s), on being warmed with iodine solution and NaOH, will give iodoform?

In the following sequence of reactions, CH₃-Br \(\overset{KCN}\longrightarrow\) A \(\overset{H_3O^+}\longrightarrow\) B \(\overset { LiAlH_{ 4 } }{ \underset { ether }{ \longrightarrow } } \) C the end product (c) is

How many alcohols with molecular formula C₄H₁₀O are chiral in nature?

Assertion: Boiling points of alcohols are higher than ethers.
Reason: They can form intennolecular hydrogen bonding.
Codes:
A) Assertion and reason both are correct and reason is correct explanation of assertion.
B) Both assertion and reason are correct statements but reason is not correct explanation of assertion.
C) Assertion is correct statement but reason is wrong statement.
D) Assertion is wrong statement but reason is correct statement.

Assertion : With HI at 373 K, ter-butyl methyl ether gives ter-butyl iodide and methanol.
Reason : The reaction occurs by SN² mechanism.
Codes:
(a) If both Assertion and Reason are correct and the Reason is a correct explanation of the Assertion.
(b) If both Assertion and Reason are correct but Reason is not a correct explanation of the Assertion.
(c) If the Assertion is correct but Reason is incorrect.
(d) If both the Assertion and Reason are incorrect.

In the following questions. an Assertion (A) is followed by a corresponding Reason (R) Use the following keys to choose the appropriate answer.
Assertion (A) Alcohols and phenols are soluble in water.
Reason (R) There occurs a dipole-dipole interaction of OH group of alcohol and phenol with water molecules which is responsible for their solubility in water.
​​​​​​​Codes:
(a) Both (A) and (R) are correct, (R) is the correct explanation of (A).
(b) Both (A) and (R) are correct, (R) is not the correct explanation of (A).
(c) (A) is correct; (R) is incorrect.
(d) (A) is incorrect; (R) is correct.

A compound (X) containing C, Hand O is unreactive towards sodium. It also does not react with Schiff’s reagent. On refluxing with an excess ofhydroiodic acid, (X) yields only one organic product (Y). On hydrolysis, (Y) yields a new compound (Z) which can be converted into (Y) by reaction with red phosphorus and iodine. The compound (Z) on oxidation with potassium permanganate gives a carboxylic acid. The equivalent weight of this acid is 60.
(i) The compound (X) is an
(a) acid
(b) aldehyde
(c) alcohol
(d) ether
ii) The IUPAC name of the acid formed is
(a) methanoic acid
(b) ethanoic acid
(c) propanoic acid
(d) butanoic acid.
iii) Compound (Y) is
(a) ethyl iodide
(b) methyl iodide
(c) propyl iodide
(d) mixture of (a) and (b).