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Published on: 28/05/2021
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Questions + Answers key
Take MCQ Chemistry Test1.
Why thermite process is not used for obtaining aluminum from bauxite.
2.
How does NaCN act as a depressant in preventing zinc from forming the froth? Explain.
3.
What is the difference between reverberatory furnace & blast furnace.
4.
Out of C and CO, which is a better reducing agent at 673 K?
5.
Why copper matte is put in silica lined converter?
1.
When aluminium metal is used as a reducing agent for reducing oxides of metals such as Mn, Fe, Cr etc., the process of reduction is known as thermite process.
Example:
Cr2O3 + \(\longrightarrow\) Al2O3 + 2Cr
2.
ZnS forms soluble complex Na2 [Zn(CN)4] while PbS forms froth.
When the minerals are expected to contain PbS and ZnS, suitable depressants such as NaCN are added.
The added NaCN, selectively prevents ZnS from coming to the froth by forming soluble complex Na2[Zn(CN)4] and PbS is removed along with the froth.
3.
Reverberatory furnace used for smelting, refining, or melting in which the fuel is not in direct contact with the contents but heats it by a flame blown over it from another chamber.
Blast furnaces are used to produce pig iron from iron ore.
4.
At 673 K, the value of \(\triangle G_{C O, C O_{2}}\) ,is less than that of \(\triangle G_{(\mathrm{C}, \mathrm{CO})}\) Therefore, CO can be oxidised more easily to CO2 than C to CO. Hence, CO is a better reducing ag ent than C at 673 K.
5.
Copper matte chiefly consists of Cu2S along with some unchanged FeS. When a blast of hot air is passed through molten matte taken in a silica lined converter, FeS present in matte is oxidised to FeO which combines with silica (SiO2) to form FeSiO3 slag.
\(2FeS+3{ O }_{ 2 }\longrightarrow 2FeO+2S{ O }_{ 2 }\uparrow \quad ;\quad FeO+\underset { Silica }{ Si{ O }_{ 2 } } \longrightarrow \underset { Slag }{ FeSi{ O }_{ 3 } } \)
When whole of iron has been removed as slag, some of the CU2S undergoes oxidation to form Cu 2O which then reacts with more Cu2S to form copper metal.
\(2{ Cu }_{ 2 }S+3{ O }_{ 2 }\longrightarrow 2{ Cu }_{ 2 }S+2S{ O }_{ 2 }\uparrow \quad ;\quad 2{ Cu }_{ 2 }O+{ Cu }_{ 2 }S\longrightarrow 6Cu+2S{ O }_{ 2 }\uparrow \)
Thus, copper matte is heated in silica lined converter to remove FeS present in matte as FeSiO3 slap.
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