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Published on: 24/05/2021
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Questions + Answers key
Take MCQ Chemistry Test

1.
The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is.................................. .
excess H2/Pt
NaOH/Br2
NaBH4/methanol
LiAIH4/ether
2.
The best reagent for converting 2-phenylpropanamide into 2-phenylpropanamine is........................... .
excess H2
Br2 in aqueous NaOH
iodine in the presence of red phosphorus
LiAlH4 in ether
3.
In order to prepare a \({ 1 }^{ \circ }\) amine from an alkyl halide with simultaneous addition of one -CH2 group in the carbon chain, the reagent used as source of nitrogen is ___________ .
Sodium amide, NaNH2
Sodium azide, NaN3
Potassium cyanide, KCN
Potassium phthalimide, C6H6(CO)2N-K+
4.
Benzylamine may be alkylated as shown in the following equation:
C6H5CH2NH2+R-X \(\longrightarrow \) C6H5CH2NHR
Which of the following alkyl halides is best suited for this reaction through SN 1 mechanism?
CH3Br
C6H5Br
C6H5CH2Br
C2H5Br
5.
The correct IUPAC name for CH2=CHCH2NHCH3 is
Allylmethylamine
2-amino-4-pentene
4-aminopent-1-ene
N-methylprop-2-en-1-amine
1.
(b)
NaOH/Br2
2.
(d)
LiAlH4 in ether
3.
(c)
Potassium cyanide, KCN
4.
Since C6H5CH2Br on ionization gives a resonance stabilized benzyl carbocation \(\left( { C }_{ 6 }{ H }_{ 5 }{ CH }_{ 2 }^{ + } \right) \) , therefore, C6H5CH2Br is best suited for SN1 reaction.
5.
\(\overset { 3 }{ C } { H }_{ 2 }=\overset { 2 }{ C } H\overset { 1 }{ C } { H }_{ 2 }NHCH_{ 3 }\quad N-Methylprop-2-en-1\quad amine\)
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